Multifunctionalized Self-supported (Nano) Membranes as Integrated Platform for Plasmonic Metamaterials
Apstrakt
We considered the possibility to fabricate multifunctional nanocomposite membranes as a platform for plasmonic metamaterials, simultaneously incorporating pores, built-in functional groups and active nanoparticles. To this purpose we combined lamination and inclusion of nanofillers into the membrane host. For the basic material we chose macroporous crosslinked copolymers based on glycidyl methacrylate (GMA). The epoxy group present in GMA molecule is readily transformed into various functional groups that further serve as affinity enhancers, ensuring the usability of the membranes as pre-concentrators of selected agents in plasmonic sensors. To form GMA-based membranes we used a recently proposed method combining the traditional immersion precipitation with photopolymerization and crosslinking of functional monomers. Further functionalization is obtained by in-situ formation of noble metal nanoparticles directly within the GMA host. In this way membranes with simultaneous plasmonic, ad...sorbent and catalytic functionality are obtained. We considered the use of the our structures for plasmonic chemical sensors where separator, pre-concentrator and binding agent are integrated with the plasmonic crystal, as well as for plasmonic enhancement of photocatalytic reactions in microreactors. Our approach gives a highly tailorable element compatible with microelectromechanical systems (MEMS) technologies and readily transferable across platforms.
Ključne reči:
nanocomposite membranes / MEMS / glycidyl methacrylate / plasmonicsIzvor:
Progress in Electromagnetics Research Symposium, PIERS 2013, 12-15 August 2013, Stockholm, Sweden, 2013, 1016-1020Izdavač:
- Cambrridge, MA : The Electromagnetics Academy
Finansiranje / projekti:
- Mikro, nano-sistemi i senzori za primenu u elektroprivredi, procesnoj industriji i zaštiti životne sredine (RS-MESTD-Technological Development (TD or TR)-32008)
- Nove tehnologije za monitoring i zaštitu životnog okruženja od štetnih hemijskih supstanci i radijacionog opterećenja (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43009)
Institucija/grupa
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - CONF AU - Jakšić, Zoran AU - Radovanović, Filip AU - Nastasović, Aleksandra AU - Matović, Jovan PY - 2013 UR - https://dais.sanu.ac.rs/123456789/783 AB - We considered the possibility to fabricate multifunctional nanocomposite membranes as a platform for plasmonic metamaterials, simultaneously incorporating pores, built-in functional groups and active nanoparticles. To this purpose we combined lamination and inclusion of nanofillers into the membrane host. For the basic material we chose macroporous crosslinked copolymers based on glycidyl methacrylate (GMA). The epoxy group present in GMA molecule is readily transformed into various functional groups that further serve as affinity enhancers, ensuring the usability of the membranes as pre-concentrators of selected agents in plasmonic sensors. To form GMA-based membranes we used a recently proposed method combining the traditional immersion precipitation with photopolymerization and crosslinking of functional monomers. Further functionalization is obtained by in-situ formation of noble metal nanoparticles directly within the GMA host. In this way membranes with simultaneous plasmonic, adsorbent and catalytic functionality are obtained. We considered the use of the our structures for plasmonic chemical sensors where separator, pre-concentrator and binding agent are integrated with the plasmonic crystal, as well as for plasmonic enhancement of photocatalytic reactions in microreactors. Our approach gives a highly tailorable element compatible with microelectromechanical systems (MEMS) technologies and readily transferable across platforms. PB - Cambrridge, MA : The Electromagnetics Academy C3 - Progress in Electromagnetics Research Symposium, PIERS 2013, 12-15 August 2013, Stockholm, Sweden T1 - Multifunctionalized Self-supported (Nano) Membranes as Integrated Platform for Plasmonic Metamaterials SP - 1016 EP - 1020 UR - https://hdl.handle.net/21.15107/rcub_dais_783 ER -
@conference{ author = "Jakšić, Zoran and Radovanović, Filip and Nastasović, Aleksandra and Matović, Jovan", year = "2013", abstract = "We considered the possibility to fabricate multifunctional nanocomposite membranes as a platform for plasmonic metamaterials, simultaneously incorporating pores, built-in functional groups and active nanoparticles. To this purpose we combined lamination and inclusion of nanofillers into the membrane host. For the basic material we chose macroporous crosslinked copolymers based on glycidyl methacrylate (GMA). The epoxy group present in GMA molecule is readily transformed into various functional groups that further serve as affinity enhancers, ensuring the usability of the membranes as pre-concentrators of selected agents in plasmonic sensors. To form GMA-based membranes we used a recently proposed method combining the traditional immersion precipitation with photopolymerization and crosslinking of functional monomers. Further functionalization is obtained by in-situ formation of noble metal nanoparticles directly within the GMA host. In this way membranes with simultaneous plasmonic, adsorbent and catalytic functionality are obtained. We considered the use of the our structures for plasmonic chemical sensors where separator, pre-concentrator and binding agent are integrated with the plasmonic crystal, as well as for plasmonic enhancement of photocatalytic reactions in microreactors. Our approach gives a highly tailorable element compatible with microelectromechanical systems (MEMS) technologies and readily transferable across platforms.", publisher = "Cambrridge, MA : The Electromagnetics Academy", journal = "Progress in Electromagnetics Research Symposium, PIERS 2013, 12-15 August 2013, Stockholm, Sweden", title = "Multifunctionalized Self-supported (Nano) Membranes as Integrated Platform for Plasmonic Metamaterials", pages = "1016-1020", url = "https://hdl.handle.net/21.15107/rcub_dais_783" }
Jakšić, Z., Radovanović, F., Nastasović, A.,& Matović, J.. (2013). Multifunctionalized Self-supported (Nano) Membranes as Integrated Platform for Plasmonic Metamaterials. in Progress in Electromagnetics Research Symposium, PIERS 2013, 12-15 August 2013, Stockholm, Sweden Cambrridge, MA : The Electromagnetics Academy., 1016-1020. https://hdl.handle.net/21.15107/rcub_dais_783
Jakšić Z, Radovanović F, Nastasović A, Matović J. Multifunctionalized Self-supported (Nano) Membranes as Integrated Platform for Plasmonic Metamaterials. in Progress in Electromagnetics Research Symposium, PIERS 2013, 12-15 August 2013, Stockholm, Sweden. 2013;:1016-1020. https://hdl.handle.net/21.15107/rcub_dais_783 .
Jakšić, Zoran, Radovanović, Filip, Nastasović, Aleksandra, Matović, Jovan, "Multifunctionalized Self-supported (Nano) Membranes as Integrated Platform for Plasmonic Metamaterials" in Progress in Electromagnetics Research Symposium, PIERS 2013, 12-15 August 2013, Stockholm, Sweden (2013):1016-1020, https://hdl.handle.net/21.15107/rcub_dais_783 .