Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization
Authorized Users Only
2020
Authors
Dodevski, VladimirPagnacco, Maja C.

Radović, Ivana
Rosić, Milena

Janković, Bojan
Stojmenović, Marija

Mitić, Vojislav V.
Article (Published version)

Elsevier
Metadata
Show full item recordAbstract
The aim of this research was to obtain a carbon solid residue by the carbonization process of biomass in an inert atmosphere which, through physical activation and chemical treatment (using TEOS - tetraethyl orthosilicate) would allow creation of highly porous and spatially distinct ordered bio-SiC ceramics. The results of carbonization experiments at several operating temperatures and activation of carbons with multiple-cycle treatments TEOS clearly showed the possibility of obtaining SiC nano-structures, after performing the carbothermal reduction at 1400 °C. The increase in the activation temperature and the duration time starts the development of the SiC particles inside the porous structure. The XRPD analysis showed that the major SiC polytype has cubic SiC (β-SiC) structure and remainder is hexagonal SiC polytypic (α-SiC) structure. It was established that the carbons obtained from carbonization of the Platanus orientalis L. plane tree fruit (PTF) precursor and activated at 850 °...C with longer holding times (1 and 2 h) exhibit β-SiC (cubic) nano-wires. A possible nano-wires increment mechanism was suggested. The obtained results represent significant contribution in understanding the process as well as the main characteristics of SiC nano-materials and their possible applications.
Keywords:
Wood-fruit precursor / Silica impregnation / Graphitic material / Stacking faults / β-SiC nano-wiresSource:
Materials Chemistry and Physics, 2020, 245, 122768-Publisher:
- Elsevier
Funding / projects:
- Functional, Functionalized and Advanced Nanomaterials (RS-45005)
- Predefined functional properties polymer composite materials processes and equipment development (RS-34011)
- Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes (RS-45001)
DOI: 10.1016/j.matchemphys.2020.122768
ISSN: 0254-0584
WoS: 000523626300006
Scopus: 2-s2.0-85079085607
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Dodevski, Vladimir AU - Pagnacco, Maja C. AU - Radović, Ivana AU - Rosić, Milena AU - Janković, Bojan AU - Stojmenović, Marija AU - Mitić, Vojislav V. PY - 2020 UR - https://dais.sanu.ac.rs/123456789/8726 AB - The aim of this research was to obtain a carbon solid residue by the carbonization process of biomass in an inert atmosphere which, through physical activation and chemical treatment (using TEOS - tetraethyl orthosilicate) would allow creation of highly porous and spatially distinct ordered bio-SiC ceramics. The results of carbonization experiments at several operating temperatures and activation of carbons with multiple-cycle treatments TEOS clearly showed the possibility of obtaining SiC nano-structures, after performing the carbothermal reduction at 1400 °C. The increase in the activation temperature and the duration time starts the development of the SiC particles inside the porous structure. The XRPD analysis showed that the major SiC polytype has cubic SiC (β-SiC) structure and remainder is hexagonal SiC polytypic (α-SiC) structure. It was established that the carbons obtained from carbonization of the Platanus orientalis L. plane tree fruit (PTF) precursor and activated at 850 °C with longer holding times (1 and 2 h) exhibit β-SiC (cubic) nano-wires. A possible nano-wires increment mechanism was suggested. The obtained results represent significant contribution in understanding the process as well as the main characteristics of SiC nano-materials and their possible applications. PB - Elsevier T2 - Materials Chemistry and Physics T1 - Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization SP - 122768 VL - 245 DO - 10.1016/j.matchemphys.2020.122768 UR - https://hdl.handle.net/21.15107/rcub_dais_8726 ER -
@article{ author = "Dodevski, Vladimir and Pagnacco, Maja C. and Radović, Ivana and Rosić, Milena and Janković, Bojan and Stojmenović, Marija and Mitić, Vojislav V.", year = "2020", abstract = "The aim of this research was to obtain a carbon solid residue by the carbonization process of biomass in an inert atmosphere which, through physical activation and chemical treatment (using TEOS - tetraethyl orthosilicate) would allow creation of highly porous and spatially distinct ordered bio-SiC ceramics. The results of carbonization experiments at several operating temperatures and activation of carbons with multiple-cycle treatments TEOS clearly showed the possibility of obtaining SiC nano-structures, after performing the carbothermal reduction at 1400 °C. The increase in the activation temperature and the duration time starts the development of the SiC particles inside the porous structure. The XRPD analysis showed that the major SiC polytype has cubic SiC (β-SiC) structure and remainder is hexagonal SiC polytypic (α-SiC) structure. It was established that the carbons obtained from carbonization of the Platanus orientalis L. plane tree fruit (PTF) precursor and activated at 850 °C with longer holding times (1 and 2 h) exhibit β-SiC (cubic) nano-wires. A possible nano-wires increment mechanism was suggested. The obtained results represent significant contribution in understanding the process as well as the main characteristics of SiC nano-materials and their possible applications.", publisher = "Elsevier", journal = "Materials Chemistry and Physics", title = "Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization", pages = "122768", volume = "245", doi = "10.1016/j.matchemphys.2020.122768", url = "https://hdl.handle.net/21.15107/rcub_dais_8726" }
Dodevski, V., Pagnacco, M. C., Radović, I., Rosić, M., Janković, B., Stojmenović, M.,& Mitić, V. V.. (2020). Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization. in Materials Chemistry and Physics Elsevier., 245, 122768. https://doi.org/10.1016/j.matchemphys.2020.122768 https://hdl.handle.net/21.15107/rcub_dais_8726
Dodevski V, Pagnacco MC, Radović I, Rosić M, Janković B, Stojmenović M, Mitić VV. Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization. in Materials Chemistry and Physics. 2020;245:122768. doi:10.1016/j.matchemphys.2020.122768 https://hdl.handle.net/21.15107/rcub_dais_8726 .
Dodevski, Vladimir, Pagnacco, Maja C., Radović, Ivana, Rosić, Milena, Janković, Bojan, Stojmenović, Marija, Mitić, Vojislav V., "Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization" in Materials Chemistry and Physics, 245 (2020):122768, https://doi.org/10.1016/j.matchemphys.2020.122768 ., https://hdl.handle.net/21.15107/rcub_dais_8726 .