The catalytic activity of the walnut shell ash was investigated in the biodiesel production by the sunflower oil methanolysis. The catalyst was characterized by the TG-DTA, XRD, Hg porosimetry, N2 physisorption, SEM, and Hammett method. In addition, the effects of the catalyst loading and the methanol-to-oil molar ratio on the methyl esters synthesis were tested at the reaction temperature of 60 °C. The walnut shell ash provided a very fast reaction and a high FAME content (over 98%). As the reaction occurred in the absence of triacylglycerols mass transfer limitation, the pseudo-first-order model was employed for describing the kinetics of the reaction. The catalyst was successfully reused four times after the regeneration of the catalytic activity by recalcination at 800 °C.
TY - JOUR
AU - Miladinović, Marija R.
AU - Zdujić, Miodrag
AU - Veljović, Đorđe
AU - Krstić, Jugoslav B.
AU - Banković Ilić, Ivana B.
AU - Veljković, Vlada B.
AU - Stamenković, Olivera S.
PY - 2020
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/3217
UR - http://dais.sanu.ac.rs/123456789/6717
AB - The catalytic activity of the walnut shell ash was investigated in the biodiesel production by the sunflower oil methanolysis. The catalyst was characterized by the TG-DTA, XRD, Hg porosimetry, N2 physisorption, SEM, and Hammett method. In addition, the effects of the catalyst loading and the methanol-to-oil molar ratio on the methyl esters synthesis were tested at the reaction temperature of 60 °C. The walnut shell ash provided a very fast reaction and a high FAME content (over 98%). As the reaction occurred in the absence of triacylglycerols mass transfer limitation, the pseudo-first-order model was employed for describing the kinetics of the reaction. The catalyst was successfully reused four times after the regeneration of the catalytic activity by recalcination at 800 °C.
PB - Elsevier
T2 - Renewable Energy
T1 - Valorization of walnut shell ash as a catalyst for biodiesel production
SP - 1033
EP - 1043
VL - 147
DO - 10.1016/j.renene.2019.09.056
ER -
@article{
author = "Miladinović, Marija R. and Zdujić, Miodrag and Veljović, Đorđe and Krstić, Jugoslav B. and Banković Ilić, Ivana B. and Veljković, Vlada B. and Stamenković, Olivera S.",
year = "2020",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/3217, http://dais.sanu.ac.rs/123456789/6717",
abstract = "The catalytic activity of the walnut shell ash was investigated in the biodiesel production by the sunflower oil methanolysis. The catalyst was characterized by the TG-DTA, XRD, Hg porosimetry, N2 physisorption, SEM, and Hammett method. In addition, the effects of the catalyst loading and the methanol-to-oil molar ratio on the methyl esters synthesis were tested at the reaction temperature of 60 °C. The walnut shell ash provided a very fast reaction and a high FAME content (over 98%). As the reaction occurred in the absence of triacylglycerols mass transfer limitation, the pseudo-first-order model was employed for describing the kinetics of the reaction. The catalyst was successfully reused four times after the regeneration of the catalytic activity by recalcination at 800 °C.",
publisher = "Elsevier",
journal = "Renewable Energy",
title = "Valorization of walnut shell ash as a catalyst for biodiesel production",
pages = "1033-1043",
volume = "147",
doi = "10.1016/j.renene.2019.09.056"
}
Miladinović MR, Zdujić M, Veljović Đ, Krstić JB, Banković Ilić IB, Veljković VB, Stamenković OS. Valorization of walnut shell ash as a catalyst for biodiesel production. Renewable Energy. 2020;147:1033-1043
Miladinović, M. R., Zdujić, M., Veljović, Đ., Krstić, J. B., Banković Ilić, I. B., Veljković, V. B.,& Stamenković, O. S. (2020). Valorization of walnut shell ash as a catalyst for biodiesel production.
Renewable EnergyElsevier., 147, 1033-1043.
https://doi.org/10.1016/j.renene.2019.09.056
Miladinović Marija R., Zdujić Miodrag, Veljović Đorđe, Krstić Jugoslav B., Banković Ilić Ivana B., Veljković Vlada B., Stamenković Olivera S., "Valorization of walnut shell ash as a catalyst for biodiesel production" 147 (2020):1033-1043,
https://doi.org/10.1016/j.renene.2019.09.056 .
