Photoluminescent properties of nanostructured Y2O 3:Eu3+ powders obtained through aerosol synthesis
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2010
Authors
Marinković, KatarinaMančić, Lidija

Gómez, Luz Stella

Rabanal, Maria Eugenia

Dramićanin, Miroslav

Milošević, Olivera

Article (Published version)

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Red emitting Y2O3:Eu3+ (5 and 10 at.%) submicronic particles were synthesized through ultrasonic spray pyrolysis method from the pure nitrate solutions at 900 °C. The employed synthesis conditions (gradual increase of temperature within triple zone reactor and extended residence time) assured formation of spherical, dense, non-agglomerated particles that are nanostructured (crystallite size ∼20 nm). The as-prepared powders were additionally thermally treated at temperatures up to 1200 °C. A bcc Ia-3 cubic phase presence and exceptional powder morphological features were maintained with heating and are followed with particle structural changes (crystallite growth up to 130 nm). Emission spectra were studied after excitation with 393 nm wavelength and together with the decay lifetimes for Eu3+ ion 5D0 and 5D1 levels revealed the effect of powder nanocrystalline nature on its luminescent properties. The emission spectra showed typical Eu3+ 5D0 → 7Fi (i = 0, 1, 2, 3, 4) transitions with do...minant red emission at 611 nm, while the lifetime measurements revealed the quenching effect with the rise of dopant concentration and its more consistent distribution into host lattice due to the thermal treatment. © 2010 Elsevier B.V. All rights reserved.
Keywords:
luminescence / spray pyrolysis / yttrium oxide / nanoparticlesSource:
Optical Materials, 2010, 32, 12, 1606-1611Publisher:
- Elsevier
Funding / projects:
- MPNS COST Action 539 - Electroceramics from Nanopowders Produced by Innovative Methods (ELENA)
- Synthesis, characterization and activity of organic and coordination composition and their application in (bio) nanotechnology (RS-142010)
DOI: 10.1016/j.optmat.2010.05.023
ISSN: 0925-3467
WoS: 000283971200011
Scopus: 2-s2.0-77957277022
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Marinković, Katarina AU - Mančić, Lidija AU - Gómez, Luz Stella AU - Rabanal, Maria Eugenia AU - Dramićanin, Miroslav AU - Milošević, Olivera PY - 2010 UR - https://dais.sanu.ac.rs/123456789/3414 AB - Red emitting Y2O3:Eu3+ (5 and 10 at.%) submicronic particles were synthesized through ultrasonic spray pyrolysis method from the pure nitrate solutions at 900 °C. The employed synthesis conditions (gradual increase of temperature within triple zone reactor and extended residence time) assured formation of spherical, dense, non-agglomerated particles that are nanostructured (crystallite size ∼20 nm). The as-prepared powders were additionally thermally treated at temperatures up to 1200 °C. A bcc Ia-3 cubic phase presence and exceptional powder morphological features were maintained with heating and are followed with particle structural changes (crystallite growth up to 130 nm). Emission spectra were studied after excitation with 393 nm wavelength and together with the decay lifetimes for Eu3+ ion 5D0 and 5D1 levels revealed the effect of powder nanocrystalline nature on its luminescent properties. The emission spectra showed typical Eu3+ 5D0 → 7Fi (i = 0, 1, 2, 3, 4) transitions with dominant red emission at 611 nm, while the lifetime measurements revealed the quenching effect with the rise of dopant concentration and its more consistent distribution into host lattice due to the thermal treatment. © 2010 Elsevier B.V. All rights reserved. PB - Elsevier T2 - Optical Materials T1 - Photoluminescent properties of nanostructured Y2O 3:Eu3+ powders obtained through aerosol synthesis SP - 1606 EP - 1611 VL - 32 IS - 12 DO - 10.1016/j.optmat.2010.05.023 UR - https://hdl.handle.net/21.15107/rcub_dais_3414 ER -
@article{ author = "Marinković, Katarina and Mančić, Lidija and Gómez, Luz Stella and Rabanal, Maria Eugenia and Dramićanin, Miroslav and Milošević, Olivera", year = "2010", abstract = "Red emitting Y2O3:Eu3+ (5 and 10 at.%) submicronic particles were synthesized through ultrasonic spray pyrolysis method from the pure nitrate solutions at 900 °C. The employed synthesis conditions (gradual increase of temperature within triple zone reactor and extended residence time) assured formation of spherical, dense, non-agglomerated particles that are nanostructured (crystallite size ∼20 nm). The as-prepared powders were additionally thermally treated at temperatures up to 1200 °C. A bcc Ia-3 cubic phase presence and exceptional powder morphological features were maintained with heating and are followed with particle structural changes (crystallite growth up to 130 nm). Emission spectra were studied after excitation with 393 nm wavelength and together with the decay lifetimes for Eu3+ ion 5D0 and 5D1 levels revealed the effect of powder nanocrystalline nature on its luminescent properties. The emission spectra showed typical Eu3+ 5D0 → 7Fi (i = 0, 1, 2, 3, 4) transitions with dominant red emission at 611 nm, while the lifetime measurements revealed the quenching effect with the rise of dopant concentration and its more consistent distribution into host lattice due to the thermal treatment. © 2010 Elsevier B.V. All rights reserved.", publisher = "Elsevier", journal = "Optical Materials", title = "Photoluminescent properties of nanostructured Y2O 3:Eu3+ powders obtained through aerosol synthesis", pages = "1606-1611", volume = "32", number = "12", doi = "10.1016/j.optmat.2010.05.023", url = "https://hdl.handle.net/21.15107/rcub_dais_3414" }
Marinković, K., Mančić, L., Gómez, L. S., Rabanal, M. E., Dramićanin, M.,& Milošević, O.. (2010). Photoluminescent properties of nanostructured Y2O 3:Eu3+ powders obtained through aerosol synthesis. in Optical Materials Elsevier., 32(12), 1606-1611. https://doi.org/10.1016/j.optmat.2010.05.023 https://hdl.handle.net/21.15107/rcub_dais_3414
Marinković K, Mančić L, Gómez LS, Rabanal ME, Dramićanin M, Milošević O. Photoluminescent properties of nanostructured Y2O 3:Eu3+ powders obtained through aerosol synthesis. in Optical Materials. 2010;32(12):1606-1611. doi:10.1016/j.optmat.2010.05.023 https://hdl.handle.net/21.15107/rcub_dais_3414 .
Marinković, Katarina, Mančić, Lidija, Gómez, Luz Stella, Rabanal, Maria Eugenia, Dramićanin, Miroslav, Milošević, Olivera, "Photoluminescent properties of nanostructured Y2O 3:Eu3+ powders obtained through aerosol synthesis" in Optical Materials, 32, no. 12 (2010):1606-1611, https://doi.org/10.1016/j.optmat.2010.05.023 ., https://hdl.handle.net/21.15107/rcub_dais_3414 .