Приказ основних података о документу
Investigation of structural, microstructural and magnetic properties of YbxY1-xF3 solid solutions
dc.creator | Aleksić, Jelena | |
dc.creator | Barudžija, Tanja | |
dc.creator | Jugović, Dragana | |
dc.creator | Mitrić, Miodrag | |
dc.creator | Bošković, Marko | |
dc.creator | Jagličić, Zvonko | |
dc.creator | Lisjak, Darja | |
dc.creator | Kostić, Ljiljana | |
dc.date.accessioned | 2020-07-17T11:51:24Z | |
dc.date.available | 2020-07-17T11:51:24Z | |
dc.date.issued | 2020 | |
dc.identifier.issn | 0022-3697 | |
dc.identifier.uri | http://www.sciencedirect.com/science/article/pii/S0022369719325983 | |
dc.identifier.uri | https://dais.sanu.ac.rs/123456789/8948 | |
dc.description.abstract | In this investigation, we have synthesized YbxY1-xF3 solid solutions by fluorination of yttrium and ytterbium sesquioxides with ammonium hydrogen difluoride. According to the XRD analysis, all synthesized YbxY1-xF3 samples have an orthorhombic crystal structure belonging to the β-YF3 structural type. The refinement of crystal structure was done by the Rietveld method within the Pnma space group using the TCH pseudo-Voigt function. The anisotropic peak broadening was analyzed, and the average apparent crystallite size is about 50 nm with a small anisotropy of shape, while the significant microstrain that is highly anisotropic is present in all samples. The temperature-dependent magnetic susceptibility was analyzed by applying the model of a free ion perturbed by the crystal field. We have obtained the effective magnetic quantum numbers Mieff of four Kramer's doublets of Yb3+ ion along with the entire crystal field splitting of the 2F7/2 manifold of Yb3+ in YF3. The acquired maximum energy splitting of the ground level is about 150 K in our most diluted samples. The field-dependent isothermal magnetization measurements were carried out at various temperatures and analyzed by classical Langevin function. Results obtained from magnetic measurements show that all YbxY1-xF3 (x ≠ 0) solid solutions exhibit pure paramagnetic behavior in the whole temperature range from 2 to 300 K, with a predominant antiferromagnetic exchange interactions. | en |
dc.language | en | |
dc.publisher | Elsevier | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45015/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45004/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/171025/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Technological Development (TD or TR)/32026/RS// | |
dc.relation | Bilateral collaboration between Serbia and Slovenia (06-00-118/2018-09/32/02) | |
dc.relation | Bilateral collaboration between Serbia and Slovenia (BI-RS/18-19-031) | |
dc.rights | restrictedAccess | |
dc.source | Journal of Physics and Chemistry of Solids | |
dc.subject | Crystal and ligand fields | |
dc.subject | Magnetic measurements | |
dc.subject | Rare-earth fluorides | |
dc.subject | X-ray diffraction | |
dc.title | Investigation of structural, microstructural and magnetic properties of YbxY1-xF3 solid solutions | en |
dc.type | article | en |
dc.rights.license | ARR | |
dcterms.abstract | Бошковић, Марко; Лисјак, Дарја; Костић, Љиљана; Јагличић, Звонко; Митрић, Миодраг; Југовић, Драгана; Баруджија, Тања; Aлексић, Јелена; | |
dc.citation.spage | 109449 | |
dc.citation.volume | 142 | |
dc.identifier.wos | 000528271700008 | |
dc.identifier.doi | 10.1016/j.jpcs.2020.109449 | |
dc.identifier.scopus | 2-s2.0-85081116825 | |
dc.description.other | Peer-reviewed manuscript: [https://hdl.handle.net/21.15107/rcub_dais_8949] | |
dc.type.version | publishedVersion | |
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_dais_8948 |