Electrochemical behavior of polyaniline in chloride/citrate electrolyte

2011
Authors
Jugović, Branimir
Gvozdenović, Milica M.

Trišović, Tomislav

Stevanović, Jasmina S.

Grgur, Branimir

Contributors
Markoš, JozefConference object (Published version)
Metadata
Show full item recordAbstract
Polyaniline electrode, was obtained by electrochemical polymerization at constant current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl containing 0.25 mol dm-3 aniline. Electrochemical characterization of the polyaniline electrode in chloride and chloride/citrate electrolyte, for different anodic potential limits, was performed using cyclic voltammetry and galvanostatic measurements. It was observed that for anodic potential 0.32 V, higher electrode capacity in chloride/citrate was obtained. For anodic potential limit of 0.50 V, faster decrease of the
electrode capacity in chloride/citrate electrolyte was also observed. It was suggested that influence of both chloride and citrate anions has to be taken into account.
Keywords:
polyaniline / chloride and citrate electrolyte / polymers / electrochemical techniques / electrochemical propertiesSource:
Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering, 2011, 963-967Publisher:
- Tatranské Matliare : Slovak Society of Chemical Engineering
Funding / projects:
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - CONF AU - Jugović, Branimir AU - Gvozdenović, Milica M. AU - Trišović, Tomislav AU - Stevanović, Jasmina S. AU - Grgur, Branimir PY - 2011 UR - https://dais.sanu.ac.rs/123456789/548 AB - Polyaniline electrode, was obtained by electrochemical polymerization at constant current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl containing 0.25 mol dm-3 aniline. Electrochemical characterization of the polyaniline electrode in chloride and chloride/citrate electrolyte, for different anodic potential limits, was performed using cyclic voltammetry and galvanostatic measurements. It was observed that for anodic potential 0.32 V, higher electrode capacity in chloride/citrate was obtained. For anodic potential limit of 0.50 V, faster decrease of the electrode capacity in chloride/citrate electrolyte was also observed. It was suggested that influence of both chloride and citrate anions has to be taken into account. PB - Tatranské Matliare : Slovak Society of Chemical Engineering C3 - Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering T1 - Electrochemical behavior of polyaniline in chloride/citrate electrolyte SP - 963 EP - 967 UR - https://hdl.handle.net/21.15107/rcub_dais_548 ER -
@conference{ author = "Jugović, Branimir and Gvozdenović, Milica M. and Trišović, Tomislav and Stevanović, Jasmina S. and Grgur, Branimir", year = "2011", abstract = "Polyaniline electrode, was obtained by electrochemical polymerization at constant current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl containing 0.25 mol dm-3 aniline. Electrochemical characterization of the polyaniline electrode in chloride and chloride/citrate electrolyte, for different anodic potential limits, was performed using cyclic voltammetry and galvanostatic measurements. It was observed that for anodic potential 0.32 V, higher electrode capacity in chloride/citrate was obtained. For anodic potential limit of 0.50 V, faster decrease of the electrode capacity in chloride/citrate electrolyte was also observed. It was suggested that influence of both chloride and citrate anions has to be taken into account.", publisher = "Tatranské Matliare : Slovak Society of Chemical Engineering", journal = "Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering", title = "Electrochemical behavior of polyaniline in chloride/citrate electrolyte", pages = "963-967", url = "https://hdl.handle.net/21.15107/rcub_dais_548" }
Jugović, B., Gvozdenović, M. M., Trišović, T., Stevanović, J. S.,& Grgur, B.. (2011). Electrochemical behavior of polyaniline in chloride/citrate electrolyte. in Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering Tatranské Matliare : Slovak Society of Chemical Engineering., 963-967. https://hdl.handle.net/21.15107/rcub_dais_548
Jugović B, Gvozdenović MM, Trišović T, Stevanović JS, Grgur B. Electrochemical behavior of polyaniline in chloride/citrate electrolyte. in Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering. 2011;:963-967. https://hdl.handle.net/21.15107/rcub_dais_548 .
Jugović, Branimir, Gvozdenović, Milica M., Trišović, Tomislav, Stevanović, Jasmina S., Grgur, Branimir, "Electrochemical behavior of polyaniline in chloride/citrate electrolyte" in Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering (2011):963-967, https://hdl.handle.net/21.15107/rcub_dais_548 .