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Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material

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2019
10.1016@j.electacta.2019.06.046.pdf (3.963Mb)
Authors
Gvozdenović, Milica M.
Jugović, Branimir
Jokić, Bojan
Džunuzović, Enis S.
Grgur, Branimir
Article (Accepted Version)
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Abstract
Poly(o-toluidine) (POT) is electrochemically synthesized on graphite electrode at constant current density of 1.5 mA cm-2 from aqueous electrolyte of 1.0 mol dm-3 H2SO4 and 0.25 mol dm-3 o-toluidine. Electrochemical characterization of POT electrode is performed using cyclic voltammetry, Mot Schottky analysis and galvanostatic measurements at different currents. POT electrode exhibited high energy storage features, with specific energy up to 17.5 Wh kg-1 and specific power up to 3300 W kg-1. Cyclic stability exceeding 90% is obtained over 2000 charge/discharge cycles at 13.1 A g-1 indicating the perspective application of POT electrode as energy storage material.
Keywords:
electrochemical polymerization / poly(o-toluidine) / specific energy / specific power / elektrohemijska polimerizacija / poli (o-toluidin) / specifična energija / specifična snaga
Source:
Electrochimica Acta, 2019, 317, 746-752
Publisher:
  • Elsevier
Funding / projects:
  • Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies (RS-172046)
Note:
  • This is Accepted Manuscript of the following article: Milica M. Gvozdenović, Braninir Z. Jugović, Bojan M. Jokić, Enis S.Džunuzović, Braninimir N. Grgur, Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material, Electrochimica Acta (2019), vol. 317. pp. 746-752, http://dx.doi.org/10.1016/j.electacta.2019.06.046
Related info:
  • Version of
    http://dx.doi.org/10.1016/j.electacta.2019.06.046
  • Version of
    https://hdl.handle.net/21.15107/rcub_dais_6297

DOI: 10.1016/j.electacta.2019.06.046

ISSN: 0013-4686

WoS: 000476718000081

Scopus: 2-s2.0-85067662251
[ Google Scholar ]
6
2
Handle
https://hdl.handle.net/21.15107/rcub_dais_6296
URI
https://dais.sanu.ac.rs/123456789/6296
Collections
  • ИТН САНУ - Општа колекција / ITS SASA - General collection
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASA
TY  - JOUR
AU  - Gvozdenović, Milica M.
AU  - Jugović, Branimir
AU  - Jokić, Bojan
AU  - Džunuzović, Enis S.
AU  - Grgur, Branimir
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/6296
AB  - Poly(o-toluidine) (POT) is electrochemically synthesized on graphite electrode at
constant current density of 1.5 mA cm-2 from aqueous electrolyte of 1.0 mol dm-3 H2SO4 and
0.25 mol dm-3 o-toluidine. Electrochemical characterization of POT electrode is performed
using cyclic voltammetry, Mot Schottky analysis and galvanostatic measurements at different
currents. POT electrode exhibited high energy storage features, with specific energy up to
17.5 Wh kg-1 and specific power up to 3300 W kg-1. Cyclic stability exceeding 90% is
obtained over 2000 charge/discharge cycles at 13.1 A g-1 indicating the perspective
application of POT electrode as energy storage material.
PB  - Elsevier
T2  - Electrochimica Acta
T1  - Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material
SP  - 746
EP  - 752
VL  - 317
DO  - 10.1016/j.electacta.2019.06.046
UR  - https://hdl.handle.net/21.15107/rcub_dais_6296
ER  - 
@article{
author = "Gvozdenović, Milica M. and Jugović, Branimir and Jokić, Bojan and Džunuzović, Enis S. and Grgur, Branimir",
year = "2019",
abstract = "Poly(o-toluidine) (POT) is electrochemically synthesized on graphite electrode at
constant current density of 1.5 mA cm-2 from aqueous electrolyte of 1.0 mol dm-3 H2SO4 and
0.25 mol dm-3 o-toluidine. Electrochemical characterization of POT electrode is performed
using cyclic voltammetry, Mot Schottky analysis and galvanostatic measurements at different
currents. POT electrode exhibited high energy storage features, with specific energy up to
17.5 Wh kg-1 and specific power up to 3300 W kg-1. Cyclic stability exceeding 90% is
obtained over 2000 charge/discharge cycles at 13.1 A g-1 indicating the perspective
application of POT electrode as energy storage material.",
publisher = "Elsevier",
journal = "Electrochimica Acta",
title = "Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material",
pages = "746-752",
volume = "317",
doi = "10.1016/j.electacta.2019.06.046",
url = "https://hdl.handle.net/21.15107/rcub_dais_6296"
}
Gvozdenović, M. M., Jugović, B., Jokić, B., Džunuzović, E. S.,& Grgur, B.. (2019). Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material. in Electrochimica Acta
Elsevier., 317, 746-752.
https://doi.org/10.1016/j.electacta.2019.06.046
https://hdl.handle.net/21.15107/rcub_dais_6296
Gvozdenović MM, Jugović B, Jokić B, Džunuzović ES, Grgur B. Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material. in Electrochimica Acta. 2019;317:746-752.
doi:10.1016/j.electacta.2019.06.046
https://hdl.handle.net/21.15107/rcub_dais_6296 .
Gvozdenović, Milica M., Jugović, Branimir, Jokić, Bojan, Džunuzović, Enis S., Grgur, Branimir, "Electrochemical synthesis and characterization of poly(o-toluidine) as high energy storage material" in Electrochimica Acta, 317 (2019):746-752,
https://doi.org/10.1016/j.electacta.2019.06.046 .,
https://hdl.handle.net/21.15107/rcub_dais_6296 .

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