Приказ основних података о документу
Structural and electrochemical properties of gamma LiV2O5 cathode
dc.creator | Milović, Miloš | |
dc.creator | Vujković, Milica | |
dc.creator | Jugović, Dragana | |
dc.creator | Mitrić, Miodrag | |
dc.date.accessioned | 2021-10-11T10:55:02Z | |
dc.date.available | 2021-10-11T10:55:02Z | |
dc.date.issued | 2021 | |
dc.identifier.isbn | 978-86-915627-8-6 | |
dc.identifier.uri | https://dais.sanu.ac.rs/123456789/11896 | |
dc.description.abstract | For its capability to reversibly remove and insert lithium ions in the range of 0 ≤ x ≤ 1.4, gamma polymorph phase of LixV2O5 makes a solid candidate for cathode application in rechargeable batteries. Accommodation of lithium in concentrations higher than x ≈1.4 brings stability issues related to the transformation towards the metastable ζ phase, which significantly limits utilization of higher capacities the material could achieve. The presented investigation has been conducted on γ-LiV2O5 powder obtained via solid state reaction at high temperatures. Structural refinement of the prepared γ phase has been carried out. Based on bond valence analysis of γ as well as of metastable γ’ and ζ phase, which occur at low and high lithium concentrations, respectively, mechanism is proposed for the observed capacity decrease. Electrochemical characteristics of γ-LiV2O5 were investigated in both aqueous and organic electrolyte in the voltage range 4-2.3 V vs. Li+/Li in order to record performances of all three occurring phases, γ and both lithium poor γ’ (high voltage region) and lithium rich ζ (low voltage region). Ionic exchange of Li+ with Mg2+, Ca2+ and Al3+ in their respective aqueous electrolytes has been conducted to examine potential use of the material in the postlithium rechargeable batteries. | sr |
dc.language.iso | en | sr |
dc.publisher | Belgrade : Serbian Ceramic Society | sr |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200175/RS// | sr |
dc.rights | openAccess | sr |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.source | Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021 | sr |
dc.subject | LiV2O5 | sr |
dc.subject | rechargeable batteries | sr |
dc.subject | Li-ion batteries | sr |
dc.subject | solid-state reaction | sr |
dc.subject | cathode materials | sr |
dc.title | Structural and electrochemical properties of gamma LiV2O5 cathode | sr |
dc.type | conferenceObject | sr |
dc.rights.license | BY | sr |
dcterms.abstract | Миловић, Милош; Вујковић, Милица; Југовић, Драгана; Митрић, Миодраг; Струцтурал анд елецтроцхемицал пропертиес оф гамма ЛиВ2О5 цатходе; Струцтурал анд елецтроцхемицал пропертиес оф гамма ЛиВ2О5 цатходе; | |
dc.citation.spage | 84 | |
dc.citation.epage | 84 | |
dc.type.version | publishedVersion | sr |
dc.identifier.fulltext | https://dais.sanu.ac.rs/bitstream/id/47402/Milovic_ACA-IX-2021.pdf | |
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_dais_11896 |