Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution

Krstajić, Nedeljko; Jović, Vladimir D.; Gajić Krstajić, Ljiljana; Jović, Borka M.; Antozzi, A. L.; Martelli, G. N.

doi:10.1016/j.ijhydene.2008.04.039

Authorized Users Only

2008

Authors

Krstajić, Nedeljko
Jović, Vladimir D.
Gajić Krstajić, Ljiljana

Jović, Borka M.
Antozzi, A. L.
Martelli, G. N.

Article (Published version)

Metadata

Show full item record

Abstract

The hydrogen evolution reaction on the electrodeposited Ni-Mo alloy coatings, as well as their electrochemical properties in the NaOH solutions, have been investigated by the polarization measurements, cyclic voltammetry and EIS technique. It was shown that the Ni-Mo alloy coatings electrodeposited from the pyrophosphate-sodium bicarbonate bath possess high catalytic activity for hydrogen evolution in the NaOH solutions. Their stability in the 1 M NaOH at 25 °C under the condition of the reverse polarization was shown to be very good, while in the 33% NaOH at 85 °C (conditions of the industrial electrolysis) the electrodeposited Ni-Mo alloy coatings exhibited also high catalytic activity, but low stability, as a consequence of a deterioration of the alloy coatings. © 2008 International Association for Hydrogen Energy.

Keywords:

coatings / EIS measurements / electrodeposition / hydrogen evolution / Ni-Mo alloy / stability

Source:
International Journal of Hydrogen Energy, 2008, 33, 14, 3676-3687

Publisher:

Elsevier

Funding / projects:

Sinteza, karakterizacija i primena nanostruktuiranih katalizatora na različitim nosačima u gorivnim spregovima, elektrolizi vode i elektroorganskoj sintezi (RS-142038)

DOI: 10.1016/j.ijhydene.2008.04.039

ISSN: 0360-3199

WoS: 000258987000008

Scopus: 2-s2.0-47749095923

[ Google Scholar ]



	261
	233

TY  - JOUR
AU  - Krstajić, Nedeljko
AU  - Jović, Vladimir D.
AU  - Gajić Krstajić, Ljiljana
AU  - Jović, Borka M.
AU  - Antozzi, A. L.
AU  - Martelli, G. N.
PY  - 2008
UR  - https://dais.sanu.ac.rs/123456789/3579
AB  - The hydrogen evolution reaction on the electrodeposited Ni-Mo alloy coatings, as well as their electrochemical properties in the NaOH solutions, have been investigated by the polarization measurements, cyclic voltammetry and EIS technique. It was shown that the Ni-Mo alloy coatings electrodeposited from the pyrophosphate-sodium bicarbonate bath possess high catalytic activity for hydrogen evolution in the NaOH solutions. Their stability in the 1 M NaOH at 25 °C under the condition of the reverse polarization was shown to be very good, while in the 33% NaOH at 85 °C (conditions of the industrial electrolysis) the electrodeposited Ni-Mo alloy coatings exhibited also high catalytic activity, but low stability, as a consequence of a deterioration of the alloy coatings. © 2008 International Association for Hydrogen Energy.
PB  - Elsevier
T2  - International Journal of Hydrogen Energy
T1  - Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution
SP  - 3676
EP  - 3687
VL  - 33
IS  - 14
DO  - 10.1016/j.ijhydene.2008.04.039
UR  - https://hdl.handle.net/21.15107/rcub_dais_3579
ER  -

@article{
author = "Krstajić, Nedeljko and Jović, Vladimir D. and Gajić Krstajić, Ljiljana and Jović, Borka M. and Antozzi, A. L. and Martelli, G. N.",
year = "2008",
abstract = "The hydrogen evolution reaction on the electrodeposited Ni-Mo alloy coatings, as well as their electrochemical properties in the NaOH solutions, have been investigated by the polarization measurements, cyclic voltammetry and EIS technique. It was shown that the Ni-Mo alloy coatings electrodeposited from the pyrophosphate-sodium bicarbonate bath possess high catalytic activity for hydrogen evolution in the NaOH solutions. Their stability in the 1 M NaOH at 25 °C under the condition of the reverse polarization was shown to be very good, while in the 33% NaOH at 85 °C (conditions of the industrial electrolysis) the electrodeposited Ni-Mo alloy coatings exhibited also high catalytic activity, but low stability, as a consequence of a deterioration of the alloy coatings. © 2008 International Association for Hydrogen Energy.",
publisher = "Elsevier",
journal = "International Journal of Hydrogen Energy",
title = "Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution",
pages = "3676-3687",
volume = "33",
number = "14",
doi = "10.1016/j.ijhydene.2008.04.039",
url = "https://hdl.handle.net/21.15107/rcub_dais_3579"
}

Krstajić, N., Jović, V. D., Gajić Krstajić, L., Jović, B. M., Antozzi, A. L.,& Martelli, G. N.. (2008). Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution. in International Journal of Hydrogen Energy
Elsevier., 33(14), 3676-3687.
https://doi.org/10.1016/j.ijhydene.2008.04.039
https://hdl.handle.net/21.15107/rcub_dais_3579

Krstajić N, Jović VD, Gajić Krstajić L, Jović BM, Antozzi AL, Martelli GN. Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution. in International Journal of Hydrogen Energy. 2008;33(14):3676-3687.
doi:10.1016/j.ijhydene.2008.04.039
https://hdl.handle.net/21.15107/rcub_dais_3579 .

Krstajić, Nedeljko, Jović, Vladimir D., Gajić Krstajić, Ljiljana, Jović, Borka M., Antozzi, A. L., Martelli, G. N., "Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution" in International Journal of Hydrogen Energy, 33, no. 14 (2008):3676-3687,
https://doi.org/10.1016/j.ijhydene.2008.04.039 .,
https://hdl.handle.net/21.15107/rcub_dais_3579 .