Europium-doped (Y0.5Gd0.5)2O3 phosphor powder is synthesized via spray pyrolysis of polymeric precursor solution obtained by dissolving the stoichiometric amount of corresponding metal nitrates in ethylenediaminetetraacetic acid (EDTA) - ethylene glycol (EG) mixture. The 0.1M true stable solution is obtained after pH correction with NH4OH (final pH=8.7). Ultrasonically (1.3MHz) generated aerosol droplets are decomposed at 550 oC in argon atmosphere. Following the initial attempt for obtaining dense, nanostructured spherical particles of pure (Y0.5Gd0.5)2O3:Eu3+ phase, as-prepared dark-gray powder is additionally thermally treated for 12 h in air up to 1100 oC. The particle morphology is analyzed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Phase identification is performed by X-ray powder diffraction (XRPD) based on which the structural refinement through Rietveld method was done. Particle chemical purity is confirmed through EDS analysis, while las...er particle sizer is used for determination of the particle size distribution.
Keywords:
phosphor powders / doping / spray pyrolysis
Source:
Programme and The Book of Abstracts / Twelfth Annual Conference YUCOMAT 2010, Herceg Novi, September 6–10, 2010, 2010, 92-92
Publisher:
Belgrade : Institute of Technical Sciences of SASA
TY - CONF
AU - Dugandžić, Ivan
AU - Lojpur, Vesna
AU - Mančić, Lidija
AU - Rabanal, Maria Eugenia
AU - Milošević, Olivera
PY - 2010
UR - http://dais.sanu.ac.rs/123456789/3551
AB - Europium-doped (Y0.5Gd0.5)2O3 phosphor powder is synthesized via spray pyrolysis of polymeric precursor solution obtained by dissolving the stoichiometric amount of corresponding metal nitrates in ethylenediaminetetraacetic acid (EDTA) - ethylene glycol (EG) mixture. The 0.1M true stable solution is obtained after pH correction with NH4OH (final pH=8.7). Ultrasonically (1.3MHz) generated aerosol droplets are decomposed at 550 oC in argon atmosphere. Following the initial attempt for obtaining dense, nanostructured spherical particles of pure (Y0.5Gd0.5)2O3:Eu3+ phase, as-prepared dark-gray powder is additionally thermally treated for 12 h in air up to 1100 oC. The particle morphology is analyzed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Phase identification is performed by X-ray powder diffraction (XRPD) based on which the structural refinement through Rietveld method was done. Particle chemical purity is confirmed through EDS analysis, while laser particle sizer is used for determination of the particle size distribution.
PB - Belgrade : Institute of Technical Sciences of SASA
C3 - Programme and The Book of Abstracts / Twelfth Annual Conference YUCOMAT 2010, Herceg Novi, September 6–10, 2010
T1 - Dense spherical rare oxide particles synthesis via spray pyrolysis of polymeric precursor solution
SP - 92
EP - 92
ER -
@conference{
author = "Dugandžić, Ivan and Lojpur, Vesna and Mančić, Lidija and Rabanal, Maria Eugenia and Milošević, Olivera",
year = "2010",
url = "http://dais.sanu.ac.rs/123456789/3551",
abstract = "Europium-doped (Y0.5Gd0.5)2O3 phosphor powder is synthesized via spray pyrolysis of polymeric precursor solution obtained by dissolving the stoichiometric amount of corresponding metal nitrates in ethylenediaminetetraacetic acid (EDTA) - ethylene glycol (EG) mixture. The 0.1M true stable solution is obtained after pH correction with NH4OH (final pH=8.7). Ultrasonically (1.3MHz) generated aerosol droplets are decomposed at 550 oC in argon atmosphere. Following the initial attempt for obtaining dense, nanostructured spherical particles of pure (Y0.5Gd0.5)2O3:Eu3+ phase, as-prepared dark-gray powder is additionally thermally treated for 12 h in air up to 1100 oC. The particle morphology is analyzed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Phase identification is performed by X-ray powder diffraction (XRPD) based on which the structural refinement through Rietveld method was done. Particle chemical purity is confirmed through EDS analysis, while laser particle sizer is used for determination of the particle size distribution.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Programme and The Book of Abstracts / Twelfth Annual Conference YUCOMAT 2010, Herceg Novi, September 6–10, 2010",
title = "Dense spherical rare oxide particles synthesis via spray pyrolysis of polymeric precursor solution",
pages = "92-92"
}
Dugandžić I, Lojpur V, Mančić L, Rabanal ME, Milošević O. Dense spherical rare oxide particles synthesis via spray pyrolysis of polymeric precursor solution. Programme and The Book of Abstracts / Twelfth Annual Conference YUCOMAT 2010, Herceg Novi, September 6–10, 2010. 2010;:92-92
Dugandžić, I., Lojpur, V., Mančić, L., Rabanal, M. E.,& Milošević, O. (2010). Dense spherical rare oxide particles synthesis via spray pyrolysis of polymeric precursor solution.
Programme and The Book of Abstracts / Twelfth Annual Conference YUCOMAT 2010, Herceg Novi, September 6–10, 2010Belgrade : Institute of Technical Sciences of SASA., null, 92-92.
Dugandžić Ivan, Lojpur Vesna, Mančić Lidija, Rabanal Maria Eugenia, Milošević Olivera, "Dense spherical rare oxide particles synthesis via spray pyrolysis of polymeric precursor solution" null (2010):92-92
