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Adsorption capacity of wollastonite based adsorbents with porous structure controlled with different progeny agents

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2016
874.pdf (9.046Mb)
Authors
Rusmirović, Jelena
Marinković, Aleksandar
Obradović, Nina
Filipović, Suzana
Pavlović, Vladimir B.
Conference object (Published version)
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Abstract
Porous wollastonite (WL) based adsorbents were fabricated by a pressureless sintering process by using low molecular weight poly(methyl methacrylate) (PMMA), nanocellulose (NC) and yeast as the pore forming agents. WL based adsorbents were synthesized in two step process. In the first step, calcium carbonate and methylhidrogen cyclosiloxane were mixed with isopropyl alcohol, dried and calcined at 250 °C. Second step included WL mixing with porogen, followed by controlled calcination and on that way the sintered materials with randomly distributed pores were obtained. The effectiveness of the synthesis steps as well as material properties, i.e., the pore morphology were determined by FTIR analysis and scanning electron microscopy (SEM), respectively. The pore morphology and adsorption capacity was changed dramatically by changing the pore forming agent. The highest adsorption capacity was obtained when NC was used as the pore forming agent. Obtained materials showed moderate adsorption ...capacities of 10.56, 8.42 and 11.33 mg/g with respect to As5+, Cr6+ and phosphate, respectively. The con centrations of heavy metal ions were determined by using Ion chromatography coupled with mass spectrometry (ICP-MS).

Keywords:
wollastonite-based adsorbents / sintering / porous materials
Source:
Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade, 2016, 62-63
Publisher:
  • Belgrade : Serbian Ceramic Society
Projects:
  • Directed synthesis, structure and properties of multifunctional materials (RS-172057)

ISBN: 978-86-915627-4-8

[ Google Scholar ]
URI
http://dais.sanu.ac.rs/123456789/877
Collections
  • ITN SANU - Opšta kolekcija / ITS SASA - General collection
Institution
Институт техничких наука САНУ / Institute of Technical Sciences of SASA
TY  - CONF
AU  - Rusmirović, Jelena
AU  - Marinković, Aleksandar
AU  - Obradović, Nina
AU  - Filipović, Suzana
AU  - Pavlović, Vladimir B.
PY  - 2016
UR  - http://dais.sanu.ac.rs/123456789/877
AB  - Porous wollastonite (WL) based adsorbents were fabricated by a pressureless sintering process by using low molecular weight poly(methyl methacrylate) (PMMA), nanocellulose (NC) and yeast as the pore forming agents. WL based adsorbents were synthesized in two step process. In the first step, calcium carbonate and methylhidrogen cyclosiloxane were mixed with isopropyl alcohol, dried and calcined at 250 °C. Second step included WL mixing with porogen, followed by controlled calcination and on that way the sintered materials with randomly distributed pores were obtained. The effectiveness of the synthesis steps as well as material properties, i.e., the pore morphology were determined by FTIR analysis and scanning electron microscopy (SEM), respectively. The pore morphology and adsorption capacity was changed dramatically by changing the pore forming agent. The highest adsorption capacity was obtained when NC was used as the pore forming agent. Obtained materials showed moderate adsorption capacities of 10.56, 8.42 and 11.33 mg/g with respect to As5+, Cr6+ and phosphate, respectively. The con centrations of heavy metal ions were determined by using Ion chromatography coupled with mass spectrometry (ICP-MS).
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade
T1  - Adsorption capacity of wollastonite based adsorbents with porous structure controlled with different progeny agents
SP  - 62
EP  - 63
ER  - 
@conference{
author = "Rusmirović, Jelena and Marinković, Aleksandar and Obradović, Nina and Filipović, Suzana and Pavlović, Vladimir B.",
year = "2016",
url = "http://dais.sanu.ac.rs/123456789/877",
abstract = "Porous wollastonite (WL) based adsorbents were fabricated by a pressureless sintering process by using low molecular weight poly(methyl methacrylate) (PMMA), nanocellulose (NC) and yeast as the pore forming agents. WL based adsorbents were synthesized in two step process. In the first step, calcium carbonate and methylhidrogen cyclosiloxane were mixed with isopropyl alcohol, dried and calcined at 250 °C. Second step included WL mixing with porogen, followed by controlled calcination and on that way the sintered materials with randomly distributed pores were obtained. The effectiveness of the synthesis steps as well as material properties, i.e., the pore morphology were determined by FTIR analysis and scanning electron microscopy (SEM), respectively. The pore morphology and adsorption capacity was changed dramatically by changing the pore forming agent. The highest adsorption capacity was obtained when NC was used as the pore forming agent. Obtained materials showed moderate adsorption capacities of 10.56, 8.42 and 11.33 mg/g with respect to As5+, Cr6+ and phosphate, respectively. The con centrations of heavy metal ions were determined by using Ion chromatography coupled with mass spectrometry (ICP-MS).",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade",
title = "Adsorption capacity of wollastonite based adsorbents with porous structure controlled with different progeny agents",
pages = "62-63"
}
Rusmirović J, Marinković A, Obradović N, Filipović S, Pavlović VB. Adsorption capacity of wollastonite based adsorbents with porous structure controlled with different progeny agents. Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade. 2016;:62-63
Rusmirović, J., Marinković, A., Obradović, N., Filipović, S.,& Pavlović, V. B. (2016). Adsorption capacity of wollastonite based adsorbents with porous structure controlled with different progeny agents.
Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, BelgradeBelgrade : Serbian Ceramic Society., null, 62-63. 
Rusmirović Jelena, Marinković Aleksandar, Obradović Nina, Filipović Suzana, Pavlović Vladimir B., "Adsorption capacity of wollastonite based adsorbents with porous structure controlled with different progeny agents" null (2016):62-63

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