In this article the influence of ball miling process on structure of MgO–TiO2 system, as well as the electrical properties of samples after sintering, was investigated. The mixtures of MgO–TiO2 powders were mechanically activated in a planetary ball mill for the time period from 0 to 120 min. The influence of mechanical activation and sintering on the lattice vibrational spectra was studied by Raman spectroscopy at room temperature. Structural investigations have been performed on produced powders. Nitrogen adsorption method was used to determine the BET specific surface area and pore size distribution. Unusual results have been obtained: specific surface area continuously decreased up to 40 min of activation and increased after that, reaching its minimum value of 5.5 m2/g. The Raman spectra of activated powders have shown that anatase modes have been decreasing in intensity and broadening as the time of activation extended. Also, the additional modes attributed to TiO2 II, srilankite ...and rutile phases started to appear as a consequence of activation. The small differences noticed in the Raman spectra of sintered samples have been explained by structural modification of MgTiO3 phase due to the presence of defects.
The effects of activation and sintering process on microstructure were investigated by scanning electron microscopy (SEM). The electrical measurements showed difference in dielectric constant (εr), loss tangent (tg δ) and specific resistance (ρ) as a function of time of mechanical treatment.
TY - JOUR
AU - Filipović, Suzana
AU - Obradović, Nina
AU - Krstić, Jugoslav
AU - Šćepanović, M.
AU - Pavlović, Vladimir B.
AU - Paunović, Vesna
AU - Ristić, Momčilo M.
PY - 2013
UR - https://dais.sanu.ac.rs/123456789/348
AB - In this article the influence of ball miling process on structure of MgO–TiO2 system, as well as the electrical properties of samples after sintering, was investigated. The mixtures of MgO–TiO2 powders were mechanically activated in a planetary ball mill for the time period from 0 to 120 min. The influence of mechanical activation and sintering on the lattice vibrational spectra was studied by Raman spectroscopy at room temperature. Structural investigations have been performed on produced powders. Nitrogen adsorption method was used to determine the BET specific surface area and pore size distribution. Unusual results have been obtained: specific surface area continuously decreased up to 40 min of activation and increased after that, reaching its minimum value of 5.5 m2/g. The Raman spectra of activated powders have shown that anatase modes have been decreasing in intensity and broadening as the time of activation extended. Also, the additional modes attributed to TiO2 II, srilankite and rutile phases started to appear as a consequence of activation. The small differences noticed in the Raman spectra of sintered samples have been explained by structural modification of MgTiO3 phase due to the presence of defects.
The effects of activation and sintering process on microstructure were investigated by scanning electron microscopy (SEM). The electrical measurements showed difference in dielectric constant (εr), loss tangent (tg δ) and specific resistance (ρ) as a function of time of mechanical treatment.
PB - Elsevier
T2 - Journal of Alloys and Compounds
T1 - Structural characterization and electrical properties of sintered magnesium–titanate ceramics
SP - 39
EP - 44
VL - 555
IS - 5
DO - 10.1016/j.jallcom.2012.12.040
UR - https://hdl.handle.net/21.15107/rcub_dais_348
ER -
@article{
author = "Filipović, Suzana and Obradović, Nina and Krstić, Jugoslav and Šćepanović, M. and Pavlović, Vladimir B. and Paunović, Vesna and Ristić, Momčilo M.",
year = "2013",
abstract = "In this article the influence of ball miling process on structure of MgO–TiO2 system, as well as the electrical properties of samples after sintering, was investigated. The mixtures of MgO–TiO2 powders were mechanically activated in a planetary ball mill for the time period from 0 to 120 min. The influence of mechanical activation and sintering on the lattice vibrational spectra was studied by Raman spectroscopy at room temperature. Structural investigations have been performed on produced powders. Nitrogen adsorption method was used to determine the BET specific surface area and pore size distribution. Unusual results have been obtained: specific surface area continuously decreased up to 40 min of activation and increased after that, reaching its minimum value of 5.5 m2/g. The Raman spectra of activated powders have shown that anatase modes have been decreasing in intensity and broadening as the time of activation extended. Also, the additional modes attributed to TiO2 II, srilankite and rutile phases started to appear as a consequence of activation. The small differences noticed in the Raman spectra of sintered samples have been explained by structural modification of MgTiO3 phase due to the presence of defects.
The effects of activation and sintering process on microstructure were investigated by scanning electron microscopy (SEM). The electrical measurements showed difference in dielectric constant (εr), loss tangent (tg δ) and specific resistance (ρ) as a function of time of mechanical treatment.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "Structural characterization and electrical properties of sintered magnesium–titanate ceramics",
pages = "39-44",
volume = "555",
number = "5",
doi = "10.1016/j.jallcom.2012.12.040",
url = "https://hdl.handle.net/21.15107/rcub_dais_348"
}
Filipović, S., Obradović, N., Krstić, J., Šćepanović, M., Pavlović, V. B., Paunović, V.,& Ristić, M. M.. (2013). Structural characterization and electrical properties of sintered magnesium–titanate ceramics. in Journal of Alloys and Compounds
Elsevier., 555(5), 39-44.
https://doi.org/10.1016/j.jallcom.2012.12.040
https://hdl.handle.net/21.15107/rcub_dais_348
Filipović S, Obradović N, Krstić J, Šćepanović M, Pavlović VB, Paunović V, Ristić MM. Structural characterization and electrical properties of sintered magnesium–titanate ceramics. in Journal of Alloys and Compounds. 2013;555(5):39-44.
doi:10.1016/j.jallcom.2012.12.040
https://hdl.handle.net/21.15107/rcub_dais_348 .
Filipović, Suzana, Obradović, Nina, Krstić, Jugoslav, Šćepanović, M., Pavlović, Vladimir B., Paunović, Vesna, Ristić, Momčilo M., "Structural characterization and electrical properties of sintered magnesium–titanate ceramics" in Journal of Alloys and Compounds, 555, no. 5 (2013):39-44,
https://doi.org/10.1016/j.jallcom.2012.12.040 .,
https://hdl.handle.net/21.15107/rcub_dais_348 .
