Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid

Jugović, Dragana; Mitrić, Miodrag; Kuzmanović, Maja; Cvjetićanin, Nikola; Škapin, Srečo Davor; Cekić, Božidar; Ivanovski, Valentin N.; Uskoković, Dragan

doi:10.1016/j.jpowsour.2011.01.072

2011

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Authors

Jugović, Dragana

Mitrić, Miodrag

Kuzmanović, Maja

Cvjetićanin, Nikola
Škapin, Srečo Davor

Cekić, Božidar
Ivanovski, Valentin N.

Uskoković, Dragan

Article (Accepted Version)

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Abstract

The olivine type LiFePO4 is synthesized via a simple and inexpensive route by aqueous co-precipitation of an Fe(II) precursor material in molten stearic acid and subsequent heat treatment at different temperatures. Stearic acid serves as both chelating agent and carbonaceous material. The obtained composites with carbon are characterized by X-ray powder diffraction, field emission scanning electron microscopy, and Mössbauer spectroscopy. Electrochemical characteristics of the composites are evaluated by using galvanostatic charge/discharge tests. The powder obtained at 700 °C delivers discharge capacity of 160 mAh g−1, quite near the theoretical value.

Keywords:

lithium iron phosphate / LiFePO4 / Rietveld analysis / Mössbauer spectroscopy / cathode

Source:
Journal of Power Sources, 2011, 196, 10, 4613-4618

Projects:

DOI: 10.1016/j.jpowsour.2011.01.072

ISSN: 0378-7753

WoS: 000289136800026

Scopus: 2-s2.0-79952283198

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TY  - JOUR
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Kuzmanović, Maja
AU  - Cvjetićanin, Nikola
AU  - Škapin, Srečo Davor
AU  - Cekić, Božidar
AU  - Ivanovski, Valentin N.
AU  - Uskoković, Dragan
PY  - 2011
UR  - http://dais.sanu.ac.rs/123456789/751
AB  - The olivine type LiFePO4 is synthesized via a simple and inexpensive route by aqueous co-precipitation of an Fe(II) precursor material in molten stearic acid and subsequent heat treatment at different temperatures. Stearic acid serves as both chelating agent and carbonaceous material. The obtained composites with carbon are characterized by X-ray powder diffraction, field emission scanning electron microscopy, and Mössbauer spectroscopy. Electrochemical characteristics of the composites are evaluated by using galvanostatic charge/discharge tests. The powder obtained at 700 °C delivers discharge capacity of 160 mAh g−1, quite near the theoretical value.
T2  - Journal of Power Sources
T1  - Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid
SP  - 4613
SP  - 4618
EP  - 4618
VL  - 196
IS  - 10
DO  - 10.1016/j.jpowsour.2011.01.072
ER  -

@article{
author = "Jugović, Dragana and Mitrić, Miodrag and Kuzmanović, Maja and Cvjetićanin, Nikola and Škapin, Srečo Davor and Cekić, Božidar and Ivanovski, Valentin N. and Uskoković, Dragan",
year = "2011",
url = "http://dais.sanu.ac.rs/123456789/751",
abstract = "The olivine type LiFePO4 is synthesized via a simple and inexpensive route by aqueous co-precipitation of an Fe(II) precursor material in molten stearic acid and subsequent heat treatment at different temperatures. Stearic acid serves as both chelating agent and carbonaceous material. The obtained composites with carbon are characterized by X-ray powder diffraction, field emission scanning electron microscopy, and Mössbauer spectroscopy. Electrochemical characteristics of the composites are evaluated by using galvanostatic charge/discharge tests. The powder obtained at 700 °C delivers discharge capacity of 160 mAh g−1, quite near the theoretical value.",
journal = "Journal of Power Sources",
title = "Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid",
pages = "4613-4618-4618",
volume = "196",
number = "10",
doi = "10.1016/j.jpowsour.2011.01.072"
}

Jugović D, Mitrić M, Kuzmanović M, Cvjetićanin N, Škapin SD, Cekić B, Ivanovski VN, Uskoković D. Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid. Journal of Power Sources. 2011;196(10):4613-4618

Jugović, D., Mitrić, M., Kuzmanović, M., Cvjetićanin, N., Škapin, S. D., Cekić, B., Ivanovski, V. N.,& Uskoković, D. (2011). Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid.
Journal of Power Sources, 196(10), 4613-4618. 
https://doi.org/10.1016/j.jpowsour.2011.01.072

Jugović Dragana, Mitrić Miodrag, Kuzmanović Maja, Cvjetićanin Nikola, Škapin Srečo Davor, Cekić Božidar, Ivanovski Valentin N., Uskoković Dragan, "Preparation of LiFePO4/C composites by co-precipitation in molten stearic acid" 196, no. 10 (2011):4613-4618,
https://doi.org/10.1016/j.jpowsour.2011.01.072 .