The influence of different milling conditions obtained using two high-energy mills on hydrogen desorption from MgH2-WO3 composites was investigated. The morphology, particle and crystallite size were studied as a function of milling speed, vial's volume, and ball-to-powder ratio. The vial's fill level, the number, and type of milling balls and additive's content kept constant. Changes in morphology and microstructure were correlated to desorption properties of materials. Higher milling speed reduced particle size but, there is no significant crystallite size reduction. On the other hand, additive distribution is similar regardless of the energy input. It has been noticed that different energy input on milling blend, which is the result of combined effects of above-mentioned factors, reflects on desorption temperature but not on the kinetics of desorption. In fact, desorption mechanism changes from 2D to 3D growth with constant nucleation rate, despite obtained changes in microstructure... or chemical composition of the material.
TY - JOUR
AU - Pantić, Tijana
AU - Milanović, Igor
AU - Lukić, Miodrag J.
AU - Grbović Novaković, Jasmina
AU - Kurko, Sandra
AU - Biliškov, Nikola
AU - Milošević Govedarović, Sanja
PY - 2020
UR - http://www.sciencedirect.com/science/article/pii/S0360319919327685
UR - http://dais.sanu.ac.rs/123456789/8963
AB - The influence of different milling conditions obtained using two high-energy mills on hydrogen desorption from MgH2-WO3 composites was investigated. The morphology, particle and crystallite size were studied as a function of milling speed, vial's volume, and ball-to-powder ratio. The vial's fill level, the number, and type of milling balls and additive's content kept constant. Changes in morphology and microstructure were correlated to desorption properties of materials. Higher milling speed reduced particle size but, there is no significant crystallite size reduction. On the other hand, additive distribution is similar regardless of the energy input. It has been noticed that different energy input on milling blend, which is the result of combined effects of above-mentioned factors, reflects on desorption temperature but not on the kinetics of desorption. In fact, desorption mechanism changes from 2D to 3D growth with constant nucleation rate, despite obtained changes in microstructure or chemical composition of the material.
PB - Elsevier
T2 - International Journal of Hydrogen Energy
T1 - The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites
SP - 7901
EP - 7911
VL - 45
IS - 14
DO - 10.1016/j.ijhydene.2019.07.167
ER -
@article{
author = "Pantić, Tijana and Milanović, Igor and Lukić, Miodrag J. and Grbović Novaković, Jasmina and Kurko, Sandra and Biliškov, Nikola and Milošević Govedarović, Sanja",
year = "2020",
url = "http://www.sciencedirect.com/science/article/pii/S0360319919327685, http://dais.sanu.ac.rs/123456789/8963",
abstract = "The influence of different milling conditions obtained using two high-energy mills on hydrogen desorption from MgH2-WO3 composites was investigated. The morphology, particle and crystallite size were studied as a function of milling speed, vial's volume, and ball-to-powder ratio. The vial's fill level, the number, and type of milling balls and additive's content kept constant. Changes in morphology and microstructure were correlated to desorption properties of materials. Higher milling speed reduced particle size but, there is no significant crystallite size reduction. On the other hand, additive distribution is similar regardless of the energy input. It has been noticed that different energy input on milling blend, which is the result of combined effects of above-mentioned factors, reflects on desorption temperature but not on the kinetics of desorption. In fact, desorption mechanism changes from 2D to 3D growth with constant nucleation rate, despite obtained changes in microstructure or chemical composition of the material.",
publisher = "Elsevier",
journal = "International Journal of Hydrogen Energy",
title = "The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites",
pages = "7901-7911",
volume = "45",
number = "14",
doi = "10.1016/j.ijhydene.2019.07.167"
}
Pantić T, Milanović I, Lukić MJ, Grbović Novaković J, Kurko S, Biliškov N, Milošević Govedarović S. The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites. International Journal of Hydrogen Energy. 2020;45(14):7901-7911
Pantić, T., Milanović, I., Lukić, M. J., Grbović Novaković, J., Kurko, S., Biliškov, N.,& Milošević Govedarović, S. (2020). The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites.
International Journal of Hydrogen EnergyElsevier., 45(14), 7901-7911.
https://doi.org/10.1016/j.ijhydene.2019.07.167
Pantić Tijana, Milanović Igor, Lukić Miodrag J., Grbović Novaković Jasmina, Kurko Sandra, Biliškov Nikola, Milošević Govedarović Sanja, "The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites" 45, no. 14 (2020):7901-7911,
https://doi.org/10.1016/j.ijhydene.2019.07.167 .
