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TY - JOUR
AU - Stefanović, Ivan S.
AU - Dostanić, Jasmina
AU - Lončarević, Davor
AU - Vasiljević Radović, Dana
AU - Ostojić, Sanja
AU - Marković, Smilja
AU - Pergal, Marija V.
PY - 2019
UR - https://dais.sanu.ac.rs/123456789/5761
AB - This work is focused on preparation of poly(urethane-siloxane)/titanium-dioxide nanocomposites (PUSNs) with enhanced features. PUSNs were prepared by the in situ polymerization reaction using titanium-dioxide as a nano-filler in different amounts (1, 2, 3 and 5 wt.%) with respect to the poly(urethane-siloxane) (PUS) matrix. PUS copolymer was based on α,ω-dihy-droxy-ethoxypropyl-poly(dimethylsiloxane), 4,4’-methylenediphenyldiisocyanate and 1,4-bu-tanediole. In order to investigate the influence of TiO 2 content on the structure, UV resistance, thermal properties, hydrophobicity and morphology of the prepared PUSNs, FTIR spectroscopy, UV-Vis diffuse-reflectance spectroscopy, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), contact angle measurements, surface free energy (SFE) analysis, water absorption, scanning electron microscopy (SEM) and atomic force microscopy (AFM) were performed. The PUSNs showed excellent UV resistance, high hydrophobicity, low surface free energy and also higher thermal stability and rougher surface and cross-section relief structure as compared to the pure PUS copolymer. Based on the obtained results it can be concluded that prepared PUSNs could be potentially used as protective coatings. © 2019, Association of Chemists and Chemical Engineers of Serbia. All rights reserved.
PB - Association of the Chemical Engineers of Serbia
T2 - Hemijska industrija
T1 - Preparation and characterization of poly(Urethane-siloxane)/titanium-dioxide nanocomposites
SP - 13
EP - 24
VL - 73
IS - 1
DO - 10.2298/HEMIND180530002S
UR - https://hdl.handle.net/21.15107/rcub_dais_5761
ER -
@article{
author = "Stefanović, Ivan S. and Dostanić, Jasmina and Lončarević, Davor and Vasiljević Radović, Dana and Ostojić, Sanja and Marković, Smilja and Pergal, Marija V.",
year = "2019",
abstract = "This work is focused on preparation of poly(urethane-siloxane)/titanium-dioxide nanocomposites (PUSNs) with enhanced features. PUSNs were prepared by the in situ polymerization reaction using titanium-dioxide as a nano-filler in different amounts (1, 2, 3 and 5 wt.%) with respect to the poly(urethane-siloxane) (PUS) matrix. PUS copolymer was based on α,ω-dihy-droxy-ethoxypropyl-poly(dimethylsiloxane), 4,4’-methylenediphenyldiisocyanate and 1,4-bu-tanediole. In order to investigate the influence of TiO 2 content on the structure, UV resistance, thermal properties, hydrophobicity and morphology of the prepared PUSNs, FTIR spectroscopy, UV-Vis diffuse-reflectance spectroscopy, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), contact angle measurements, surface free energy (SFE) analysis, water absorption, scanning electron microscopy (SEM) and atomic force microscopy (AFM) were performed. The PUSNs showed excellent UV resistance, high hydrophobicity, low surface free energy and also higher thermal stability and rougher surface and cross-section relief structure as compared to the pure PUS copolymer. Based on the obtained results it can be concluded that prepared PUSNs could be potentially used as protective coatings. © 2019, Association of Chemists and Chemical Engineers of Serbia. All rights reserved.",
publisher = "Association of the Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Preparation and characterization of poly(Urethane-siloxane)/titanium-dioxide nanocomposites",
pages = "13-24",
volume = "73",
number = "1",
doi = "10.2298/HEMIND180530002S",
url = "https://hdl.handle.net/21.15107/rcub_dais_5761"
}
Stefanović, I. S., Dostanić, J., Lončarević, D., Vasiljević Radović, D., Ostojić, S., Marković, S.,& Pergal, M. V.. (2019). Preparation and characterization of poly(Urethane-siloxane)/titanium-dioxide nanocomposites. in Hemijska industrija
Association of the Chemical Engineers of Serbia., 73(1), 13-24.
https://doi.org/10.2298/HEMIND180530002S
https://hdl.handle.net/21.15107/rcub_dais_5761
Stefanović IS, Dostanić J, Lončarević D, Vasiljević Radović D, Ostojić S, Marković S, Pergal MV. Preparation and characterization of poly(Urethane-siloxane)/titanium-dioxide nanocomposites. in Hemijska industrija. 2019;73(1):13-24.
doi:10.2298/HEMIND180530002S
https://hdl.handle.net/21.15107/rcub_dais_5761 .
Stefanović, Ivan S., Dostanić, Jasmina, Lončarević, Davor, Vasiljević Radović, Dana, Ostojić, Sanja, Marković, Smilja, Pergal, Marija V., "Preparation and characterization of poly(Urethane-siloxane)/titanium-dioxide nanocomposites" in Hemijska industrija, 73, no. 1 (2019):13-24,
https://doi.org/10.2298/HEMIND180530002S .,
https://hdl.handle.net/21.15107/rcub_dais_5761 .
