The influence of fluorine doping on the structural and the electrical properties of LiFePO4 powder

2016
Authors
Jugović, Dragana
Mitrić, Miodrag

Milović, Miloš

Cvjetićanin, Nikola
Jokić, Bojan
Umićević, Ana

Uskoković, Dragan

Conference object (Published version)
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Low intrinsic electronic conductivity is the main weakness of LiFePO4 for the use as cathode material in lithium ion batteries. Here is presented an experimental proof of the theoretical prediction that fluorine doping of LiFePO4 can enhance its electrical conductivity. LiFePO4 and fluorine-doped LiFePO4 olivine type, carbon-free powders are synthesized and examined. Crystal structure refinements in the space group Pnma reveal that doping with fluorine ions preserves olivine structure with the reduction of both the lattice parameters and the antisite defect, and an increase of a crystallite size. A small amount of incorporated fluorine enhances electrical conductivity from 4.6 × 10-7 Scm-1 to 2.3 × 10-6 Scm-1 and has positive impact on the electrochemical performances. Several spectroscopy techniques (Mössbauer, FTIR, and Raman) disclose differences between two powders and additionally support the findings of both the Rietveld refinement and the conductivity measurements.
Keywords:
LiFePO4 / fluorine doping / magnetic propertiesSource:
Programme and The Book of Abstracts / Eighteenth Annual Conference YUCOMAT 2016, Herceg Novi, September 5-10, 2016, 2016, 35-35Publisher:
- Belgrade : Materials Research Society of Serbia
Projects:
- Molecular designing of nanoparticles with controlled morphological and physicochemical characteristics and functional materials based on them (RS-45004)
- Lithium-ion batteries and fuel cells - research and development (RS-45014)
TY - CONF AU - Jugović, Dragana AU - Mitrić, Miodrag AU - Milović, Miloš AU - Cvjetićanin, Nikola AU - Jokić, Bojan AU - Umićević, Ana AU - Uskoković, Dragan PY - 2016 UR - http://dais.sanu.ac.rs/123456789/898 AB - Low intrinsic electronic conductivity is the main weakness of LiFePO4 for the use as cathode material in lithium ion batteries. Here is presented an experimental proof of the theoretical prediction that fluorine doping of LiFePO4 can enhance its electrical conductivity. LiFePO4 and fluorine-doped LiFePO4 olivine type, carbon-free powders are synthesized and examined. Crystal structure refinements in the space group Pnma reveal that doping with fluorine ions preserves olivine structure with the reduction of both the lattice parameters and the antisite defect, and an increase of a crystallite size. A small amount of incorporated fluorine enhances electrical conductivity from 4.6 × 10-7 Scm-1 to 2.3 × 10-6 Scm-1 and has positive impact on the electrochemical performances. Several spectroscopy techniques (Mössbauer, FTIR, and Raman) disclose differences between two powders and additionally support the findings of both the Rietveld refinement and the conductivity measurements. PB - Belgrade : Materials Research Society of Serbia C3 - Programme and The Book of Abstracts / Eighteenth Annual Conference YUCOMAT 2016, Herceg Novi, September 5-10, 2016 T1 - The influence of fluorine doping on the structural and the electrical properties of LiFePO4 powder SP - 35 EP - 35 ER -
@conference{ author = "Jugović, Dragana and Mitrić, Miodrag and Milović, Miloš and Cvjetićanin, Nikola and Jokić, Bojan and Umićević, Ana and Uskoković, Dragan", year = "2016", url = "http://dais.sanu.ac.rs/123456789/898", abstract = "Low intrinsic electronic conductivity is the main weakness of LiFePO4 for the use as cathode material in lithium ion batteries. Here is presented an experimental proof of the theoretical prediction that fluorine doping of LiFePO4 can enhance its electrical conductivity. LiFePO4 and fluorine-doped LiFePO4 olivine type, carbon-free powders are synthesized and examined. Crystal structure refinements in the space group Pnma reveal that doping with fluorine ions preserves olivine structure with the reduction of both the lattice parameters and the antisite defect, and an increase of a crystallite size. A small amount of incorporated fluorine enhances electrical conductivity from 4.6 × 10-7 Scm-1 to 2.3 × 10-6 Scm-1 and has positive impact on the electrochemical performances. Several spectroscopy techniques (Mössbauer, FTIR, and Raman) disclose differences between two powders and additionally support the findings of both the Rietveld refinement and the conductivity measurements.", publisher = "Belgrade : Materials Research Society of Serbia", journal = "Programme and The Book of Abstracts / Eighteenth Annual Conference YUCOMAT 2016, Herceg Novi, September 5-10, 2016", title = "The influence of fluorine doping on the structural and the electrical properties of LiFePO4 powder", pages = "35-35" }
Jugović D, Mitrić M, Milović M, Cvjetićanin N, Jokić B, Umićević A, Uskoković D. The influence of fluorine doping on the structural and the electrical properties of LiFePO4 powder. Programme and The Book of Abstracts / Eighteenth Annual Conference YUCOMAT 2016, Herceg Novi, September 5-10, 2016. 2016;:35-35
Jugović, D., Mitrić, M., Milović, M., Cvjetićanin, N., Jokić, B., Umićević, A.,& Uskoković, D. (2016). The influence of fluorine doping on the structural and the electrical properties of LiFePO4 powder. Programme and The Book of Abstracts / Eighteenth Annual Conference YUCOMAT 2016, Herceg Novi, September 5-10, 2016Belgrade : Materials Research Society of Serbia., null, 35-35.
Jugović Dragana, Mitrić Miodrag, Milović Miloš, Cvjetićanin Nikola, Jokić Bojan, Umićević Ana, Uskoković Dragan, "The influence of fluorine doping on the structural and the electrical properties of LiFePO4 powder" null (2016):35-35