Rapid crystallization of LiFePO4 particles by facile emulsion-mediated solvothermal synthesis

2012
Authors
Jugović, Dragana
Mitrić, Miodrag

Kuzmanović, Maja

Cvjetićanin, Nikola

Marković, Smilja

Škapin, Srečo Davor

Uskoković, Dragan

Article (Accepted Version)
Metadata
Show full item recordAbstract
Lithium iron phosphate powders were obtained by solvothermal treatments of quaternary emulsions Triton X-100/cyclohexane/n-hexanol/water at low temperature (180 °C), with or without stirring. Such synthesis conditions allowed for fast crystallization of pure olivine-type LiFePO4 powder, evidenced by the X-ray powder diffraction measurements and energy dispersive spectroscopy. It has been found that stirring drastically changes the morphology of LiFePO4 particles, causing a preferential crystal orientation. Also, a great difference in the morphology was demonstrated by field emission scanning electron microscopy. The powder obtained after only half an hour of the dynamic solvothermal treatment, without additional post annealing, and without carbon coating, was electrochemically active, showing the discharge capacity of 115 mAh g− 1.
Keywords:
lithium iron phosphate / LiFePO4 / electrode materials / X-ray diffraction / scanning electron microscopySource:
Powder Technology, 2012, 219, 128-134Funding / projects:
- Molecular designing of nanoparticles with controlled morphological and physicochemical characteristics and functional materials based on them (RS-45004)
- Magnetic and radionuclide labeled nanostructured materials for medical applications (RS-45015)
- Lithium-ion batteries and fuel cells - research and development (RS-45014)
Note:
- This is the peer reviewed version of the following article: Jugović, D., M. Mitrić, M. Kuzmanović, N. Cvjetićanin, S. Marković, S. Škapin, and D. Uskoković. “Rapid Crystallization of LiFePO4 Particles by Facile Emulsion-Mediated Solvothermal Synthesis.” Powder Technology 219 (March 2012): 128–34. http://dx.doi.org/10.1016/j.powtec.2011.12.028
DOI: 10.1016/j.powtec.2011.12.028
ISSN: 0032-5910
WoS: 000301310400017
Scopus: 2-s2.0-84856431744
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Jugović, Dragana AU - Mitrić, Miodrag AU - Kuzmanović, Maja AU - Cvjetićanin, Nikola AU - Marković, Smilja AU - Škapin, Srečo Davor AU - Uskoković, Dragan PY - 2012 UR - https://dais.sanu.ac.rs/123456789/750 AB - Lithium iron phosphate powders were obtained by solvothermal treatments of quaternary emulsions Triton X-100/cyclohexane/n-hexanol/water at low temperature (180 °C), with or without stirring. Such synthesis conditions allowed for fast crystallization of pure olivine-type LiFePO4 powder, evidenced by the X-ray powder diffraction measurements and energy dispersive spectroscopy. It has been found that stirring drastically changes the morphology of LiFePO4 particles, causing a preferential crystal orientation. Also, a great difference in the morphology was demonstrated by field emission scanning electron microscopy. The powder obtained after only half an hour of the dynamic solvothermal treatment, without additional post annealing, and without carbon coating, was electrochemically active, showing the discharge capacity of 115 mAh g− 1. T2 - Powder Technology T1 - Rapid crystallization of LiFePO4 particles by facile emulsion-mediated solvothermal synthesis SP - 128 EP - 134 VL - 219 DO - 10.1016/j.powtec.2011.12.028 UR - https://hdl.handle.net/21.15107/rcub_dais_750 ER -
@article{ author = "Jugović, Dragana and Mitrić, Miodrag and Kuzmanović, Maja and Cvjetićanin, Nikola and Marković, Smilja and Škapin, Srečo Davor and Uskoković, Dragan", year = "2012", abstract = "Lithium iron phosphate powders were obtained by solvothermal treatments of quaternary emulsions Triton X-100/cyclohexane/n-hexanol/water at low temperature (180 °C), with or without stirring. Such synthesis conditions allowed for fast crystallization of pure olivine-type LiFePO4 powder, evidenced by the X-ray powder diffraction measurements and energy dispersive spectroscopy. It has been found that stirring drastically changes the morphology of LiFePO4 particles, causing a preferential crystal orientation. Also, a great difference in the morphology was demonstrated by field emission scanning electron microscopy. The powder obtained after only half an hour of the dynamic solvothermal treatment, without additional post annealing, and without carbon coating, was electrochemically active, showing the discharge capacity of 115 mAh g− 1.", journal = "Powder Technology", title = "Rapid crystallization of LiFePO4 particles by facile emulsion-mediated solvothermal synthesis", pages = "128-134", volume = "219", doi = "10.1016/j.powtec.2011.12.028", url = "https://hdl.handle.net/21.15107/rcub_dais_750" }
Jugović, D., Mitrić, M., Kuzmanović, M., Cvjetićanin, N., Marković, S., Škapin, S. D.,& Uskoković, D.. (2012). Rapid crystallization of LiFePO4 particles by facile emulsion-mediated solvothermal synthesis. in Powder Technology, 219, 128-134. https://doi.org/10.1016/j.powtec.2011.12.028 https://hdl.handle.net/21.15107/rcub_dais_750
Jugović D, Mitrić M, Kuzmanović M, Cvjetićanin N, Marković S, Škapin SD, Uskoković D. Rapid crystallization of LiFePO4 particles by facile emulsion-mediated solvothermal synthesis. in Powder Technology. 2012;219:128-134. doi:10.1016/j.powtec.2011.12.028 https://hdl.handle.net/21.15107/rcub_dais_750 .
Jugović, Dragana, Mitrić, Miodrag, Kuzmanović, Maja, Cvjetićanin, Nikola, Marković, Smilja, Škapin, Srečo Davor, Uskoković, Dragan, "Rapid crystallization of LiFePO4 particles by facile emulsion-mediated solvothermal synthesis" in Powder Technology, 219 (2012):128-134, https://doi.org/10.1016/j.powtec.2011.12.028 ., https://hdl.handle.net/21.15107/rcub_dais_750 .