Polyaniline electrode, was obtained by electrochemical polymerization at constant current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl containing 0.25 mol dm-3 aniline. Electrochemical characterization of the polyaniline electrode in chloride and chloride/citrate electrolyte, for different anodic potential limits, was performed using cyclic voltammetry and galvanostatic measurements. It was observed that for anodic potential 0.32 V, higher electrode capacity in chloride/citrate was obtained. For anodic potential limit of 0.50 V, faster decrease of the electrode capacity in chloride/citrate electrolyte was also observed. It was suggested that influence of both chloride and citrate anions has to be taken into account.
Keywords:
electrochemistry / polymers / power sources
Source:
The 61st Annual Meeting of the International Society of Electrochemistry: Electrochemistry from Biology to Physics September 26th - October 1st, 2010, Nice, France: Book of Abstracts, 2010, s05-P-054-
TY - CONF
AU - Jugović, Branimir
AU - Gvozdenović, Milica M.
AU - Stevanović, Jasmina S.
AU - Trišović, Tomislav
AU - Grgur, Branimir
PY - 2010
UR - https://dais.sanu.ac.rs/123456789/3511
AB - Polyaniline electrode, was obtained by electrochemical polymerization at constant current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl containing 0.25 mol dm-3 aniline. Electrochemical characterization of the polyaniline electrode in chloride and chloride/citrate electrolyte, for different anodic potential limits, was performed using cyclic voltammetry and galvanostatic measurements. It was observed that for anodic potential 0.32 V, higher electrode capacity in chloride/citrate was obtained. For anodic potential limit of 0.50 V, faster decrease of the electrode capacity in chloride/citrate electrolyte was also observed. It was suggested that influence of both chloride and citrate anions has to be taken into account.
PB - Nice : International Society of Electrochemistry
C3 - The 61st Annual Meeting of the International Society of Electrochemistry: Electrochemistry from Biology to Physics September 26th - October 1st, 2010, Nice, France: Book of Abstracts
T1 - Electrochemical characterization of electrochemically polymerized polyaniline in citrate containing electrolyte
SP - s05-P-054
UR - https://hdl.handle.net/21.15107/rcub_dais_3511
ER -
@conference{
author = "Jugović, Branimir and Gvozdenović, Milica M. and Stevanović, Jasmina S. and Trišović, Tomislav and Grgur, Branimir",
year = "2010",
abstract = "Polyaniline electrode, was obtained by electrochemical polymerization at constant current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl containing 0.25 mol dm-3 aniline. Electrochemical characterization of the polyaniline electrode in chloride and chloride/citrate electrolyte, for different anodic potential limits, was performed using cyclic voltammetry and galvanostatic measurements. It was observed that for anodic potential 0.32 V, higher electrode capacity in chloride/citrate was obtained. For anodic potential limit of 0.50 V, faster decrease of the electrode capacity in chloride/citrate electrolyte was also observed. It was suggested that influence of both chloride and citrate anions has to be taken into account.",
publisher = "Nice : International Society of Electrochemistry",
journal = "The 61st Annual Meeting of the International Society of Electrochemistry: Electrochemistry from Biology to Physics September 26th - October 1st, 2010, Nice, France: Book of Abstracts",
title = "Electrochemical characterization of electrochemically polymerized polyaniline in citrate containing electrolyte",
pages = "s05-P-054",
url = "https://hdl.handle.net/21.15107/rcub_dais_3511"
}
Jugović, B., Gvozdenović, M. M., Stevanović, J. S., Trišović, T.,& Grgur, B.. (2010). Electrochemical characterization of electrochemically polymerized polyaniline in citrate containing electrolyte. in The 61st Annual Meeting of the International Society of Electrochemistry: Electrochemistry from Biology to Physics September 26th - October 1st, 2010, Nice, France: Book of Abstracts
Nice : International Society of Electrochemistry., s05-P-054.
https://hdl.handle.net/21.15107/rcub_dais_3511
Jugović B, Gvozdenović MM, Stevanović JS, Trišović T, Grgur B. Electrochemical characterization of electrochemically polymerized polyaniline in citrate containing electrolyte. in The 61st Annual Meeting of the International Society of Electrochemistry: Electrochemistry from Biology to Physics September 26th - October 1st, 2010, Nice, France: Book of Abstracts. 2010;:s05-P-054.
https://hdl.handle.net/21.15107/rcub_dais_3511 .
Jugović, Branimir, Gvozdenović, Milica M., Stevanović, Jasmina S., Trišović, Tomislav, Grgur, Branimir, "Electrochemical characterization of electrochemically polymerized polyaniline in citrate containing electrolyte" in The 61st Annual Meeting of the International Society of Electrochemistry: Electrochemistry from Biology to Physics September 26th - October 1st, 2010, Nice, France: Book of Abstracts (2010):s05-P-054,
https://hdl.handle.net/21.15107/rcub_dais_3511 .
