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Characterization of electrochemically synthesized PANI on graphite electrode for potential use in electrochemical power sources

Authorized Users Only
2009
Authors
Jugović, Branimir
Gvozdenović, Milica M.
Stevanović, Jasmina S.
Trišović, Tomislav
Grgur, Branimir
Article (Published version)
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Abstract
Polyaniline (PANI) on graphite electrode was synthesized electrochemically under galvanostatic condition at current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl and 0.25 mol dm-3 aniline monomer. Electrochemical characterization of the PANI electrode was performed in 0.5 mol dm-3 HCl using cyclic voltammetry and galvanostatic measurements. The overall charge capacity of the PANI electrode was estimated to be 0.154 mAh cm-2, which corresponds to 25% of the theoretical mass of PANI available for doping exchange. It was observed that during initial cyclization at low pH, the extent of PANI degradation products was insignificant and practically had no influence on the charge/discharge characteristics of the PANI electrode. © 2008 Elsevier B.V. All rights reserved.
Keywords:
electropolymerization / polyaniline / rechargeable power sources / PANI
Source:
Materials Chemistry and Physics, 2009, 114, 2-3, 939-942
Funding / projects:
  • Modifikacija metalnih i nemetalnih materijala elektroprovodnim polimerima za primenu u novim tehnologijama (RS-142044)

DOI: 10.1016/j.matchemphys.2008.10.069

ISSN: 0254-0584

WoS: 000263833500077

Scopus: 2-s2.0-58949099336
[ Google Scholar ]
41
36
Handle
https://hdl.handle.net/21.15107/rcub_dais_3471
URI
https://dais.sanu.ac.rs/123456789/3471
Collections
  • ИТН САНУ - Општа колекција / ITS SASA - General collection
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASA
TY  - JOUR
AU  - Jugović, Branimir
AU  - Gvozdenović, Milica M.
AU  - Stevanović, Jasmina S.
AU  - Trišović, Tomislav
AU  - Grgur, Branimir
PY  - 2009
UR  - https://dais.sanu.ac.rs/123456789/3471
AB  - Polyaniline (PANI) on graphite electrode was synthesized electrochemically under galvanostatic condition at current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl and 0.25 mol dm-3 aniline monomer. Electrochemical characterization of the PANI electrode was performed in 0.5 mol dm-3 HCl using cyclic voltammetry and galvanostatic measurements. The overall charge capacity of the PANI electrode was estimated to be 0.154 mAh cm-2, which corresponds to 25% of the theoretical mass of PANI available for doping exchange. It was observed that during initial cyclization at low pH, the extent of PANI degradation products was insignificant and practically had no influence on the charge/discharge characteristics of the PANI electrode. © 2008 Elsevier B.V. All rights reserved.
T2  - Materials Chemistry and Physics
T1  - Characterization of electrochemically synthesized PANI on graphite electrode for potential use in electrochemical power sources
SP  - 939
EP  - 942
VL  - 114
IS  - 2-3
DO  - 10.1016/j.matchemphys.2008.10.069
UR  - https://hdl.handle.net/21.15107/rcub_dais_3471
ER  - 
@article{
author = "Jugović, Branimir and Gvozdenović, Milica M. and Stevanović, Jasmina S. and Trišović, Tomislav and Grgur, Branimir",
year = "2009",
abstract = "Polyaniline (PANI) on graphite electrode was synthesized electrochemically under galvanostatic condition at current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl and 0.25 mol dm-3 aniline monomer. Electrochemical characterization of the PANI electrode was performed in 0.5 mol dm-3 HCl using cyclic voltammetry and galvanostatic measurements. The overall charge capacity of the PANI electrode was estimated to be 0.154 mAh cm-2, which corresponds to 25% of the theoretical mass of PANI available for doping exchange. It was observed that during initial cyclization at low pH, the extent of PANI degradation products was insignificant and practically had no influence on the charge/discharge characteristics of the PANI electrode. © 2008 Elsevier B.V. All rights reserved.",
journal = "Materials Chemistry and Physics",
title = "Characterization of electrochemically synthesized PANI on graphite electrode for potential use in electrochemical power sources",
pages = "939-942",
volume = "114",
number = "2-3",
doi = "10.1016/j.matchemphys.2008.10.069",
url = "https://hdl.handle.net/21.15107/rcub_dais_3471"
}
Jugović, B., Gvozdenović, M. M., Stevanović, J. S., Trišović, T.,& Grgur, B.. (2009). Characterization of electrochemically synthesized PANI on graphite electrode for potential use in electrochemical power sources. in Materials Chemistry and Physics, 114(2-3), 939-942.
https://doi.org/10.1016/j.matchemphys.2008.10.069
https://hdl.handle.net/21.15107/rcub_dais_3471
Jugović B, Gvozdenović MM, Stevanović JS, Trišović T, Grgur B. Characterization of electrochemically synthesized PANI on graphite electrode for potential use in electrochemical power sources. in Materials Chemistry and Physics. 2009;114(2-3):939-942.
doi:10.1016/j.matchemphys.2008.10.069
https://hdl.handle.net/21.15107/rcub_dais_3471 .
Jugović, Branimir, Gvozdenović, Milica M., Stevanović, Jasmina S., Trišović, Tomislav, Grgur, Branimir, "Characterization of electrochemically synthesized PANI on graphite electrode for potential use in electrochemical power sources" in Materials Chemistry and Physics, 114, no. 2-3 (2009):939-942,
https://doi.org/10.1016/j.matchemphys.2008.10.069 .,
https://hdl.handle.net/21.15107/rcub_dais_3471 .

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