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The influence of m-aminobenzoic acid on electrochemical synthesis and behavior of poly(aniline-co-(m-aminobenzoic acid)

Authorized Users Only
2017
Authors
Jokić, Bojan
Džunuzovic, Enis
Grgur, Branimir
Jugović, Branimir
Trišović, Tomislav
Stevanović, Jasmina S.
Gvozdenovic, Milica M.
Article (Published version)
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Abstract
Poly(aniline-co-(m-aminobenzoic acid)) was synthesized electrochemically at graphite electrode under galvanostatic conditions. Aqueous electrolyte for synthesis was consisted of HCl and different amount of aniline and m-aminobenzoic acid. The presence of the meta positioned carboxylic group in m-aminobenzoic acid influenced higher co-polymerization potential, different morphology and electrochemical behavior of copolymers compared to polyaniline. Electrochemical activity is achieved by proton exchange in neutral environment that can result in a faster charge/discharge process, which is in the case of PANI limited by slow anion exchange, making this material promising for consideration in super-capacitors and in biological system.
Keywords:
electrochemical co-polymerization / cyclic voltammetry / poly(aniline-co-(m-aminobenzoic acid) / UV-vis spectroscopy
Source:
Journal of Polymer Research, 2017, 24, 9, 146-
Publisher:
  • Springer, Dordrecht
Funding / projects:
  • Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies (RS-172046)
  • Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-45019)

DOI: 10.1007/s10965-017-1313-5

ISSN: 1022-9760

WoS: 000408478900001

Scopus: 2-s2.0-85028326537
[ Google Scholar ]
5
3
Handle
https://hdl.handle.net/21.15107/rcub_dais_4843
URI
https://dais.sanu.ac.rs/123456789/4843
Collections
  • ИТН САНУ - Општа колекција / ITS SASA - General collection
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASA
TY  - JOUR
AU  - Jokić, Bojan
AU  - Džunuzovic, Enis
AU  - Grgur, Branimir
AU  - Jugović, Branimir
AU  - Trišović, Tomislav
AU  - Stevanović, Jasmina S.
AU  - Gvozdenovic, Milica M.
PY  - 2017
UR  - https://dais.sanu.ac.rs/123456789/4843
AB  - Poly(aniline-co-(m-aminobenzoic acid)) was synthesized electrochemically at graphite electrode under galvanostatic conditions. Aqueous electrolyte for synthesis was consisted of HCl and different amount of aniline and m-aminobenzoic acid. The presence of the meta positioned carboxylic group in m-aminobenzoic acid influenced higher co-polymerization potential, different morphology and electrochemical behavior of copolymers compared to polyaniline. Electrochemical activity is achieved by proton exchange in neutral environment that can result in a faster charge/discharge process, which is in the case of PANI limited by slow anion exchange, making this material promising for consideration in super-capacitors and in biological system.
PB  - Springer, Dordrecht
T2  - Journal of Polymer Research
T1  - The influence of m-aminobenzoic acid on electrochemical synthesis and behavior of poly(aniline-co-(m-aminobenzoic acid)
SP  - 146
VL  - 24
IS  - 9
DO  - 10.1007/s10965-017-1313-5
UR  - https://hdl.handle.net/21.15107/rcub_dais_4843
ER  - 
@article{
author = "Jokić, Bojan and Džunuzovic, Enis and Grgur, Branimir and Jugović, Branimir and Trišović, Tomislav and Stevanović, Jasmina S. and Gvozdenovic, Milica M.",
year = "2017",
abstract = "Poly(aniline-co-(m-aminobenzoic acid)) was synthesized electrochemically at graphite electrode under galvanostatic conditions. Aqueous electrolyte for synthesis was consisted of HCl and different amount of aniline and m-aminobenzoic acid. The presence of the meta positioned carboxylic group in m-aminobenzoic acid influenced higher co-polymerization potential, different morphology and electrochemical behavior of copolymers compared to polyaniline. Electrochemical activity is achieved by proton exchange in neutral environment that can result in a faster charge/discharge process, which is in the case of PANI limited by slow anion exchange, making this material promising for consideration in super-capacitors and in biological system.",
publisher = "Springer, Dordrecht",
journal = "Journal of Polymer Research",
title = "The influence of m-aminobenzoic acid on electrochemical synthesis and behavior of poly(aniline-co-(m-aminobenzoic acid)",
pages = "146",
volume = "24",
number = "9",
doi = "10.1007/s10965-017-1313-5",
url = "https://hdl.handle.net/21.15107/rcub_dais_4843"
}
Jokić, B., Džunuzovic, E., Grgur, B., Jugović, B., Trišović, T., Stevanović, J. S.,& Gvozdenovic, M. M.. (2017). The influence of m-aminobenzoic acid on electrochemical synthesis and behavior of poly(aniline-co-(m-aminobenzoic acid). in Journal of Polymer Research
Springer, Dordrecht., 24(9), 146.
https://doi.org/10.1007/s10965-017-1313-5
https://hdl.handle.net/21.15107/rcub_dais_4843
Jokić B, Džunuzovic E, Grgur B, Jugović B, Trišović T, Stevanović JS, Gvozdenovic MM. The influence of m-aminobenzoic acid on electrochemical synthesis and behavior of poly(aniline-co-(m-aminobenzoic acid). in Journal of Polymer Research. 2017;24(9):146.
doi:10.1007/s10965-017-1313-5
https://hdl.handle.net/21.15107/rcub_dais_4843 .
Jokić, Bojan, Džunuzovic, Enis, Grgur, Branimir, Jugović, Branimir, Trišović, Tomislav, Stevanović, Jasmina S., Gvozdenovic, Milica M., "The influence of m-aminobenzoic acid on electrochemical synthesis and behavior of poly(aniline-co-(m-aminobenzoic acid)" in Journal of Polymer Research, 24, no. 9 (2017):146,
https://doi.org/10.1007/s10965-017-1313-5 .,
https://hdl.handle.net/21.15107/rcub_dais_4843 .

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