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Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films

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2018
peles2018.pdf (1.505Mb)
Authors
Peleš, Adriana
Aleksić, Obrad S.
Pavlović, Vera P.
Đoković, Vladimir
Dojčilović, Radovan
Nikolić, Z.
Marinković, F.
Mitrić, Miodrag
Blagojević, Vladimir A.
Vlahović, Branislav
Pavlović, Vladimir B.
Article (Accepted Version)
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Abstract
The influence of the mechanical activation of ZnO nanoparticle fillers on the structural and electrical properties of the matrix of poly(vinylidenefluoride)-ZnO (PVDF-ZnO) films was investigated. Transmission electron microscopy and scanning electron microscopy analyses showed that mechanical activation in a high energy planetary ball mill reduces the size of ZnO particles. X-ray diffraction and Raman spectroscopy revealed that PVDF crystallized predominantly as the γ-phase. Non-activated ZnO filler reduces the degree of the crystallinity of the matrix and promotes crystallization of α-phase of PVDF in the film, while the fillers activated for 5 and 10 min induce crystallization of β-phase, indicating that mechanical activation of the filler can be used as a general method for fabrication of PVDF composites with increased content of piezoelectric β-phase crystals. Dielectric spectroscopy measurements show that polymer composite with the high content of β-phase (with ZnO filler activate...d for 5 min) exhibits the highest value of dielectric permittivity in 150-400 K range of temperatures. Kinetic analysis shows combined effects of increased surface area and increased concentration of surface defects on the interactions between polymer chains and activated nanoparticles. © 2018 IOP Publishing Ltd.

Keywords:
crystallization / dielectric properties / mechanical activation / polymer composites / PVDF / ZnO
Source:
Physica Scripta, 2018, 93, 105801-
Publisher:
  • IOP Publishing
Funding / projects:
  • Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites (RS-172056)
  • Directed synthesis, structure and properties of multifunctional materials (RS-172057)
  • United States National Science Foundation (NSF) / Centers of Research Excellence in Science and Technology (CREST), Grant HRD-0833184
  • United States National Aeronautics and Space Administration (NASA), Grant NNX09AV07A
Note:
  • This is the peer-reviewed version of the article: Peleš, A., Aleksić, O., Pavlović, V.P., Djoković, V., Dojčilović, R., Nikolić, Z., Marinković, F., Mitrić, M., Blagojević, V., Vlahović, B., Pavlović, V.B., 2018. Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films. Physica Scripta 93. https://doi.org/10.1088/1402-4896/aad749

DOI: 10.1088/1402-4896/aad749

ISSN: 0031-8949 (Print); 1402-4896 (Online)

WoS: 000442645300001

Scopus: 2-s2.0-85054040483
[ Google Scholar ]
13
12
Handle
https://hdl.handle.net/21.15107/rcub_dais_4608
URI
https://dais.sanu.ac.rs/123456789/4608
Collections
  • ИТН САНУ - Општа колекција / ITS SASA - General collection
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASA
TY  - JOUR
AU  - Peleš, Adriana
AU  - Aleksić, Obrad S.
AU  - Pavlović, Vera P.
AU  - Đoković, Vladimir
AU  - Dojčilović, Radovan
AU  - Nikolić, Z.
AU  - Marinković, F.
AU  - Mitrić, Miodrag
AU  - Blagojević, Vladimir A.
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2018
UR  - https://dais.sanu.ac.rs/123456789/4608
AB  - The influence of the mechanical activation of ZnO nanoparticle fillers on the structural and electrical properties of the matrix of poly(vinylidenefluoride)-ZnO (PVDF-ZnO) films was investigated. Transmission electron microscopy and scanning electron microscopy analyses showed that mechanical activation in a high energy planetary ball mill reduces the size of ZnO particles. X-ray diffraction and Raman spectroscopy revealed that PVDF crystallized predominantly as the γ-phase. Non-activated ZnO filler reduces the degree of the crystallinity of the matrix and promotes crystallization of α-phase of PVDF in the film, while the fillers activated for 5 and 10 min induce crystallization of β-phase, indicating that mechanical activation of the filler can be used as a general method for fabrication of PVDF composites with increased content of piezoelectric β-phase crystals. Dielectric spectroscopy measurements show that polymer composite with the high content of β-phase (with ZnO filler activated for 5 min) exhibits the highest value of dielectric permittivity in 150-400 K range of temperatures. Kinetic analysis shows combined effects of increased surface area and increased concentration of surface defects on the interactions between polymer chains and activated nanoparticles. © 2018 IOP Publishing Ltd.
PB  - IOP Publishing
T2  - Physica Scripta
T1  - Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films
SP  - 105801
VL  - 93
DO  - 10.1088/1402-4896/aad749
UR  - https://hdl.handle.net/21.15107/rcub_dais_4608
ER  - 
@article{
author = "Peleš, Adriana and Aleksić, Obrad S. and Pavlović, Vera P. and Đoković, Vladimir and Dojčilović, Radovan and Nikolić, Z. and Marinković, F. and Mitrić, Miodrag and Blagojević, Vladimir A. and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2018",
abstract = "The influence of the mechanical activation of ZnO nanoparticle fillers on the structural and electrical properties of the matrix of poly(vinylidenefluoride)-ZnO (PVDF-ZnO) films was investigated. Transmission electron microscopy and scanning electron microscopy analyses showed that mechanical activation in a high energy planetary ball mill reduces the size of ZnO particles. X-ray diffraction and Raman spectroscopy revealed that PVDF crystallized predominantly as the γ-phase. Non-activated ZnO filler reduces the degree of the crystallinity of the matrix and promotes crystallization of α-phase of PVDF in the film, while the fillers activated for 5 and 10 min induce crystallization of β-phase, indicating that mechanical activation of the filler can be used as a general method for fabrication of PVDF composites with increased content of piezoelectric β-phase crystals. Dielectric spectroscopy measurements show that polymer composite with the high content of β-phase (with ZnO filler activated for 5 min) exhibits the highest value of dielectric permittivity in 150-400 K range of temperatures. Kinetic analysis shows combined effects of increased surface area and increased concentration of surface defects on the interactions between polymer chains and activated nanoparticles. © 2018 IOP Publishing Ltd.",
publisher = "IOP Publishing",
journal = "Physica Scripta",
title = "Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films",
pages = "105801",
volume = "93",
doi = "10.1088/1402-4896/aad749",
url = "https://hdl.handle.net/21.15107/rcub_dais_4608"
}
Peleš, A., Aleksić, O. S., Pavlović, V. P., Đoković, V., Dojčilović, R., Nikolić, Z., Marinković, F., Mitrić, M., Blagojević, V. A., Vlahović, B.,& Pavlović, V. B.. (2018). Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films. in Physica Scripta
IOP Publishing., 93, 105801.
https://doi.org/10.1088/1402-4896/aad749
https://hdl.handle.net/21.15107/rcub_dais_4608
Peleš A, Aleksić OS, Pavlović VP, Đoković V, Dojčilović R, Nikolić Z, Marinković F, Mitrić M, Blagojević VA, Vlahović B, Pavlović VB. Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films. in Physica Scripta. 2018;93:105801.
doi:10.1088/1402-4896/aad749
https://hdl.handle.net/21.15107/rcub_dais_4608 .
Peleš, Adriana, Aleksić, Obrad S., Pavlović, Vera P., Đoković, Vladimir, Dojčilović, Radovan, Nikolić, Z., Marinković, F., Mitrić, Miodrag, Blagojević, Vladimir A., Vlahović, Branislav, Pavlović, Vladimir B., "Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films" in Physica Scripta, 93 (2018):105801,
https://doi.org/10.1088/1402-4896/aad749 .,
https://hdl.handle.net/21.15107/rcub_dais_4608 .

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