1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study
Само за регистроване кориснике
2020
Аутори
Ristić, PredragTodorović, Tamara R.
Blagojević, Vladimir
Klisurić, Olivera R.
Marjanović, Ivana
Holló, Berta Barta
Vulić, Predrag
Gulea, Mihaela
Donnard, Morgan
Monge, Miguel
Rodríguez-Castillo, María
López-de-Luzuriaga, José M.
Filipović, Nenad R.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Four silver-based coordination polymers, {[Ag(L)2](BF4)}∞ (1), {[Ag(H2BTC)(L)]·(H3BTC)}∞ (2), {[Ag2(H2BTEC)(L)2]·3.33H2O}∞ (3), and [Ag(H25SSA)(L)]∞ (4), were synthesized using thiomorpholine-4-carbonitrile (L) as the primary ligand and three aromatic polyoxoacids as coligands: trimesic (H3BTC), pyromellitic (H4BTEC), and 5-sulfosalicylic acid (H35SSA). Compounds 1 and 3 are two-dimensional, while 2 and 4 are one-dimensional. L acts as a bis-monodentate ligand, while the Ag(I) ion is three-coordinated in 2 and four-coordinated in all of the other compounds. The tetrahedral coordination of Ag(I) in 3 leads to an almost complete absence of intermolecular interactions with the metal center. All compounds show reasonable photocatalytic activity for photocatalytic degradation of mordant blue 9 dye, with reaction rates in the 0.036–0.056 min–1 range. Changes in the reaction rates can be correlated with the type and coordination of the coligand. Complex 3 exhibits photoluminescence at 77 K, w...hile 4 exhibits photoluminescence at both room temperature and 77 K. Luminescence lifetimes indicate electronic transitions of singlet parentage, where transitions are allowed. A TD-DFT study determined the contributions of individual singlet–singlet electronic excitations to the fluorescence, indicating that metal– intraligand transitions are responsible for luminescence in both complexes.
Кључне речи:
coordination polymers / photocatalysis / photoluminescence / TD-DFT / ligandsИзвор:
Crystal Growth & Design, 2020, 20, 7, 4461-4478Издавач:
- American Chemical Society
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200116 (Универзитет у Београду, Пољопривредни факултет) (RS-200116)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200161 (Универзитет у Београду, Фармацеутски факултет) (RS-200161)
- D.G.I.(MEC)/FEDER (CTQ2016-75816-C02-02-P)
Напомена:
- Peer-reviewed manuscript: https://hdl.handle.net/21.15107/rcub_dais_8956
- Supplementary material: https://hdl.handle.net/21.15107/rcub_dais_9452
Повезане информације:
- Друга верзија
https://hdl.handle.net/21.15107/rcub_dais_8956 - Повезани садржај
https://hdl.handle.net/21.15107/rcub_dais_9452
DOI: 10.1021/acs.cgd.0c00287
ISSN: 1528-7483
WoS: 000546699900029
Scopus: 2-s2.0-85087637395
Институција/група
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Ristić, Predrag AU - Todorović, Tamara R. AU - Blagojević, Vladimir AU - Klisurić, Olivera R. AU - Marjanović, Ivana AU - Holló, Berta Barta AU - Vulić, Predrag AU - Gulea, Mihaela AU - Donnard, Morgan AU - Monge, Miguel AU - Rodríguez-Castillo, María AU - López-de-Luzuriaga, José M. AU - Filipović, Nenad R. PY - 2020 UR - https://dais.sanu.ac.rs/123456789/8960 AB - Four silver-based coordination polymers, {[Ag(L)2](BF4)}∞ (1), {[Ag(H2BTC)(L)]·(H3BTC)}∞ (2), {[Ag2(H2BTEC)(L)2]·3.33H2O}∞ (3), and [Ag(H25SSA)(L)]∞ (4), were synthesized using thiomorpholine-4-carbonitrile (L) as the primary ligand and three aromatic polyoxoacids as coligands: trimesic (H3BTC), pyromellitic (H4BTEC), and 5-sulfosalicylic acid (H35SSA). Compounds 1 and 3 are two-dimensional, while 2 and 4 are one-dimensional. L acts as a bis-monodentate ligand, while the Ag(I) ion is three-coordinated in 2 and four-coordinated in all of the other compounds. The tetrahedral coordination of Ag(I) in 3 leads to an almost complete absence of intermolecular interactions with the metal center. All compounds show reasonable photocatalytic activity for photocatalytic degradation of mordant blue 9 dye, with reaction rates in the 0.036–0.056 min–1 range. Changes in the reaction rates can be correlated with the type and coordination of the coligand. Complex 3 exhibits photoluminescence at 77 K, while 4 exhibits photoluminescence at both room temperature and 77 K. Luminescence lifetimes indicate electronic transitions of singlet parentage, where transitions are allowed. A TD-DFT study determined the contributions of individual singlet–singlet electronic excitations to the fluorescence, indicating that metal– intraligand transitions are responsible for luminescence in both complexes. PB - American Chemical Society T2 - Crystal Growth & Design T1 - 1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study SP - 4461 EP - 4478 VL - 20 IS - 7 DO - 10.1021/acs.cgd.0c00287 UR - https://hdl.handle.net/21.15107/rcub_dais_8960 ER -
@article{ author = "Ristić, Predrag and Todorović, Tamara R. and Blagojević, Vladimir and Klisurić, Olivera R. and Marjanović, Ivana and Holló, Berta Barta and Vulić, Predrag and Gulea, Mihaela and Donnard, Morgan and Monge, Miguel and Rodríguez-Castillo, María and López-de-Luzuriaga, José M. and Filipović, Nenad R.", year = "2020", abstract = "Four silver-based coordination polymers, {[Ag(L)2](BF4)}∞ (1), {[Ag(H2BTC)(L)]·(H3BTC)}∞ (2), {[Ag2(H2BTEC)(L)2]·3.33H2O}∞ (3), and [Ag(H25SSA)(L)]∞ (4), were synthesized using thiomorpholine-4-carbonitrile (L) as the primary ligand and three aromatic polyoxoacids as coligands: trimesic (H3BTC), pyromellitic (H4BTEC), and 5-sulfosalicylic acid (H35SSA). Compounds 1 and 3 are two-dimensional, while 2 and 4 are one-dimensional. L acts as a bis-monodentate ligand, while the Ag(I) ion is three-coordinated in 2 and four-coordinated in all of the other compounds. The tetrahedral coordination of Ag(I) in 3 leads to an almost complete absence of intermolecular interactions with the metal center. All compounds show reasonable photocatalytic activity for photocatalytic degradation of mordant blue 9 dye, with reaction rates in the 0.036–0.056 min–1 range. Changes in the reaction rates can be correlated with the type and coordination of the coligand. Complex 3 exhibits photoluminescence at 77 K, while 4 exhibits photoluminescence at both room temperature and 77 K. Luminescence lifetimes indicate electronic transitions of singlet parentage, where transitions are allowed. A TD-DFT study determined the contributions of individual singlet–singlet electronic excitations to the fluorescence, indicating that metal– intraligand transitions are responsible for luminescence in both complexes.", publisher = "American Chemical Society", journal = "Crystal Growth & Design", title = "1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study", pages = "4461-4478", volume = "20", number = "7", doi = "10.1021/acs.cgd.0c00287", url = "https://hdl.handle.net/21.15107/rcub_dais_8960" }
Ristić, P., Todorović, T. R., Blagojević, V., Klisurić, O. R., Marjanović, I., Holló, B. B., Vulić, P., Gulea, M., Donnard, M., Monge, M., Rodríguez-Castillo, M., López-de-Luzuriaga, J. M.,& Filipović, N. R.. (2020). 1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study. in Crystal Growth & Design American Chemical Society., 20(7), 4461-4478. https://doi.org/10.1021/acs.cgd.0c00287 https://hdl.handle.net/21.15107/rcub_dais_8960
Ristić P, Todorović TR, Blagojević V, Klisurić OR, Marjanović I, Holló BB, Vulić P, Gulea M, Donnard M, Monge M, Rodríguez-Castillo M, López-de-Luzuriaga JM, Filipović NR. 1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study. in Crystal Growth & Design. 2020;20(7):4461-4478. doi:10.1021/acs.cgd.0c00287 https://hdl.handle.net/21.15107/rcub_dais_8960 .
Ristić, Predrag, Todorović, Tamara R., Blagojević, Vladimir, Klisurić, Olivera R., Marjanović, Ivana, Holló, Berta Barta, Vulić, Predrag, Gulea, Mihaela, Donnard, Morgan, Monge, Miguel, Rodríguez-Castillo, María, López-de-Luzuriaga, José M., Filipović, Nenad R., "1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study" in Crystal Growth & Design, 20, no. 7 (2020):4461-4478, https://doi.org/10.1021/acs.cgd.0c00287 ., https://hdl.handle.net/21.15107/rcub_dais_8960 .