The initial characteristics of the polypyrrole based aqueous rechargeable batteries with supercapattery characteristics

Grgur, Branimir; Janačković, Marija; Jugović, Branimir; Gvozdenović, Milica M.

doi:10.1016/j.mseb.2019.04.013

2019

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Authors

Grgur, Branimir

Janačković, Marija
Jugović, Branimir

Gvozdenović, Milica M.

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Abstract

The electrochemically synthesized polypyrrole (PPy) is investigated as a possible active material of the low-cost aqueous based secondary power sources in combination with zinc, lead oxide, and lead sulfate. The discharge capacity of the polypyrrole in the chloride-based electrolyte (for the Zn|PPy cell) is in the range 110 mAh g −1 of PPy, while in the sulfate-based electrolyte ∼150 mAh g −1 of PPy (for the PbSO 4 |PPy and PPy|PbO 2 cells), which is close to the theoretically calculated values. Electrochemical and electrical parameters, reactions in the cells, specific capacity, specific capacitance, energy, and power, for the Zn|PPy, PPy|PbO 2 and PbSO 4 |PPy cells are determined. In addition, the energy efficiency, for the considered systems is estimated. Obtained values of the specific power and energy, could classified investigated systems as a battery type hybrid superacapacitors or “supercapattery”. © 2019 Elsevier B.V.

Keywords:

lead oxide / lead sulfate / power / supercapattery / zinc

Source:
Materials Science and Engineering B: Solid-State Materials for Advanced Technology, 2019, 243, 175-182

Publisher:

Elsevier

DOI: 10.1016/j.mseb.2019.04.013

ISSN: 0921-5107

WoS: 000468720500021

Scopus: 2-s2.0-85064168813

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Handle

https://hdl.handle.net/21.15107/rcub_dais_5804

URI

https://dais.sanu.ac.rs/123456789/5804

Collections

ИТН САНУ - Општа колекција / ITS SASA - General collection

Institution/Community

Институт техничких наука САНУ / Institute of Technical Sciences of SASA

TY  - JOUR
AU  - Grgur, Branimir
AU  - Janačković, Marija
AU  - Jugović, Branimir
AU  - Gvozdenović, Milica M.
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/5804
AB  - The electrochemically synthesized polypyrrole (PPy) is investigated as a possible active material of the low-cost aqueous based secondary power sources in combination with zinc, lead oxide, and lead sulfate. The discharge capacity of the polypyrrole in the chloride-based electrolyte (for the Zn|PPy cell) is in the range 110 mAh g −1 of PPy, while in the sulfate-based electrolyte ∼150 mAh g −1 of PPy (for the PbSO 4 |PPy and PPy|PbO 2 cells), which is close to the theoretically calculated values. Electrochemical and electrical parameters, reactions in the cells, specific capacity, specific capacitance, energy, and power, for the Zn|PPy, PPy|PbO 2 and PbSO 4 |PPy cells are determined. In addition, the energy efficiency, for the considered systems is estimated. Obtained values of the specific power and energy, could classified investigated systems as a battery type hybrid superacapacitors or “supercapattery”. © 2019 Elsevier B.V.
PB  - Elsevier
T2  - Materials Science and Engineering B: Solid-State Materials for Advanced Technology
T1  - The initial characteristics of the polypyrrole based aqueous rechargeable batteries with supercapattery characteristics
SP  - 175
EP  - 182
VL  - 243
DO  - 10.1016/j.mseb.2019.04.013
UR  - https://hdl.handle.net/21.15107/rcub_dais_5804
ER  -

@article{
author = "Grgur, Branimir and Janačković, Marija and Jugović, Branimir and Gvozdenović, Milica M.",
year = "2019",
abstract = "The electrochemically synthesized polypyrrole (PPy) is investigated as a possible active material of the low-cost aqueous based secondary power sources in combination with zinc, lead oxide, and lead sulfate. The discharge capacity of the polypyrrole in the chloride-based electrolyte (for the Zn|PPy cell) is in the range 110 mAh g −1 of PPy, while in the sulfate-based electrolyte ∼150 mAh g −1 of PPy (for the PbSO 4 |PPy and PPy|PbO 2 cells), which is close to the theoretically calculated values. Electrochemical and electrical parameters, reactions in the cells, specific capacity, specific capacitance, energy, and power, for the Zn|PPy, PPy|PbO 2 and PbSO 4 |PPy cells are determined. In addition, the energy efficiency, for the considered systems is estimated. Obtained values of the specific power and energy, could classified investigated systems as a battery type hybrid superacapacitors or “supercapattery”. © 2019 Elsevier B.V.",
publisher = "Elsevier",
journal = "Materials Science and Engineering B: Solid-State Materials for Advanced Technology",
title = "The initial characteristics of the polypyrrole based aqueous rechargeable batteries with supercapattery characteristics",
pages = "175-182",
volume = "243",
doi = "10.1016/j.mseb.2019.04.013",
url = "https://hdl.handle.net/21.15107/rcub_dais_5804"
}

Grgur, B., Janačković, M., Jugović, B.,& Gvozdenović, M. M.. (2019). The initial characteristics of the polypyrrole based aqueous rechargeable batteries with supercapattery characteristics. in Materials Science and Engineering B: Solid-State Materials for Advanced Technology
Elsevier., 243, 175-182.
https://doi.org/10.1016/j.mseb.2019.04.013
https://hdl.handle.net/21.15107/rcub_dais_5804

Grgur B, Janačković M, Jugović B, Gvozdenović MM. The initial characteristics of the polypyrrole based aqueous rechargeable batteries with supercapattery characteristics. in Materials Science and Engineering B: Solid-State Materials for Advanced Technology. 2019;243:175-182.
doi:10.1016/j.mseb.2019.04.013
https://hdl.handle.net/21.15107/rcub_dais_5804 .

Grgur, Branimir, Janačković, Marija, Jugović, Branimir, Gvozdenović, Milica M., "The initial characteristics of the polypyrrole based aqueous rechargeable batteries with supercapattery characteristics" in Materials Science and Engineering B: Solid-State Materials for Advanced Technology, 243 (2019):175-182,
https://doi.org/10.1016/j.mseb.2019.04.013 .,
https://hdl.handle.net/21.15107/rcub_dais_5804 .