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Catalytic combustion of methane over Pd containing perovskite type oxides
dc.creator | Petrović, Srđan | |
dc.creator | Karanović, Ljiljana | |
dc.creator | Stefanov, Plamen K. | |
dc.creator | Zdujić, Miodrag | |
dc.creator | Terlecki Baričević, Ana | |
dc.date.accessioned | 2019-02-03T16:49:30Z | |
dc.date.available | 2019-02-03T16:49:30Z | |
dc.date.issued | 2005 | |
dc.identifier.issn | 0926-3373 | |
dc.identifier.uri | https://dais.sanu.ac.rs/123456789/4838 | |
dc.description.abstract | The mixed perovskite type oxides with nominal formula LaTi0.5Mg0.5-xPdxO3, (0 LT = x LT = 0.10) were prepared by anneling the ethanol solution of precursor in nitrogen flow at 1200 degrees C. X-ray powder diffraction (XRPD) analysis shows that the orthorhombic perovskite structure was found in all investigated samples. However, at least a part of palladium is not incorporated into perovskite structure and remains as separate phase, which is reduced to Pd-0 at 1200 degrees C. X-ray photoelectron spectroscopy (XPS) reveled the presence of Pd2+, which indicate a reoxidation of Pd-0 in the surface layers during cooling. The Pd content in the samples has a small influence on the methane oxidation activity below the temperature of 500 degrees C. At temperatures higher than 500 C, the methane oxidation activity of the sample with x = 0.05 exceeds the activity of the sample with x = 0.10. The sharp increase of methane oxidation activity over the sample with lower content of palladium at about 500 degrees C was ascribed to the higher dispersion of PdO and Pd-0 phases. Thus, the higher contribution of lattice oxygen and possible local change in oxidation state of palladium can be a reason for the enhanced activity. Contrary to the supported Pd/Al2O3 catalyst, the incorporation of palladium into perovskite matrix and interaction of PdO-Pd-0 benefits the activity of smaller particles at higher reaction temperatures. | en |
dc.publisher | Elsevier Science Bv, Amsterdam | |
dc.rights | restrictedAccess | |
dc.source | Applied Catalysis B: Environmental | |
dc.subject | XPS | en |
dc.subject | perovskite | en |
dc.subject | catalytic combustion | en |
dc.title | Catalytic combustion of methane over Pd containing perovskite type oxides | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Петровић, Срђан; Карановић, Љиљана; Здујић, Миодраг; Стефанов, Пламен К.; Терлецки Баричевић, Aна; | |
dc.citation.spage | 133 | |
dc.citation.epage | 141 | |
dc.citation.volume | 58 | |
dc.citation.issue | 1-2 | |
dc.identifier.wos | 000229514800016 | |
dc.identifier.doi | 10.1016/j.apcatb.2004.11.020 | |
dc.identifier.scopus | 2-s2.0-18544382870 | |
dc.type.version | publishedVersion | |
dc.citation.other | 58(1-2): 133-141 | |
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_dais_4838 |