Monoclinic Li2FeSiO4 that crystallizes in P21/n space group was investigated as a potential cathode material for lithium-ion batteries. A combined X-ray diffraction and Mössbauer spectroscopy study was used for the structural investigation. It was found that the crystal structure is prone to an “antisite” defect, the one in which the Fe ion and the Li ion exchange places. This finding was also confirmed by the Mössbauer spectroscopy. In order to obtain composites of Li2FeSiO4 and carbon, several synthesis techniques that use different carbon sources were involved. Electrochemical performances were investigated through galvanostatic charge/discharge tests. Discharge curve profile did not reflect a two-phase intercalation reaction (no obvious voltage plateau) due to the low conductivity at room temperature.
TY - CONF
AU - Jugović, Dragana
AU - Milović, Miloš
AU - Mitrić, Miodrag
AU - Ivanovski, Valentin N.
AU - Avdeev, Maxim
AU - Jokić, Bojan
AU - Dominko, Robert
AU - Uskoković, Dragan
PY - 2014
UR - https://dais.sanu.ac.rs/123456789/590
AB - Monoclinic Li2FeSiO4 that crystallizes in P21/n space group was investigated as a potential cathode material for lithium-ion batteries. A combined X-ray diffraction and Mössbauer spectroscopy study was used for the structural investigation. It was found that the crystal structure is prone to an “antisite” defect, the one in which the Fe ion and the Li ion exchange places. This finding was also confirmed by the Mössbauer spectroscopy. In order to obtain composites of Li2FeSiO4 and carbon, several synthesis techniques that use different carbon sources were involved. Electrochemical performances were investigated through galvanostatic charge/discharge tests. Discharge curve profile did not reflect a two-phase intercalation reaction (no obvious voltage plateau) due to the low conductivity at room temperature.
PB - Belgrade : Materials Research Society of Serbia
C3 - The Sixteenth Annual Conference YUCOMAT 2014: Programme and the Book of Abstracts
T1 - Li2FeSiO4 cathode material: the structure and electrochemical performances
SP - 6
EP - 6
UR - https://hdl.handle.net/21.15107/rcub_dais_590
ER -
@conference{
author = "Jugović, Dragana and Milović, Miloš and Mitrić, Miodrag and Ivanovski, Valentin N. and Avdeev, Maxim and Jokić, Bojan and Dominko, Robert and Uskoković, Dragan",
year = "2014",
abstract = "Monoclinic Li2FeSiO4 that crystallizes in P21/n space group was investigated as a potential cathode material for lithium-ion batteries. A combined X-ray diffraction and Mössbauer spectroscopy study was used for the structural investigation. It was found that the crystal structure is prone to an “antisite” defect, the one in which the Fe ion and the Li ion exchange places. This finding was also confirmed by the Mössbauer spectroscopy. In order to obtain composites of Li2FeSiO4 and carbon, several synthesis techniques that use different carbon sources were involved. Electrochemical performances were investigated through galvanostatic charge/discharge tests. Discharge curve profile did not reflect a two-phase intercalation reaction (no obvious voltage plateau) due to the low conductivity at room temperature.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "The Sixteenth Annual Conference YUCOMAT 2014: Programme and the Book of Abstracts",
title = "Li2FeSiO4 cathode material: the structure and electrochemical performances",
pages = "6-6",
url = "https://hdl.handle.net/21.15107/rcub_dais_590"
}
Jugović, D., Milović, M., Mitrić, M., Ivanovski, V. N., Avdeev, M., Jokić, B., Dominko, R.,& Uskoković, D.. (2014). Li2FeSiO4 cathode material: the structure and electrochemical performances. in The Sixteenth Annual Conference YUCOMAT 2014: Programme and the Book of Abstracts
Belgrade : Materials Research Society of Serbia., 6-6.
https://hdl.handle.net/21.15107/rcub_dais_590
Jugović D, Milović M, Mitrić M, Ivanovski VN, Avdeev M, Jokić B, Dominko R, Uskoković D. Li2FeSiO4 cathode material: the structure and electrochemical performances. in The Sixteenth Annual Conference YUCOMAT 2014: Programme and the Book of Abstracts. 2014;:6-6.
https://hdl.handle.net/21.15107/rcub_dais_590 .
Jugović, Dragana, Milović, Miloš, Mitrić, Miodrag, Ivanovski, Valentin N., Avdeev, Maxim, Jokić, Bojan, Dominko, Robert, Uskoković, Dragan, "Li2FeSiO4 cathode material: the structure and electrochemical performances" in The Sixteenth Annual Conference YUCOMAT 2014: Programme and the Book of Abstracts (2014):6-6,
https://hdl.handle.net/21.15107/rcub_dais_590 .
