DAIS - Digital Archive of the Serbian Academy of Sciences and Arts
    • English
    • Српски
    • Српски (Serbia)
  • English 
    • English
    • Serbian (Cyrillic)
    • Serbian (Latin)
  • Login
View Item 
  •   DAIS
  • Институт техничких наука САНУ / Institute of Technical Sciences of SASA
  • ИТН САНУ - Општа колекција / ITS SASA - General collection
  • View Item
  •   DAIS
  • Институт техничких наука САНУ / Institute of Technical Sciences of SASA
  • ИТН САНУ - Општа колекција / ITS SASA - General collection
  • View Item
JavaScript is disabled for your browser. Some features of this site may not work without it.

Effect of the vinyl modification of multi-walled carbon nanotubes on the performances of waste poly(ethylene terephthalate)-based nanocomposites

Authorized Users Only
2017
Authors
Tasić, Ana
Rusmirović, Jelena
Nikolić, Jovana
Božić, Aleksandra
Pavlović, Vladimir B.
Marinković, Aleksandar D.
Uskoković, Petar S.
Article (Published version)
Metadata
Show full item record
Abstract
Production of high-performance nanocomposite materials obtained from unsaturated polyester resin, based on products of the waste poly(ethylene terephthalate) recycling, and modified multi-walled carbon nanotubes is presented. Di-hydroxy functional glycolysates, synthesized by catalytic depolymerization of poly(ethylene terephthalate) with propylene glycol, were used for the unsaturated polyester resin synthesis. The structure of the obtained glycolysis product and unsaturated polyester resin were characterized by using FTIR and NMR spectroscopy, and by acid, iodine, and hydroxyl value. Nanofillers were prepared by direct and two-step amidation of oxidized multi-walled carbon nanotubes. Direct amidation with diallylamine produced multi-walled carbon nanotube-diallylamine reactive nanofiller. Two-step modification with diamines: hexamethylenediamine and p-phenylenediamine gave multi-walled carbon nanotube-hexamethylenediamine and multi-walled carbon nanotube-p-phenylenediamine nanofiller..., respectively, whose amidation with methyl ester of linseed oil fatty acids gave multi-walled carbon nanotube-hexamethylenediamine/methyl ester of linseed oil fatty acid and multi-walled carbon nanotube-p-phenylenediamine/methyl ester of linseed oil fatty acid nanofiller, respectively. Influences of vinyl functionalities on mechanical properties of nanocomposite were analyzed from tensile strength (σb), elongation (ϵb) and Young's modulus (E) determination. An increase of 97.4, 119 and 139% of σb was obtained for nanocomposites with addition of 0.25 wt.% of diallylamine, p-phenylenediamine/methyl ester of linseed oil fatty acid and hexamethylenediamine/methyl ester of linseed oil fatty acid multi-walled carbon nanotubes, respectively. Short techno-economic analysis, performed on the basis of fixed and variable unsaturated polyester resin production costs, showed satisfactory potential profit, which could be realized by the implementation of the presented technology. © The Author(s) 2016.

Keywords:
poly(ethylene terephthalate)-based composites / unsaturated polyester / Vinyl MWCNT modification
Source:
Journal of Composite Materials, 2017, 51, 4, 491-505
Publisher:
  • SAGE
Funding / projects:
  • Directed synthesis, structure and properties of multifunctional materials (RS-172057)
  • Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-45019)

DOI: 10.1177/0021998316648757

ISSN: 0021-9983 (Print); 1530-793X (Online)

WoS: 000398638500005

Scopus: 2-s2.0-85012070614
[ Google Scholar ]
10
2
Handle
https://hdl.handle.net/21.15107/rcub_dais_3682
URI
https://dais.sanu.ac.rs/123456789/3682
Collections
  • ИТН САНУ - Општа колекција / ITS SASA - General collection
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASA
TY  - JOUR
AU  - Tasić, Ana
AU  - Rusmirović, Jelena
AU  - Nikolić, Jovana
AU  - Božić, Aleksandra
AU  - Pavlović, Vladimir B.
AU  - Marinković, Aleksandar D.
AU  - Uskoković, Petar S.
PY  - 2017
UR  - https://dais.sanu.ac.rs/123456789/3682
AB  - Production of high-performance nanocomposite materials obtained from unsaturated polyester resin, based on products of the waste poly(ethylene terephthalate) recycling, and modified multi-walled carbon nanotubes is presented. Di-hydroxy functional glycolysates, synthesized by catalytic depolymerization of poly(ethylene terephthalate) with propylene glycol, were used for the unsaturated polyester resin synthesis. The structure of the obtained glycolysis product and unsaturated polyester resin were characterized by using FTIR and NMR spectroscopy, and by acid, iodine, and hydroxyl value. Nanofillers were prepared by direct and two-step amidation of oxidized multi-walled carbon nanotubes. Direct amidation with diallylamine produced multi-walled carbon nanotube-diallylamine reactive nanofiller. Two-step modification with diamines: hexamethylenediamine and p-phenylenediamine gave multi-walled carbon nanotube-hexamethylenediamine and multi-walled carbon nanotube-p-phenylenediamine nanofiller, respectively, whose amidation with methyl ester of linseed oil fatty acids gave multi-walled carbon nanotube-hexamethylenediamine/methyl ester of linseed oil fatty acid and multi-walled carbon nanotube-p-phenylenediamine/methyl ester of linseed oil fatty acid nanofiller, respectively. Influences of vinyl functionalities on mechanical properties of nanocomposite were analyzed from tensile strength (σb), elongation (ϵb) and Young's modulus (E) determination. An increase of 97.4, 119 and 139% of σb was obtained for nanocomposites with addition of 0.25 wt.% of diallylamine, p-phenylenediamine/methyl ester of linseed oil fatty acid and hexamethylenediamine/methyl ester of linseed oil fatty acid multi-walled carbon nanotubes, respectively. Short techno-economic analysis, performed on the basis of fixed and variable unsaturated polyester resin production costs, showed satisfactory potential profit, which could be realized by the implementation of the presented technology. © The Author(s) 2016.
PB  - SAGE
T2  - Journal of Composite Materials
T1  - Effect of the vinyl modification of multi-walled carbon nanotubes on the performances of waste poly(ethylene terephthalate)-based nanocomposites
SP  - 491
EP  - 505
VL  - 51
IS  - 4
DO  - 10.1177/0021998316648757
UR  - https://hdl.handle.net/21.15107/rcub_dais_3682
ER  - 
@article{
author = "Tasić, Ana and Rusmirović, Jelena and Nikolić, Jovana and Božić, Aleksandra and Pavlović, Vladimir B. and Marinković, Aleksandar D. and Uskoković, Petar S.",
year = "2017",
abstract = "Production of high-performance nanocomposite materials obtained from unsaturated polyester resin, based on products of the waste poly(ethylene terephthalate) recycling, and modified multi-walled carbon nanotubes is presented. Di-hydroxy functional glycolysates, synthesized by catalytic depolymerization of poly(ethylene terephthalate) with propylene glycol, were used for the unsaturated polyester resin synthesis. The structure of the obtained glycolysis product and unsaturated polyester resin were characterized by using FTIR and NMR spectroscopy, and by acid, iodine, and hydroxyl value. Nanofillers were prepared by direct and two-step amidation of oxidized multi-walled carbon nanotubes. Direct amidation with diallylamine produced multi-walled carbon nanotube-diallylamine reactive nanofiller. Two-step modification with diamines: hexamethylenediamine and p-phenylenediamine gave multi-walled carbon nanotube-hexamethylenediamine and multi-walled carbon nanotube-p-phenylenediamine nanofiller, respectively, whose amidation with methyl ester of linseed oil fatty acids gave multi-walled carbon nanotube-hexamethylenediamine/methyl ester of linseed oil fatty acid and multi-walled carbon nanotube-p-phenylenediamine/methyl ester of linseed oil fatty acid nanofiller, respectively. Influences of vinyl functionalities on mechanical properties of nanocomposite were analyzed from tensile strength (σb), elongation (ϵb) and Young's modulus (E) determination. An increase of 97.4, 119 and 139% of σb was obtained for nanocomposites with addition of 0.25 wt.% of diallylamine, p-phenylenediamine/methyl ester of linseed oil fatty acid and hexamethylenediamine/methyl ester of linseed oil fatty acid multi-walled carbon nanotubes, respectively. Short techno-economic analysis, performed on the basis of fixed and variable unsaturated polyester resin production costs, showed satisfactory potential profit, which could be realized by the implementation of the presented technology. © The Author(s) 2016.",
publisher = "SAGE",
journal = "Journal of Composite Materials",
title = "Effect of the vinyl modification of multi-walled carbon nanotubes on the performances of waste poly(ethylene terephthalate)-based nanocomposites",
pages = "491-505",
volume = "51",
number = "4",
doi = "10.1177/0021998316648757",
url = "https://hdl.handle.net/21.15107/rcub_dais_3682"
}
Tasić, A., Rusmirović, J., Nikolić, J., Božić, A., Pavlović, V. B., Marinković, A. D.,& Uskoković, P. S.. (2017). Effect of the vinyl modification of multi-walled carbon nanotubes on the performances of waste poly(ethylene terephthalate)-based nanocomposites. in Journal of Composite Materials
SAGE., 51(4), 491-505.
https://doi.org/10.1177/0021998316648757
https://hdl.handle.net/21.15107/rcub_dais_3682
Tasić A, Rusmirović J, Nikolić J, Božić A, Pavlović VB, Marinković AD, Uskoković PS. Effect of the vinyl modification of multi-walled carbon nanotubes on the performances of waste poly(ethylene terephthalate)-based nanocomposites. in Journal of Composite Materials. 2017;51(4):491-505.
doi:10.1177/0021998316648757
https://hdl.handle.net/21.15107/rcub_dais_3682 .
Tasić, Ana, Rusmirović, Jelena, Nikolić, Jovana, Božić, Aleksandra, Pavlović, Vladimir B., Marinković, Aleksandar D., Uskoković, Petar S., "Effect of the vinyl modification of multi-walled carbon nanotubes on the performances of waste poly(ethylene terephthalate)-based nanocomposites" in Journal of Composite Materials, 51, no. 4 (2017):491-505,
https://doi.org/10.1177/0021998316648757 .,
https://hdl.handle.net/21.15107/rcub_dais_3682 .

DSpace software copyright © 2002-2015  DuraSpace
About DAIS - Digital Archive of the Serbian Academy of Sciences and Arts | Send Feedback

re3dataOpenAIRERCUB
 

 

All of DSpaceInstitutions/communitiesAuthorsTitlesSubjectsThis institutionAuthorsTitlesSubjects

Statistics

View Usage Statistics

DSpace software copyright © 2002-2015  DuraSpace
About DAIS - Digital Archive of the Serbian Academy of Sciences and Arts | Send Feedback

re3dataOpenAIRERCUB