DAIS - Digital Archive of the Serbian Academy of Sciences and Arts
    • English
    • Српски
    • Српски (Serbia)
  • English 
    • English
    • Serbian (Cyrillic)
    • Serbian (Latin)
  • Login
View Item 
  •   DAIS
  • Институт техничких наука САНУ / Institute of Technical Sciences of SASA
  • ИТН САНУ - Општа колекција / ITS SASA - General collection
  • View Item
  •   DAIS
  • Институт техничких наука САНУ / Institute of Technical Sciences of SASA
  • ИТН САНУ - Општа колекција / ITS SASA - General collection
  • View Item
JavaScript is disabled for your browser. Some features of this site may not work without it.

The effect of Sn for Ti substitution on the average and local crystal structure of BaTi1−xSnxO3 (0 ≤x≤ 0.20)

Authorized Users Only
2014
Authors
Veselinović, Ljiljana
Mitrić, Miodrag
Mančić, Lidija
Vukomanović, Marija
Hadžić, Branka
Marković, Smilja
Uskoković, Dragan
Article (Published version)
Metadata
Show full item record
Abstract
The effect of Sn for Ti substitution on the crystal structure of a perovskite, barium titanate stannate (BTS), BaTi1−xSnxO3 for x = 0, 0.025, 0.05, 0.07, 0.10, 0.12, 0.15 and 0.20, was investigated. The powders were prepared by the conventional solid-state reaction technique. The structural investigations of the BTS powders were done at room temperature by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), high-resolution TEM (HRTEM), selected-area electron diffraction (SAED) and Raman spectroscopy analyses. Rietveld refinement of XRD data indicates that gradual replacement of titanium by tin in BaTiO3 provokes a phase transition from tetragonal for 0 ≤x≤ 0.07 to cubic for x = 0.12, 0.15 and 0.20. The coexistence of tetragonal (P4mm) and cubic (Pminline imagem) crystal phases was established in powder with nominal composition BaTi0.9Sn0.1O3. The crystal phases determined by Rietveld refinement were confirmed by HRTEM and SAED analyses. The crystal structures of the... BTS powders at short-range scale were studied by Raman spectroscopy, which shows tetragonal (P4mm) and a small fraction of orthorhombic (Pmm2) crystal phases for all the examined BTS powders, implying a lower local ordering when compared to the average symmetry.

Keywords:
perovskites / phase transitions / barium titanate stannate
Source:
Journal of Applied Crystallography, 2014, 47, 3, 999-1007
Publisher:
  • Hoboken, NJ : John Wiley & Sons
Funding / projects:
  • Molecular designing of nanoparticles with controlled morphological and physicochemical characteristics and functional materials based on them (RS-45004)

DOI: 10.1107/S1600576714007584

ISSN: 1600-5767

WoS: 000336738500020

Scopus: 2-s2.0-84901832760
[ Google Scholar ]
22
17
Handle
https://hdl.handle.net/21.15107/rcub_dais_668
URI
https://dais.sanu.ac.rs/123456789/668
Collections
  • ИТН САНУ - Општа колекција / ITS SASA - General collection
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASA
TY  - JOUR
AU  - Veselinović, Ljiljana
AU  - Mitrić, Miodrag
AU  - Mančić, Lidija
AU  - Vukomanović, Marija
AU  - Hadžić, Branka
AU  - Marković, Smilja
AU  - Uskoković, Dragan
PY  - 2014
UR  - https://dais.sanu.ac.rs/123456789/668
AB  - The effect of Sn for Ti substitution on the crystal structure of a perovskite, barium titanate stannate (BTS), BaTi1−xSnxO3 for x = 0, 0.025, 0.05, 0.07, 0.10, 0.12, 0.15 and 0.20, was investigated. The powders were prepared by the conventional solid-state reaction technique. The structural investigations of the BTS powders were done at room temperature by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), high-resolution TEM (HRTEM), selected-area electron diffraction (SAED) and Raman spectroscopy analyses. Rietveld refinement of XRD data indicates that gradual replacement of titanium by tin in BaTiO3 provokes a phase transition from tetragonal for 0 ≤x≤ 0.07 to cubic for x = 0.12, 0.15 and 0.20. The coexistence of tetragonal (P4mm) and cubic (Pminline imagem) crystal phases was established in powder with nominal composition BaTi0.9Sn0.1O3. The crystal phases determined by Rietveld refinement were confirmed by HRTEM and SAED analyses. The crystal structures of the BTS powders at short-range scale were studied by Raman spectroscopy, which shows tetragonal (P4mm) and a small fraction of orthorhombic (Pmm2) crystal phases for all the examined BTS powders, implying a lower local ordering when compared to the average symmetry.
PB  - Hoboken, NJ : John Wiley & Sons
T2  - Journal of Applied Crystallography
T1  - The effect of Sn for Ti substitution on the average and local crystal structure of BaTi1−xSnxO3 (0 ≤x≤ 0.20)
SP  - 999
EP  - 1007
VL  - 47
IS  - 3
DO  - 10.1107/S1600576714007584
UR  - https://hdl.handle.net/21.15107/rcub_dais_668
ER  - 
@article{
author = "Veselinović, Ljiljana and Mitrić, Miodrag and Mančić, Lidija and Vukomanović, Marija and Hadžić, Branka and Marković, Smilja and Uskoković, Dragan",
year = "2014",
abstract = "The effect of Sn for Ti substitution on the crystal structure of a perovskite, barium titanate stannate (BTS), BaTi1−xSnxO3 for x = 0, 0.025, 0.05, 0.07, 0.10, 0.12, 0.15 and 0.20, was investigated. The powders were prepared by the conventional solid-state reaction technique. The structural investigations of the BTS powders were done at room temperature by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), high-resolution TEM (HRTEM), selected-area electron diffraction (SAED) and Raman spectroscopy analyses. Rietveld refinement of XRD data indicates that gradual replacement of titanium by tin in BaTiO3 provokes a phase transition from tetragonal for 0 ≤x≤ 0.07 to cubic for x = 0.12, 0.15 and 0.20. The coexistence of tetragonal (P4mm) and cubic (Pminline imagem) crystal phases was established in powder with nominal composition BaTi0.9Sn0.1O3. The crystal phases determined by Rietveld refinement were confirmed by HRTEM and SAED analyses. The crystal structures of the BTS powders at short-range scale were studied by Raman spectroscopy, which shows tetragonal (P4mm) and a small fraction of orthorhombic (Pmm2) crystal phases for all the examined BTS powders, implying a lower local ordering when compared to the average symmetry.",
publisher = "Hoboken, NJ : John Wiley & Sons",
journal = "Journal of Applied Crystallography",
title = "The effect of Sn for Ti substitution on the average and local crystal structure of BaTi1−xSnxO3 (0 ≤x≤ 0.20)",
pages = "999-1007",
volume = "47",
number = "3",
doi = "10.1107/S1600576714007584",
url = "https://hdl.handle.net/21.15107/rcub_dais_668"
}
Veselinović, L., Mitrić, M., Mančić, L., Vukomanović, M., Hadžić, B., Marković, S.,& Uskoković, D.. (2014). The effect of Sn for Ti substitution on the average and local crystal structure of BaTi1−xSnxO3 (0 ≤x≤ 0.20). in Journal of Applied Crystallography
Hoboken, NJ : John Wiley & Sons., 47(3), 999-1007.
https://doi.org/10.1107/S1600576714007584
https://hdl.handle.net/21.15107/rcub_dais_668
Veselinović L, Mitrić M, Mančić L, Vukomanović M, Hadžić B, Marković S, Uskoković D. The effect of Sn for Ti substitution on the average and local crystal structure of BaTi1−xSnxO3 (0 ≤x≤ 0.20). in Journal of Applied Crystallography. 2014;47(3):999-1007.
doi:10.1107/S1600576714007584
https://hdl.handle.net/21.15107/rcub_dais_668 .
Veselinović, Ljiljana, Mitrić, Miodrag, Mančić, Lidija, Vukomanović, Marija, Hadžić, Branka, Marković, Smilja, Uskoković, Dragan, "The effect of Sn for Ti substitution on the average and local crystal structure of BaTi1−xSnxO3 (0 ≤x≤ 0.20)" in Journal of Applied Crystallography, 47, no. 3 (2014):999-1007,
https://doi.org/10.1107/S1600576714007584 .,
https://hdl.handle.net/21.15107/rcub_dais_668 .

DSpace software copyright © 2002-2015  DuraSpace
About DAIS - Digital Archive of the Serbian Academy of Sciences and Arts | Send Feedback

CoreTrustSealre3dataOpenAIRERCUB
 

 

All of DSpaceInstitutions/communitiesAuthorsTitlesSubjectsThis institutionAuthorsTitlesSubjects

Statistics

View Usage Statistics

DSpace software copyright © 2002-2015  DuraSpace
About DAIS - Digital Archive of the Serbian Academy of Sciences and Arts | Send Feedback

CoreTrustSealre3dataOpenAIRERCUB