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Continuous biodiesel production under subcritical condition of methanol – Design of pilot plant and packed bed reactor with MnCO3/Na-silicate catalyst

Authorized Users Only
2018
Authors
Liu, Hui
Lukić, Ivana
Miladinović, Marija R.
Veljković, Vlada B.
Zdujić, Miodrag
Zhu, Xiaosun
Zhang, Yanan
Skala, Dejan
Article (Published version)
Metadata
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Abstract
The continuous biodiesel production from soybean oil was carried out under the subcritical condition of methanol with MnCO3/Na-silicate as a heterogeneous catalyst. The transesterification rate was first investigated in a set of experiments performed in a batch autoclave at 448 K using methanol-to-oil molar ratio of 18:1 and various catalyst loadings (5, 10 and 20 wt% based on the oil mass). The results from these experiments, as well as the experimental data and the appropriate kinetic model recently reported in the literature were used for designing a packed bed tubular reactor (PBTR), a main unit of the pilot plant with the capacity of 100 L of biodiesel per day. The pilot plant was constructed and tested under various operating conditions. The first 11 h of the pilot-plant operation was realized in the tubular reactor packed with inert glass beads (i.e. without the catalyst) in order to analyze the effect of the non-catalyzed subcritical biodiesel (fatty acid methyl esters, FAME) p...roduction. Then, glass beads were replaced with a mix of MnCO3/Na-silicate catalyst particles and glass beads, and the catalytic biodiesel production was continuously run under the subcritical methanol condition for 85 h. Two mass balance tests during the continuous pilot plant operation were performed. © 2018 Elsevier Ltd

Keywords:
biodiesel / kinetic modeling / MnCO3/Na-silicate catalyst / pilot-plant design / subcritical methanolysis
Source:
Energy Conversion and Management, 2018, 168, 494-504
Publisher:
  • Elsevier
Funding / projects:
  • Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes (RS-45001)
  • International S&T Cooperation Program of China - Grant No. 2013DFG92250

DOI: 10.1016/j.enconman.2018.05.028

ISSN: 0196-8904

WoS: 000435619500040

Scopus: 2-s2.0-85047264849
[ Google Scholar ]
4
4
Handle
https://hdl.handle.net/21.15107/rcub_dais_3701
URI
https://dais.sanu.ac.rs/123456789/3701
Collections
  • ИТН САНУ - Општа колекција / ITS SASA - General collection
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASA
TY  - JOUR
AU  - Liu, Hui
AU  - Lukić, Ivana
AU  - Miladinović, Marija R.
AU  - Veljković, Vlada B.
AU  - Zdujić, Miodrag
AU  - Zhu, Xiaosun
AU  - Zhang, Yanan
AU  - Skala, Dejan
PY  - 2018
UR  - https://dais.sanu.ac.rs/123456789/3701
AB  - The continuous biodiesel production from soybean oil was carried out under the subcritical condition of methanol with MnCO3/Na-silicate as a heterogeneous catalyst. The transesterification rate was first investigated in a set of experiments performed in a batch autoclave at 448 K using methanol-to-oil molar ratio of 18:1 and various catalyst loadings (5, 10 and 20 wt% based on the oil mass). The results from these experiments, as well as the experimental data and the appropriate kinetic model recently reported in the literature were used for designing a packed bed tubular reactor (PBTR), a main unit of the pilot plant with the capacity of 100 L of biodiesel per day. The pilot plant was constructed and tested under various operating conditions. The first 11 h of the pilot-plant operation was realized in the tubular reactor packed with inert glass beads (i.e. without the catalyst) in order to analyze the effect of the non-catalyzed subcritical biodiesel (fatty acid methyl esters, FAME) production. Then, glass beads were replaced with a mix of MnCO3/Na-silicate catalyst particles and glass beads, and the catalytic biodiesel production was continuously run under the subcritical methanol condition for 85 h. Two mass balance tests during the continuous pilot plant operation were performed. © 2018 Elsevier Ltd
PB  - Elsevier
T2  - Energy Conversion and Management
T1  - Continuous biodiesel production under subcritical condition of methanol – Design of pilot plant and packed bed reactor with MnCO3/Na-silicate catalyst
SP  - 494
EP  - 504
VL  - 168
DO  - 10.1016/j.enconman.2018.05.028
UR  - https://hdl.handle.net/21.15107/rcub_dais_3701
ER  - 
@article{
author = "Liu, Hui and Lukić, Ivana and Miladinović, Marija R. and Veljković, Vlada B. and Zdujić, Miodrag and Zhu, Xiaosun and Zhang, Yanan and Skala, Dejan",
year = "2018",
abstract = "The continuous biodiesel production from soybean oil was carried out under the subcritical condition of methanol with MnCO3/Na-silicate as a heterogeneous catalyst. The transesterification rate was first investigated in a set of experiments performed in a batch autoclave at 448 K using methanol-to-oil molar ratio of 18:1 and various catalyst loadings (5, 10 and 20 wt% based on the oil mass). The results from these experiments, as well as the experimental data and the appropriate kinetic model recently reported in the literature were used for designing a packed bed tubular reactor (PBTR), a main unit of the pilot plant with the capacity of 100 L of biodiesel per day. The pilot plant was constructed and tested under various operating conditions. The first 11 h of the pilot-plant operation was realized in the tubular reactor packed with inert glass beads (i.e. without the catalyst) in order to analyze the effect of the non-catalyzed subcritical biodiesel (fatty acid methyl esters, FAME) production. Then, glass beads were replaced with a mix of MnCO3/Na-silicate catalyst particles and glass beads, and the catalytic biodiesel production was continuously run under the subcritical methanol condition for 85 h. Two mass balance tests during the continuous pilot plant operation were performed. © 2018 Elsevier Ltd",
publisher = "Elsevier",
journal = "Energy Conversion and Management",
title = "Continuous biodiesel production under subcritical condition of methanol – Design of pilot plant and packed bed reactor with MnCO3/Na-silicate catalyst",
pages = "494-504",
volume = "168",
doi = "10.1016/j.enconman.2018.05.028",
url = "https://hdl.handle.net/21.15107/rcub_dais_3701"
}
Liu, H., Lukić, I., Miladinović, M. R., Veljković, V. B., Zdujić, M., Zhu, X., Zhang, Y.,& Skala, D.. (2018). Continuous biodiesel production under subcritical condition of methanol – Design of pilot plant and packed bed reactor with MnCO3/Na-silicate catalyst. in Energy Conversion and Management
Elsevier., 168, 494-504.
https://doi.org/10.1016/j.enconman.2018.05.028
https://hdl.handle.net/21.15107/rcub_dais_3701
Liu H, Lukić I, Miladinović MR, Veljković VB, Zdujić M, Zhu X, Zhang Y, Skala D. Continuous biodiesel production under subcritical condition of methanol – Design of pilot plant and packed bed reactor with MnCO3/Na-silicate catalyst. in Energy Conversion and Management. 2018;168:494-504.
doi:10.1016/j.enconman.2018.05.028
https://hdl.handle.net/21.15107/rcub_dais_3701 .
Liu, Hui, Lukić, Ivana, Miladinović, Marija R., Veljković, Vlada B., Zdujić, Miodrag, Zhu, Xiaosun, Zhang, Yanan, Skala, Dejan, "Continuous biodiesel production under subcritical condition of methanol – Design of pilot plant and packed bed reactor with MnCO3/Na-silicate catalyst" in Energy Conversion and Management, 168 (2018):494-504,
https://doi.org/10.1016/j.enconman.2018.05.028 .,
https://hdl.handle.net/21.15107/rcub_dais_3701 .

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