Novel membrane-supported hydrogel for removal of heavy metals
Authorized Users Only
2015
Authors
Stajčić, AleksandarNastasović, Aleksandra
Stajić-Trošić, Jasna
Marković, Jelena
Onjia, Antonije
Radovanović, Filip
Article (Published version)
Metadata
Show full item recordAbstract
Polyethersulfone membranes with integrated negatively-charged hydrogel of crosslinked poly(acrylamido-2-methylpropane sulfonic acid) were prepared by a combination of a liquid phase inversion process with photopolymerization and crosslinking of functional monomers included in the casting solution. A designed experiment was conducted to select the optimal composition for preparing membranes with a sufficient degree of swelling and ion exchange capacity. Scanning electron microscopy images revealed an ultrafine hybrid structure with an interconnected network of submicron particles embedded within the microporous polyethersulfone support. An intramembrane diffusion model was used to describe kinetics of heavy metal sorption by these hydrogels and the calculated apparent diffusion coefficients were 2–3 times larger than in commercial ion-exchange resins. Equilibrium sorption of heavy metals was described using a semi-empirical Langmuir model.
Keywords:
Membrane formation / Photoirradiation / Hydrogel / Heavy metal removalSource:
Journal of Environmental Chemical Engineering, 2015, 3, 1, 453-461Publisher:
- Elsevier
Funding / projects:
- Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43009)
- Micro- Nanosystems and Sensors for Electric Power and Process Industry and Environmental Protection (RS-MESTD-Technological Development (TD or TR)-32008)
DOI: 10.1016/j.jece.2015.01.005
ISSN: 2213-3437 (Print); 2213-2929 (Online)
WoS: 000217976100054
Scopus: 2-s2.0-84961290325
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Stajčić, Aleksandar AU - Nastasović, Aleksandra AU - Stajić-Trošić, Jasna AU - Marković, Jelena AU - Onjia, Antonije AU - Radovanović, Filip PY - 2015 UR - https://dais.sanu.ac.rs/123456789/774 AB - Polyethersulfone membranes with integrated negatively-charged hydrogel of crosslinked poly(acrylamido-2-methylpropane sulfonic acid) were prepared by a combination of a liquid phase inversion process with photopolymerization and crosslinking of functional monomers included in the casting solution. A designed experiment was conducted to select the optimal composition for preparing membranes with a sufficient degree of swelling and ion exchange capacity. Scanning electron microscopy images revealed an ultrafine hybrid structure with an interconnected network of submicron particles embedded within the microporous polyethersulfone support. An intramembrane diffusion model was used to describe kinetics of heavy metal sorption by these hydrogels and the calculated apparent diffusion coefficients were 2–3 times larger than in commercial ion-exchange resins. Equilibrium sorption of heavy metals was described using a semi-empirical Langmuir model. PB - Elsevier T2 - Journal of Environmental Chemical Engineering T1 - Novel membrane-supported hydrogel for removal of heavy metals SP - 453 EP - 461 VL - 3 IS - 1 DO - 10.1016/j.jece.2015.01.005 UR - https://hdl.handle.net/21.15107/rcub_dais_774 ER -
@article{ author = "Stajčić, Aleksandar and Nastasović, Aleksandra and Stajić-Trošić, Jasna and Marković, Jelena and Onjia, Antonije and Radovanović, Filip", year = "2015", abstract = "Polyethersulfone membranes with integrated negatively-charged hydrogel of crosslinked poly(acrylamido-2-methylpropane sulfonic acid) were prepared by a combination of a liquid phase inversion process with photopolymerization and crosslinking of functional monomers included in the casting solution. A designed experiment was conducted to select the optimal composition for preparing membranes with a sufficient degree of swelling and ion exchange capacity. Scanning electron microscopy images revealed an ultrafine hybrid structure with an interconnected network of submicron particles embedded within the microporous polyethersulfone support. An intramembrane diffusion model was used to describe kinetics of heavy metal sorption by these hydrogels and the calculated apparent diffusion coefficients were 2–3 times larger than in commercial ion-exchange resins. Equilibrium sorption of heavy metals was described using a semi-empirical Langmuir model.", publisher = "Elsevier", journal = "Journal of Environmental Chemical Engineering", title = "Novel membrane-supported hydrogel for removal of heavy metals", pages = "453-461", volume = "3", number = "1", doi = "10.1016/j.jece.2015.01.005", url = "https://hdl.handle.net/21.15107/rcub_dais_774" }
Stajčić, A., Nastasović, A., Stajić-Trošić, J., Marković, J., Onjia, A.,& Radovanović, F.. (2015). Novel membrane-supported hydrogel for removal of heavy metals. in Journal of Environmental Chemical Engineering Elsevier., 3(1), 453-461. https://doi.org/10.1016/j.jece.2015.01.005 https://hdl.handle.net/21.15107/rcub_dais_774
Stajčić A, Nastasović A, Stajić-Trošić J, Marković J, Onjia A, Radovanović F. Novel membrane-supported hydrogel for removal of heavy metals. in Journal of Environmental Chemical Engineering. 2015;3(1):453-461. doi:10.1016/j.jece.2015.01.005 https://hdl.handle.net/21.15107/rcub_dais_774 .
Stajčić, Aleksandar, Nastasović, Aleksandra, Stajić-Trošić, Jasna, Marković, Jelena, Onjia, Antonije, Radovanović, Filip, "Novel membrane-supported hydrogel for removal of heavy metals" in Journal of Environmental Chemical Engineering, 3, no. 1 (2015):453-461, https://doi.org/10.1016/j.jece.2015.01.005 ., https://hdl.handle.net/21.15107/rcub_dais_774 .