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Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase
dc.creator | Stamenković, Tijana | |
dc.creator | Dinić, Ivana | |
dc.creator | Vuković, Marina | |
dc.creator | Radmilović, Nadežda | |
dc.creator | Barudžija, Tanja | |
dc.creator | Tomić, Miloš | |
dc.creator | Mančić, Lidija | |
dc.creator | Lojpur, Vesna | |
dc.date.accessioned | 2023-10-18T22:38:09Z | |
dc.date.available | 2023-10-18T22:38:09Z | |
dc.date.issued | 2023 | |
dc.identifier.issn | 0272-8842 | |
dc.identifier.uri | https://dais.sanu.ac.rs/123456789/15138 | |
dc.description.abstract | In this investigation, samples of strontium-gadolinium-oxide (SrGd2O4) doped with different Yb3+ (2, 4 and 6 at%) and constant Ho3+ (1 at%) contents and co-doped with Bi3+ (2 at%) were prepared using the glycine-assisted sol–gel method. The pure orthorhombic SrGd2O4 phase, space group Pnma, was revealed using X-ray diffraction in all samples. Transmission electron microscopy discovered agglomerated clusters of spherical particles measuring approximately 150 nm in size. The inclusion of Bi3+ ions into the structure influenced the morphology since the formation of larger grains was observed, with sizes reaching up to ∼1.7 μm. The uniform distribution of all constitutive elements was confirmed by energy-dispersive X-ray spectroscopy. In all samples, up-conversion emission spectra revealed two dominant green (540 and 550 nm), red (671 nm), and infrared (758 nm) emission lines, due to the 5F4,5S2→5I8, 5F5→5I8, and 5F4,5S2 → 5I7 transitions, respectively. The sample co-doped with Bi3+ showed the most intense photoluminescent emissions, shorter luminescence decay, and the highest quantum yield. Additionally, a significant decrease in the energy band gap value was detected using diffuse reflectance spectroscopy for this sample. Methylene blue was used as a test pollutant to investigate its photocatalytic efficiency under simulated sunlight irradiation. The results show that Bi3+ co-doping deteriorates the photocatalytic efficiency of the SrGd2O4:Yb3+/Ho3+ phase by reducing hydroxyl radical formation. | en |
dc.language | en | |
dc.publisher | Elsevier | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200017/RS// | en |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200175/RS// | en |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200288/RS// | en |
dc.rights | restrictedAccess | |
dc.source | Ceramics International | en |
dc.subject | up-conversion | en |
dc.subject | SrGd2O4 | en |
dc.subject | rare earth ions | en |
dc.subject | luminescence | en |
dc.subject | bandgap | en |
dc.subject | photocatalysis | en |
dc.title | Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase | en |
dc.type | article | en |
dc.rights.license | ARR | en |
dc.citation.spage | 37758 | |
dc.citation.epage | 37767 | |
dc.citation.volume | 49 | |
dc.citation.issue | 23 | |
dc.identifier.doi | 10.1016/j.ceramint.2023.09.103 | |
dc.identifier.scopus | 2-s2.0-85171296363 | |
dc.type.version | publishedVersion | |
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_dais_15138 |