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Structural and magnetic properties of Y1-xYbxF3 solid solution

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2018
Aleksic-ACA-VII.pdf (1.034Mb)
Authors
Aleksić, Jelena
Barudžija, Tanja
Mitrić, Miodrag
Jugović, Dragana
Kostić, Ljiljana
Conference object (Published version)
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Abstract
In this work, the polycrystalline samples Y1-xYbxF3 (x = 0.01, 0.05, 0.1, 0.25, 0.5, 0.75 and 1) were synthesized and characterized by X-ray powder diffraction and magnetic measurements. In the first stage of synthesis, mixed sesquioxides (Y1-xYbx)2O3 were obtained by ceramic technology. In the second stage, obtained mixed sesquioxides were treated with an excess of ammonium hydrogen fluoride in air at 170 °C for 20 h. In the third and last stage, Y1-xYbxF3 samples were obtained by heating the product from the second stage of synthesis at 500 °C for 3 h in an inert atmosphere. The X-ray diffraction revealed that the crystal structure of the Y1-xYbxF3 solid solution is orthorhombic (YF3 structural type). The structure refinements were done by the Rietveld full-profile method within Pnma space group. Magnetic susceptibility measurements of all samples were done in a temperature range 2-300 K by SQUID magnetometer. The relation between magnetic and structural properties was discussed.
Keywords:
Y1-xYbxF3 / magnetic properties / structural analysis / X-ray powder diffraction / crystal structure
Source:
Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018, 2018, 99-99
Publisher:
  • Belgrade : Serbian Ceramic Society
Funding / projects:
  • Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes (RS-45001)
  • Magnetic and radionuclide labeled nanostructured materials for medical applications (RS-45015)

ISBN: 978-86-915627-6-2

[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_dais_4092
URI
https://dais.sanu.ac.rs/123456789/4092
Collections
  • ИТН САНУ - Општа колекција / ITS SASA - General collection
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASA
TY  - CONF
AU  - Aleksić, Jelena
AU  - Barudžija, Tanja
AU  - Mitrić, Miodrag
AU  - Jugović, Dragana
AU  - Kostić, Ljiljana
PY  - 2018
UR  - https://dais.sanu.ac.rs/123456789/4092
AB  - In this work, the polycrystalline samples Y1-xYbxF3 (x = 0.01, 0.05, 0.1, 0.25, 0.5, 0.75 and 1) were synthesized and characterized by X-ray powder diffraction and magnetic measurements. In the first stage of synthesis, mixed sesquioxides (Y1-xYbx)2O3 were obtained by ceramic technology. In the second stage, obtained mixed sesquioxides were treated with an excess of ammonium hydrogen fluoride in air at 170 °C for 20 h. In the third and last stage, Y1-xYbxF3 samples were obtained by heating the product from the second stage of synthesis at 500 °C for 3 h in an inert atmosphere. The X-ray diffraction revealed that the crystal structure of the Y1-xYbxF3 solid solution is orthorhombic (YF3 structural type). The structure refinements were done by the Rietveld full-profile method within Pnma space group. Magnetic susceptibility measurements of all samples were done in a temperature range 2-300 K by SQUID magnetometer. The relation between magnetic and structural properties was discussed.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018
T1  - Structural and magnetic properties of Y1-xYbxF3 solid solution
SP  - 99
EP  - 99
UR  - https://hdl.handle.net/21.15107/rcub_dais_4092
ER  - 
@conference{
author = "Aleksić, Jelena and Barudžija, Tanja and Mitrić, Miodrag and Jugović, Dragana and Kostić, Ljiljana",
year = "2018",
abstract = "In this work, the polycrystalline samples Y1-xYbxF3 (x = 0.01, 0.05, 0.1, 0.25, 0.5, 0.75 and 1) were synthesized and characterized by X-ray powder diffraction and magnetic measurements. In the first stage of synthesis, mixed sesquioxides (Y1-xYbx)2O3 were obtained by ceramic technology. In the second stage, obtained mixed sesquioxides were treated with an excess of ammonium hydrogen fluoride in air at 170 °C for 20 h. In the third and last stage, Y1-xYbxF3 samples were obtained by heating the product from the second stage of synthesis at 500 °C for 3 h in an inert atmosphere. The X-ray diffraction revealed that the crystal structure of the Y1-xYbxF3 solid solution is orthorhombic (YF3 structural type). The structure refinements were done by the Rietveld full-profile method within Pnma space group. Magnetic susceptibility measurements of all samples were done in a temperature range 2-300 K by SQUID magnetometer. The relation between magnetic and structural properties was discussed.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018",
title = "Structural and magnetic properties of Y1-xYbxF3 solid solution",
pages = "99-99",
url = "https://hdl.handle.net/21.15107/rcub_dais_4092"
}
Aleksić, J., Barudžija, T., Mitrić, M., Jugović, D.,& Kostić, L.. (2018). Structural and magnetic properties of Y1-xYbxF3 solid solution. in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018
Belgrade : Serbian Ceramic Society., 99-99.
https://hdl.handle.net/21.15107/rcub_dais_4092
Aleksić J, Barudžija T, Mitrić M, Jugović D, Kostić L. Structural and magnetic properties of Y1-xYbxF3 solid solution. in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018. 2018;:99-99.
https://hdl.handle.net/21.15107/rcub_dais_4092 .
Aleksić, Jelena, Barudžija, Tanja, Mitrić, Miodrag, Jugović, Dragana, Kostić, Ljiljana, "Structural and magnetic properties of Y1-xYbxF3 solid solution" in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018 (2018):99-99,
https://hdl.handle.net/21.15107/rcub_dais_4092 .

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