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Structural analysis of Zn2TiO4 doped with MgO

Authorized Users Only
2009
Authors
Nikolić, Maria Vesna
Obradović, Nina
Paraskevopoulos, Konstantinos M.
Zorba, Triantafyllia T.
Savić, Slavica M.
Ristić, Momčilo M.
Article (Published version)
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Abstract
The starting mixtures of ZnO, TiO2, and MgO (0, 1.25, and 2.5 wt.%) powders are mechanically activated in a high-energy planetary mill for 15 min and then sintered between 800 and 1100°C for 2 h. The influence of MgO addition on the structure of the samples obtained is analyzed with X-ray diffraction and infrared reflection spectroscopy. Room-temperature far-infrared reflectivity spectra of the samples doped with MgO (0, 1.25, and 2.5 wt.%) and sintered at 1100 °C in the frequency range between 100 and 1200 cm- 1 are measured and analyzed. Optical parameters are determined for seven oscillators belonging to the spinel structure using the four-parameter model of coupled oscillators. Born effective charges are calculated from the transversal/longitudinal splitting. © 2009 Springer Science+Business Media, Inc.
Keywords:
sintering / mechanical activation / X-ray diffraction / powders / structure / zinc titanate / Infrared Reflection Spectroscopy / magnesium oxide
Source:
Powder Metallurgy and Metal Ceramics, 2009, 48, 11-12, 712-717
Publisher:
  • Springer
Funding / projects:
  • Investigation of the relation in triad: Synthesis structure-properties for functional materials (RS-142011)

DOI: 10.1007/s11106-010-9190-z

ISSN: 1068-1302

Scopus: 2-s2.0-77952634867
[ Google Scholar ]
2
Handle
https://hdl.handle.net/21.15107/rcub_dais_3460
URI
https://dais.sanu.ac.rs/123456789/3460
Collections
  • ИТН САНУ - Општа колекција / ITS SASA - General collection
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASA
TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Obradović, Nina
AU  - Paraskevopoulos, Konstantinos M.
AU  - Zorba, Triantafyllia T.
AU  - Savić, Slavica M.
AU  - Ristić, Momčilo M.
PY  - 2009
UR  - https://dais.sanu.ac.rs/123456789/3460
AB  - The starting mixtures of ZnO, TiO2, and MgO (0, 1.25, and 2.5 wt.%) powders are mechanically activated in a high-energy planetary mill for 15 min and then sintered between 800 and 1100°C for 2 h. The influence of MgO addition on the structure of the samples obtained is analyzed with X-ray diffraction and infrared reflection spectroscopy. Room-temperature far-infrared reflectivity spectra of the samples doped with MgO (0, 1.25, and 2.5 wt.%) and sintered at 1100 °C in the frequency range between 100 and 1200 cm- 1 are measured and analyzed. Optical parameters are determined for seven oscillators belonging to the spinel structure using the four-parameter model of coupled oscillators. Born effective charges are calculated from the transversal/longitudinal splitting. © 2009 Springer Science+Business Media, Inc.
PB  - Springer
T2  - Powder Metallurgy and Metal Ceramics
T1  - Structural analysis of Zn2TiO4 doped with MgO
SP  - 712
EP  - 717
VL  - 48
IS  - 11-12
DO  - 10.1007/s11106-010-9190-z
UR  - https://hdl.handle.net/21.15107/rcub_dais_3460
ER  - 
@article{
author = "Nikolić, Maria Vesna and Obradović, Nina and Paraskevopoulos, Konstantinos M. and Zorba, Triantafyllia T. and Savić, Slavica M. and Ristić, Momčilo M.",
year = "2009",
abstract = "The starting mixtures of ZnO, TiO2, and MgO (0, 1.25, and 2.5 wt.%) powders are mechanically activated in a high-energy planetary mill for 15 min and then sintered between 800 and 1100°C for 2 h. The influence of MgO addition on the structure of the samples obtained is analyzed with X-ray diffraction and infrared reflection spectroscopy. Room-temperature far-infrared reflectivity spectra of the samples doped with MgO (0, 1.25, and 2.5 wt.%) and sintered at 1100 °C in the frequency range between 100 and 1200 cm- 1 are measured and analyzed. Optical parameters are determined for seven oscillators belonging to the spinel structure using the four-parameter model of coupled oscillators. Born effective charges are calculated from the transversal/longitudinal splitting. © 2009 Springer Science+Business Media, Inc.",
publisher = "Springer",
journal = "Powder Metallurgy and Metal Ceramics",
title = "Structural analysis of Zn2TiO4 doped with MgO",
pages = "712-717",
volume = "48",
number = "11-12",
doi = "10.1007/s11106-010-9190-z",
url = "https://hdl.handle.net/21.15107/rcub_dais_3460"
}
Nikolić, M. V., Obradović, N., Paraskevopoulos, K. M., Zorba, T. T., Savić, S. M.,& Ristić, M. M.. (2009). Structural analysis of Zn2TiO4 doped with MgO. in Powder Metallurgy and Metal Ceramics
Springer., 48(11-12), 712-717.
https://doi.org/10.1007/s11106-010-9190-z
https://hdl.handle.net/21.15107/rcub_dais_3460
Nikolić MV, Obradović N, Paraskevopoulos KM, Zorba TT, Savić SM, Ristić MM. Structural analysis of Zn2TiO4 doped with MgO. in Powder Metallurgy and Metal Ceramics. 2009;48(11-12):712-717.
doi:10.1007/s11106-010-9190-z
https://hdl.handle.net/21.15107/rcub_dais_3460 .
Nikolić, Maria Vesna, Obradović, Nina, Paraskevopoulos, Konstantinos M., Zorba, Triantafyllia T., Savić, Slavica M., Ristić, Momčilo M., "Structural analysis of Zn2TiO4 doped with MgO" in Powder Metallurgy and Metal Ceramics, 48, no. 11-12 (2009):712-717,
https://doi.org/10.1007/s11106-010-9190-z .,
https://hdl.handle.net/21.15107/rcub_dais_3460 .

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