The oxygen reduction reaction (ORR) was studied on the polycrystalline Pt electrode in 0.1 M NaCl electrolyte containing various amounts of acetonitrile (AcN). The state of the electrode surface was characterized by the cyclic voltammetry in oxygen free electrolytes, while ORR studies were performed on the polycrystalline Pt rotating disc electrode by the linear sweep voltammetry in oxygen saturated electrolytes. The acetonitrile is chemisorbed on Pt over a wide potential range, inhibiting both hydrogen adsorption and oxide formation. The extent of AcN chemisorption depends on its concentration in the solution. Initial potential of oxygen reduction is shifted negatively, while the ORR current is increasingly reduced with the increase of AcN concentration. Complete inhibition of ORR in the potential range of AcN and Cl-anion coadsorption is achieved for (0.1 M NaCl + 1 M AcN) solution.
TY - JOUR
AU - Smiljanić, Milutin
AU - Srejić, Irina
AU - Marinović, Vedrana
AU - Rakočević, Zlatko
AU - Štrbac, Svetlana
PY - 2012
UR - https://dais.sanu.ac.rs/123456789/259
AB - The oxygen reduction reaction (ORR) was studied on the polycrystalline Pt electrode in 0.1 M NaCl electrolyte containing various amounts of acetonitrile (AcN). The state of the electrode surface was characterized by the cyclic voltammetry in oxygen free electrolytes, while ORR studies were performed on the polycrystalline Pt rotating disc electrode by the linear sweep voltammetry in oxygen saturated electrolytes. The acetonitrile is chemisorbed on Pt over a wide potential range, inhibiting both hydrogen adsorption and oxide formation. The extent of AcN chemisorption depends on its concentration in the solution. Initial potential of oxygen reduction is shifted negatively, while the ORR current is increasingly reduced with the increase of AcN concentration. Complete inhibition of ORR in the potential range of AcN and Cl-anion coadsorption is achieved for (0.1 M NaCl + 1 M AcN) solution.
PB - Belgrade : Association of the Chemical Engineers of Serbia
T2 - Hemijska industrija
T1 - Inhibiting effect of acetonitrile on oxygen reduction on polycrystalline pt electrode in sodium chloride solution
SP - 327
EP - 333
VL - 66
IS - 3
DO - 10.2298/HEMIND111010097S
UR - https://hdl.handle.net/21.15107/rcub_dais_259
ER -
@article{
author = "Smiljanić, Milutin and Srejić, Irina and Marinović, Vedrana and Rakočević, Zlatko and Štrbac, Svetlana",
year = "2012",
abstract = "The oxygen reduction reaction (ORR) was studied on the polycrystalline Pt electrode in 0.1 M NaCl electrolyte containing various amounts of acetonitrile (AcN). The state of the electrode surface was characterized by the cyclic voltammetry in oxygen free electrolytes, while ORR studies were performed on the polycrystalline Pt rotating disc electrode by the linear sweep voltammetry in oxygen saturated electrolytes. The acetonitrile is chemisorbed on Pt over a wide potential range, inhibiting both hydrogen adsorption and oxide formation. The extent of AcN chemisorption depends on its concentration in the solution. Initial potential of oxygen reduction is shifted negatively, while the ORR current is increasingly reduced with the increase of AcN concentration. Complete inhibition of ORR in the potential range of AcN and Cl-anion coadsorption is achieved for (0.1 M NaCl + 1 M AcN) solution.",
publisher = "Belgrade : Association of the Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Inhibiting effect of acetonitrile on oxygen reduction on polycrystalline pt electrode in sodium chloride solution",
pages = "327-333",
volume = "66",
number = "3",
doi = "10.2298/HEMIND111010097S",
url = "https://hdl.handle.net/21.15107/rcub_dais_259"
}
Smiljanić, M., Srejić, I., Marinović, V., Rakočević, Z.,& Štrbac, S.. (2012). Inhibiting effect of acetonitrile on oxygen reduction on polycrystalline pt electrode in sodium chloride solution. in Hemijska industrija
Belgrade : Association of the Chemical Engineers of Serbia., 66(3), 327-333.
https://doi.org/10.2298/HEMIND111010097S
https://hdl.handle.net/21.15107/rcub_dais_259
Smiljanić M, Srejić I, Marinović V, Rakočević Z, Štrbac S. Inhibiting effect of acetonitrile on oxygen reduction on polycrystalline pt electrode in sodium chloride solution. in Hemijska industrija. 2012;66(3):327-333.
doi:10.2298/HEMIND111010097S
https://hdl.handle.net/21.15107/rcub_dais_259 .
Smiljanić, Milutin, Srejić, Irina, Marinović, Vedrana, Rakočević, Zlatko, Štrbac, Svetlana, "Inhibiting effect of acetonitrile on oxygen reduction on polycrystalline pt electrode in sodium chloride solution" in Hemijska industrija, 66, no. 3 (2012):327-333,
https://doi.org/10.2298/HEMIND111010097S .,
https://hdl.handle.net/21.15107/rcub_dais_259 .
