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dc.creatorJovanović, Zoran
dc.creatorMravik, Željko
dc.creatorBajuk Bogdanović, Danica
dc.creatorJovanović, Sonja
dc.creatorMarković, Smilja
dc.creatorVujković, Milica
dc.creatorKovač, Janez
dc.creatorVengust, Damjan
dc.creatorUskoković-Marković, Snežana
dc.creatorHolclajtner Antunović, Ivanka
dc.date.accessioned2019-12-26T12:35:27Z
dc.date.available2019-12-26T12:35:27Z
dc.date.issued2020
dc.identifier.issn0008-6223
dc.identifier.urihttp://dais.sanu.ac.rs/123456789/6882
dc.description.abstractIn the present study we investigated the interaction between 12-tungstophosphoric acid (WPA) and graphene oxide (GO) in their nanocomposite by utilizing the loading of WPA as an intrinsic parameter for interaction tuning. The Fourier-transform infrared spectroscopy, temperature-programmed desorption, X-ray photoelectron spectroscopy, zeta-potential measurements, thermogravimetric analysis, X-ray diffraction, Raman spectroscopy and transmission electron microscopy methods revealed that ∼5–13 wt% of WPA represents critical loading that separates two distinct contributions to GO-WPA interaction. This was explained by the self-limiting nature of GO-WPA interaction, initially controlled by high dispersion of WPA on GO (up to 13 wt%), that is eventually overpowered by WPA-WPA interaction as loading increases. As a result, the WPA agglomerates are being formed because of which the hybrid character of the nanocomposite diminishes, i.e., the properties of independent components start to be manifested to greater extent. The obtained results provide an important framework for considering possible outcomes in other 2D-0D systems, whose interaction is relevant both from fundamental and applicative point of view. Thus, the GO/WPA nanocomposite illustrates how the interactions between the components can be used for tuning the properties of nanocomposite as a whole.
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45006/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172043/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45014/RS//
dc.relationSlovenian Research Agency (Project P2-0091).
dc.relationSerbia-Slovenia bilateral project (Project No. 451-03-38/2016-09/50).
dc.rightsrestrictedAccess
dc.sourceCarbon
dc.subjectFourier transform infrared spectroscopy
dc.subjectgraphene
dc.subjecthigh-resolution transmission electron microscopy (HRTEM)
dc.subjectnanocomposites
dc.subjecttemperature programmed desorption
dc.subjectthermogravimetric analysis
dc.subjecttuning
dc.subjectX ray photoelectron spectroscopy
dc.titleSelf-limiting interactions in 2D–0D system: A case study of graphene oxide and 12-tungstophosphoric acid nanocomposite
dc.typearticle
dc.rights.licenseARR
dcterms.abstractХолцлајтнер Aнтуновић, Иванка; Марковић, Смиља; Ускоковић-Марковић, Снежана; Венгуст, Дамјан; Јовановић, Зоран; Мравик, Жељко; Бајук Богдановић, Даница; Јовановић, Соња; Вујковић, Милица; Ковач, Јанез;
dc.citation.spage166
dc.citation.epage178
dc.citation.volume156
dc.identifier.wos000509332200015
dc.identifier.doi10.1016/j.carbon.2019.09.072
dc.identifier.scopus2-s2.0-85072633199
dc.type.versionpublishedVersion


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