Perovskite oxides with the composition LaFe1-xCrxO3 (x = 0.5 and 0.75) have been studied. The samples have been prepared using the mechanochemical treatment. A mixture of crystalline La(OH)3, Fe2O3 and Cr2O3 powders in stoichiometric ratio was mechanochemically treated in a planetary ball mill up to 40 h of milling. The mechanochemical formation of the LaFe1-xCrxO3 perovskite phase was followed by X-ray diffraction and magnetization measurements. The Rietveld refinement of the XRD data shows that the compounds crystallize in an orthorhombic perovskite structure with a random distribution of the Fe and Cr cations at the B sublattice. All structural and microstructural parameters were analyzed. In addition, magnetic measurements for LaFe0.5Cr0.5O3 show clear antiferromagnetic ordering bellow 250 K, which supports above conclusion of random distribution of Fe and Cr cations.
Keywords:
mechanochemistry / perovskite oxides / magnetic properties
Source:
Programme and The Book of Abstracts / Eighteenth Annual Conference YUCOMAT 2016, Herceg Novi, September 5-10, 2016, 2016, 57-57
TY - CONF
AU - Jugović, Dragana
AU - Bradarić, Ivica
AU - Jovalekić, Čedomir
AU - Barudžija, Tanja
AU - Kusigerski, Vladan
AU - Mitrić, Miodrag
PY - 2016
UR - https://dais.sanu.ac.rs/123456789/897
AB - Perovskite oxides with the composition LaFe1-xCrxO3 (x = 0.5 and 0.75) have been studied. The samples have been prepared using the mechanochemical treatment. A mixture of crystalline La(OH)3, Fe2O3 and Cr2O3 powders in stoichiometric ratio was mechanochemically treated in a planetary ball mill up to 40 h of milling. The mechanochemical formation of the LaFe1-xCrxO3 perovskite phase was followed by X-ray diffraction and magnetization measurements. The Rietveld refinement of the XRD data shows that the compounds crystallize in an orthorhombic perovskite structure with a random distribution of the Fe and Cr cations at the B sublattice. All structural and microstructural parameters were analyzed. In addition, magnetic measurements for LaFe0.5Cr0.5O3 show clear antiferromagnetic ordering bellow 250 K, which supports above conclusion of random distribution of Fe and Cr cations.
PB - Belgrade : Materials Research Society of Serbia
C3 - Programme and The Book of Abstracts / Eighteenth Annual Conference YUCOMAT 2016, Herceg Novi, September 5-10, 2016
T1 - Structural and magnetic properties of mechanochemically synthesized LaFe1-xCrxO3 (x = 0.5 and 0.75)
SP - 57
EP - 57
UR - https://hdl.handle.net/21.15107/rcub_dais_897
ER -
@conference{
author = "Jugović, Dragana and Bradarić, Ivica and Jovalekić, Čedomir and Barudžija, Tanja and Kusigerski, Vladan and Mitrić, Miodrag",
year = "2016",
abstract = "Perovskite oxides with the composition LaFe1-xCrxO3 (x = 0.5 and 0.75) have been studied. The samples have been prepared using the mechanochemical treatment. A mixture of crystalline La(OH)3, Fe2O3 and Cr2O3 powders in stoichiometric ratio was mechanochemically treated in a planetary ball mill up to 40 h of milling. The mechanochemical formation of the LaFe1-xCrxO3 perovskite phase was followed by X-ray diffraction and magnetization measurements. The Rietveld refinement of the XRD data shows that the compounds crystallize in an orthorhombic perovskite structure with a random distribution of the Fe and Cr cations at the B sublattice. All structural and microstructural parameters were analyzed. In addition, magnetic measurements for LaFe0.5Cr0.5O3 show clear antiferromagnetic ordering bellow 250 K, which supports above conclusion of random distribution of Fe and Cr cations.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of Abstracts / Eighteenth Annual Conference YUCOMAT 2016, Herceg Novi, September 5-10, 2016",
title = "Structural and magnetic properties of mechanochemically synthesized LaFe1-xCrxO3 (x = 0.5 and 0.75)",
pages = "57-57",
url = "https://hdl.handle.net/21.15107/rcub_dais_897"
}
Jugović, D., Bradarić, I., Jovalekić, Č., Barudžija, T., Kusigerski, V.,& Mitrić, M.. (2016). Structural and magnetic properties of mechanochemically synthesized LaFe1-xCrxO3 (x = 0.5 and 0.75). in Programme and The Book of Abstracts / Eighteenth Annual Conference YUCOMAT 2016, Herceg Novi, September 5-10, 2016
Belgrade : Materials Research Society of Serbia., 57-57.
https://hdl.handle.net/21.15107/rcub_dais_897
Jugović D, Bradarić I, Jovalekić Č, Barudžija T, Kusigerski V, Mitrić M. Structural and magnetic properties of mechanochemically synthesized LaFe1-xCrxO3 (x = 0.5 and 0.75). in Programme and The Book of Abstracts / Eighteenth Annual Conference YUCOMAT 2016, Herceg Novi, September 5-10, 2016. 2016;:57-57.
https://hdl.handle.net/21.15107/rcub_dais_897 .
Jugović, Dragana, Bradarić, Ivica, Jovalekić, Čedomir, Barudžija, Tanja, Kusigerski, Vladan, Mitrić, Miodrag, "Structural and magnetic properties of mechanochemically synthesized LaFe1-xCrxO3 (x = 0.5 and 0.75)" in Programme and The Book of Abstracts / Eighteenth Annual Conference YUCOMAT 2016, Herceg Novi, September 5-10, 2016 (2016):57-57,
https://hdl.handle.net/21.15107/rcub_dais_897 .
