Several monomers and crosslinker in a broad range of concentrations in water and 1-Methyl-2-pyrrolidone (NMP) respectively were screened for their mechanical properties, water uptake and conductivity by photo polymerization with a polar photo initiator in porous membranes made of polypropylene and polyethersulfone respectively. As conductive polymer, primarily poly(2-acrylamido-2-methylpropane sulfonic acid) (PAMPS) and poly(2-sulfoethyl methacrylate) (PSEM) respectively as well as polymers of phosphonic acid containing monomers or newly synthesized monomers were used. The conductive monomers were crosslinked with varying hydrophobic and hydrophilic multifunctional monomers like N,N'-methylene bisacrylamide (MBA), 2-Propenoic acid, 2-methyl-, 1,1'-(1,10-decanediyl) ester (D3MA) or polyethyleneglycol diacrylates with two varying chainlengths (PEG-DA700, PEG-DA330). Furthermore several new multifunctional crosslinker with enhanced thermal and ageing stability have been synthesized and te...sted.
The advantage of several different building blocks with known characteristics is the possibility to tune the polymer to special needs of an application. For example, some polymer compositions have good conductivity at lower temperatures whereas other polymers develop better properties at elevated temperatures.
TY - CONF
AU - Kellner, Michael
AU - Radovanović, Filip
AU - Matović, Jovan
AU - Liska, Robert
PY - 2011
UR - http://dais.sanu.ac.rs/123456789/780
AB - Several monomers and crosslinker in a broad range of concentrations in water and 1-Methyl-2-pyrrolidone (NMP) respectively were screened for their mechanical properties, water uptake and conductivity by photo polymerization with a polar photo initiator in porous membranes made of polypropylene and polyethersulfone respectively. As conductive polymer, primarily poly(2-acrylamido-2-methylpropane sulfonic acid) (PAMPS) and poly(2-sulfoethyl methacrylate) (PSEM) respectively as well as polymers of phosphonic acid containing monomers or newly synthesized monomers were used. The conductive monomers were crosslinked with varying hydrophobic and hydrophilic multifunctional monomers like N,N'-methylene bisacrylamide (MBA), 2-Propenoic acid, 2-methyl-, 1,1'-(1,10-decanediyl) ester (D3MA) or polyethyleneglycol diacrylates with two varying chainlengths (PEG-DA700, PEG-DA330). Furthermore several new multifunctional crosslinker with enhanced thermal and ageing stability have been synthesized and tested.
The advantage of several different building blocks with known characteristics is the possibility to tune the polymer to special needs of an application. For example, some polymer compositions have good conductivity at lower temperatures whereas other polymers develop better properties at elevated temperatures.
PB - Singapore : Research Publishing
C3 - Proceedings of the 8th International Conference on Multi-Material Micro Manufacture
T1 - Photopolymerizable monomer formulations for nanoporous proton conducting membranes
ER -
@conference{
author = "Kellner, Michael and Radovanović, Filip and Matović, Jovan and Liska, Robert",
year = "2011",
url = "http://dais.sanu.ac.rs/123456789/780",
abstract = "Several monomers and crosslinker in a broad range of concentrations in water and 1-Methyl-2-pyrrolidone (NMP) respectively were screened for their mechanical properties, water uptake and conductivity by photo polymerization with a polar photo initiator in porous membranes made of polypropylene and polyethersulfone respectively. As conductive polymer, primarily poly(2-acrylamido-2-methylpropane sulfonic acid) (PAMPS) and poly(2-sulfoethyl methacrylate) (PSEM) respectively as well as polymers of phosphonic acid containing monomers or newly synthesized monomers were used. The conductive monomers were crosslinked with varying hydrophobic and hydrophilic multifunctional monomers like N,N'-methylene bisacrylamide (MBA), 2-Propenoic acid, 2-methyl-, 1,1'-(1,10-decanediyl) ester (D3MA) or polyethyleneglycol diacrylates with two varying chainlengths (PEG-DA700, PEG-DA330). Furthermore several new multifunctional crosslinker with enhanced thermal and ageing stability have been synthesized and tested.
The advantage of several different building blocks with known characteristics is the possibility to tune the polymer to special needs of an application. For example, some polymer compositions have good conductivity at lower temperatures whereas other polymers develop better properties at elevated temperatures.",
publisher = "Singapore : Research Publishing",
journal = "Proceedings of the 8th International Conference on Multi-Material Micro Manufacture",
title = "Photopolymerizable monomer formulations for nanoporous proton conducting membranes"
}
Kellner M, Radovanović F, Matović J, Liska R. Photopolymerizable monomer formulations for nanoporous proton conducting membranes. Proceedings of the 8th International Conference on Multi-Material Micro Manufacture. 2011;
Kellner, M., Radovanović, F., Matović, J.,& Liska, R. (2011). Photopolymerizable monomer formulations for nanoporous proton conducting membranes.
Proceedings of the 8th International Conference on Multi-Material Micro ManufactureSingapore : Research Publishing., null.
