Far infrared reflection spectroscopy of Zn2SnO4 ceramics obtained by sintering mechanically activated ZnO-SnO2 powder mixtures
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2007
Authors
Nikolić, Maria Vesna![](/themes/MirageDAIS/images/orcid.png)
Ivetić, Tamara
![](/themes/MirageDAIS/images/orcid.png)
Paraskevopoulos, Konstantinos M.
![](/themes/MirageDAIS/images/orcid.png)
Zorbas, Kostas T.
Blagojević, Vladimir D.
Vasiljević Radović, Dana
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Article (Published version)
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A mixture of starting ZnO and SnO2 powders (molar ratio 2: 1) were mechanically activated for 10, 40, 80 and 160 min in a planetary ball mill and then isothermally sintered at 1300 degrees C for 2 h in order to obtain Zn2SnO4 ceramics. X-ray diffraction analysis confirmed single-phase polycrystals. Far infrared reflection spectra were measured (100-1400 cm(-1)). The same oscillators were observed, but the highest intensity of reflectivity peaks was obtained for the powder activated 10min and it gradually decreased with longer times of mechanical activation. This is in agreement with microstructure analvsis where longer times of mechanical activation lead to increased porosity and defects. Using group theory six ionic oscillators were calculated for single crystal Zn2SnO4 Spectra, but two more oscillators were observed in the obtained experimental spectra, which Could be the result of mechanical activation and sintering. The FIR experimental results were numerically analyzed and oscilla...tor parameters were calculated.
Keywords:
spinels / spectroscopy / sintering / optical properties / millingSource:
Journal of the European Ceramic Society, 2007, 27, 13-15, 3727-3730Publisher:
- Elsevier Sci Ltd, Oxford
Funding / projects:
- Investigation of the relation in triad: Synthesis structure-properties for functional materials (RS-MESTD-MPN2006-2010-142011)
DOI: 10.1016/j.jeurceramsoc.2007.02.040
ISSN: 0955-2219
WoS: 000248822800032
Scopus: 2-s2.0-34347380610
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Nikolić, Maria Vesna AU - Ivetić, Tamara AU - Paraskevopoulos, Konstantinos M. AU - Zorbas, Kostas T. AU - Blagojević, Vladimir D. AU - Vasiljević Radović, Dana PY - 2007 UR - https://dais.sanu.ac.rs/123456789/12888 AB - A mixture of starting ZnO and SnO2 powders (molar ratio 2: 1) were mechanically activated for 10, 40, 80 and 160 min in a planetary ball mill and then isothermally sintered at 1300 degrees C for 2 h in order to obtain Zn2SnO4 ceramics. X-ray diffraction analysis confirmed single-phase polycrystals. Far infrared reflection spectra were measured (100-1400 cm(-1)). The same oscillators were observed, but the highest intensity of reflectivity peaks was obtained for the powder activated 10min and it gradually decreased with longer times of mechanical activation. This is in agreement with microstructure analvsis where longer times of mechanical activation lead to increased porosity and defects. Using group theory six ionic oscillators were calculated for single crystal Zn2SnO4 Spectra, but two more oscillators were observed in the obtained experimental spectra, which Could be the result of mechanical activation and sintering. The FIR experimental results were numerically analyzed and oscillator parameters were calculated. PB - Elsevier Sci Ltd, Oxford T2 - Journal of the European Ceramic Society T1 - Far infrared reflection spectroscopy of Zn2SnO4 ceramics obtained by sintering mechanically activated ZnO-SnO2 powder mixtures SP - 3727 EP - 3730 VL - 27 IS - 13-15 DO - 10.1016/j.jeurceramsoc.2007.02.040 UR - https://hdl.handle.net/21.15107/rcub_dais_12888 ER -
@article{ author = "Nikolić, Maria Vesna and Ivetić, Tamara and Paraskevopoulos, Konstantinos M. and Zorbas, Kostas T. and Blagojević, Vladimir D. and Vasiljević Radović, Dana", year = "2007", abstract = "A mixture of starting ZnO and SnO2 powders (molar ratio 2: 1) were mechanically activated for 10, 40, 80 and 160 min in a planetary ball mill and then isothermally sintered at 1300 degrees C for 2 h in order to obtain Zn2SnO4 ceramics. X-ray diffraction analysis confirmed single-phase polycrystals. Far infrared reflection spectra were measured (100-1400 cm(-1)). The same oscillators were observed, but the highest intensity of reflectivity peaks was obtained for the powder activated 10min and it gradually decreased with longer times of mechanical activation. This is in agreement with microstructure analvsis where longer times of mechanical activation lead to increased porosity and defects. Using group theory six ionic oscillators were calculated for single crystal Zn2SnO4 Spectra, but two more oscillators were observed in the obtained experimental spectra, which Could be the result of mechanical activation and sintering. The FIR experimental results were numerically analyzed and oscillator parameters were calculated.", publisher = "Elsevier Sci Ltd, Oxford", journal = "Journal of the European Ceramic Society", title = "Far infrared reflection spectroscopy of Zn2SnO4 ceramics obtained by sintering mechanically activated ZnO-SnO2 powder mixtures", pages = "3727-3730", volume = "27", number = "13-15", doi = "10.1016/j.jeurceramsoc.2007.02.040", url = "https://hdl.handle.net/21.15107/rcub_dais_12888" }
Nikolić, M. V., Ivetić, T., Paraskevopoulos, K. M., Zorbas, K. T., Blagojević, V. D.,& Vasiljević Radović, D.. (2007). Far infrared reflection spectroscopy of Zn2SnO4 ceramics obtained by sintering mechanically activated ZnO-SnO2 powder mixtures. in Journal of the European Ceramic Society Elsevier Sci Ltd, Oxford., 27(13-15), 3727-3730. https://doi.org/10.1016/j.jeurceramsoc.2007.02.040 https://hdl.handle.net/21.15107/rcub_dais_12888
Nikolić MV, Ivetić T, Paraskevopoulos KM, Zorbas KT, Blagojević VD, Vasiljević Radović D. Far infrared reflection spectroscopy of Zn2SnO4 ceramics obtained by sintering mechanically activated ZnO-SnO2 powder mixtures. in Journal of the European Ceramic Society. 2007;27(13-15):3727-3730. doi:10.1016/j.jeurceramsoc.2007.02.040 https://hdl.handle.net/21.15107/rcub_dais_12888 .
Nikolić, Maria Vesna, Ivetić, Tamara, Paraskevopoulos, Konstantinos M., Zorbas, Kostas T., Blagojević, Vladimir D., Vasiljević Radović, Dana, "Far infrared reflection spectroscopy of Zn2SnO4 ceramics obtained by sintering mechanically activated ZnO-SnO2 powder mixtures" in Journal of the European Ceramic Society, 27, no. 13-15 (2007):3727-3730, https://doi.org/10.1016/j.jeurceramsoc.2007.02.040 ., https://hdl.handle.net/21.15107/rcub_dais_12888 .