The key parameters related to cathode materials for commercial use are a high specific capacity, good cycling stability, capacity retention at high current rates, as well as the simplicity of the synthesis process. This study presents a facile synthesis of a composite cathode material, Li2FeSiO4 with carbon, under extreme conditions: rapid heating, short dwell at 750 °C and subsequent quenching. The water-soluble polymer methylcellulose was used both as an excellent dispersing agent and a carbon source that pyrolytically degrades to carbon, thereby enabling the homogeneous deployment of the precursor compounds and the control of the Li2FeSiO4 particle growth from the earliest stage of processing. X-ray powder diffraction reveals the formation of Li2FeSiO4 nanocrystallites with a monoclinic structure in the P21/n space group (#14). The composite’s electrochemical performance as a cathode material in Li-ion batteries was examined. The influence of the amount of methylcellulose on the mic...rostructural, morphological, conductive, and electrochemical properties of the obtained powders has been discussed. It has been shown that the overall electrochemical performance is improved with an increase of carbon content, through both the decrease of the mean particle diameter and the increase of electrical conductivity.
TY - JOUR
AU - Milović, Miloš
AU - Jugović, Dragana
AU - Mitrić, Miodrag
AU - Dominko, Robert
AU - Stojković Simatović, Ivana
AU - Jokić, Bojan
AU - Uskoković, Dragan
PY - 2016
UR - https://dais.sanu.ac.rs/123456789/2318
AB - The key parameters related to cathode materials for commercial use are a high specific capacity, good cycling stability, capacity retention at high current rates, as well as the simplicity of the synthesis process. This study presents a facile synthesis of a composite cathode material, Li2FeSiO4 with carbon, under extreme conditions: rapid heating, short dwell at 750 °C and subsequent quenching. The water-soluble polymer methylcellulose was used both as an excellent dispersing agent and a carbon source that pyrolytically degrades to carbon, thereby enabling the homogeneous deployment of the precursor compounds and the control of the Li2FeSiO4 particle growth from the earliest stage of processing. X-ray powder diffraction reveals the formation of Li2FeSiO4 nanocrystallites with a monoclinic structure in the P21/n space group (#14). The composite’s electrochemical performance as a cathode material in Li-ion batteries was examined. The influence of the amount of methylcellulose on the microstructural, morphological, conductive, and electrochemical properties of the obtained powders has been discussed. It has been shown that the overall electrochemical performance is improved with an increase of carbon content, through both the decrease of the mean particle diameter and the increase of electrical conductivity.
PB - Springer
T2 - Cellulose
T1 - The use of methylcellulose for the synthesis of Li2FeSiO4/C composites
SP - 239
EP - 246
VL - 23
IS - 1
DO - 10.1007/s10570-015-0806-9
UR - https://hdl.handle.net/21.15107/rcub_dais_2318
ER -
@article{
author = "Milović, Miloš and Jugović, Dragana and Mitrić, Miodrag and Dominko, Robert and Stojković Simatović, Ivana and Jokić, Bojan and Uskoković, Dragan",
year = "2016",
abstract = "The key parameters related to cathode materials for commercial use are a high specific capacity, good cycling stability, capacity retention at high current rates, as well as the simplicity of the synthesis process. This study presents a facile synthesis of a composite cathode material, Li2FeSiO4 with carbon, under extreme conditions: rapid heating, short dwell at 750 °C and subsequent quenching. The water-soluble polymer methylcellulose was used both as an excellent dispersing agent and a carbon source that pyrolytically degrades to carbon, thereby enabling the homogeneous deployment of the precursor compounds and the control of the Li2FeSiO4 particle growth from the earliest stage of processing. X-ray powder diffraction reveals the formation of Li2FeSiO4 nanocrystallites with a monoclinic structure in the P21/n space group (#14). The composite’s electrochemical performance as a cathode material in Li-ion batteries was examined. The influence of the amount of methylcellulose on the microstructural, morphological, conductive, and electrochemical properties of the obtained powders has been discussed. It has been shown that the overall electrochemical performance is improved with an increase of carbon content, through both the decrease of the mean particle diameter and the increase of electrical conductivity.",
publisher = "Springer",
journal = "Cellulose",
title = "The use of methylcellulose for the synthesis of Li2FeSiO4/C composites",
pages = "239-246",
volume = "23",
number = "1",
doi = "10.1007/s10570-015-0806-9",
url = "https://hdl.handle.net/21.15107/rcub_dais_2318"
}
Milović, M., Jugović, D., Mitrić, M., Dominko, R., Stojković Simatović, I., Jokić, B.,& Uskoković, D.. (2016). The use of methylcellulose for the synthesis of Li2FeSiO4/C composites. in Cellulose
Springer., 23(1), 239-246.
https://doi.org/10.1007/s10570-015-0806-9
https://hdl.handle.net/21.15107/rcub_dais_2318
Milović M, Jugović D, Mitrić M, Dominko R, Stojković Simatović I, Jokić B, Uskoković D. The use of methylcellulose for the synthesis of Li2FeSiO4/C composites. in Cellulose. 2016;23(1):239-246.
doi:10.1007/s10570-015-0806-9
https://hdl.handle.net/21.15107/rcub_dais_2318 .
Milović, Miloš, Jugović, Dragana, Mitrić, Miodrag, Dominko, Robert, Stojković Simatović, Ivana, Jokić, Bojan, Uskoković, Dragan, "The use of methylcellulose for the synthesis of Li2FeSiO4/C composites" in Cellulose, 23, no. 1 (2016):239-246,
https://doi.org/10.1007/s10570-015-0806-9 .,
https://hdl.handle.net/21.15107/rcub_dais_2318 .
