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Correlation between isothermal expansion and functional properties change of the Fe81B13Si4C2 amorphous alloy

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2009
203.pdf (356.5Kb)
Authors
Kalezić Glišović, Aleksandra
Maričić, V. A.
Kosanović, Darko
Đukić, S.
Simeunović, R.
Contributors
Ristić, Momčilo M.
Article (Published version)
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Abstract
The structural changes effect on functional properties of ribbon shaped samples of the Fe81B13Si4C2 amorphous alloy during annealing process was investigated in this paper. Differential scanning calorimetry method has shown that this alloy crystallizes in one stage, in temperature range from room temperature up to 700°C. Structural relaxation process was investigated by sensitive dilatation method in nonisothermal and isothermal conditions. It has been shown that structural relaxation process occurs in two stages by measuring thermal expansion at constant temperatures of t1=420°C, t2 = 440°C and t3 = 460°C. The first stage is characterized by linear logarithmic dependence of thermal expansion upon time at constant temperature. The second stage of structural relaxation process is characterized by linear dependence of isothermal expansion upon the square root of process time. These results imply that the first stage of structural relaxation process is a rapid kinetic process, while the s...econd stage of structural relaxation process is a slow diffusion process. The rate constants k11 = 2,27⋅10- 3 s-1, k12 = 2,79⋅10-3 s-1, k13 = 3,6⋅10-3 s-1, k21 = 0,67⋅10-4 s-1, k22 = 3,72⋅10-4 s-1, k23 = 21,53⋅10-4 s-1 and activation energies E1 = 48,64 kJ/mol and E2 = 366, 23 kJ/mol were determined for both stages of structural relaxation process. The distinct correlation between structural relaxation process and magnetic susceptibility relative change was determined by thermomagnetic measurements. It has been shown that magnetic susceptibility can be increased by up to 80%, by convenient annealings after structural relaxation process, at magnetic field intensity of 8 kA/m.

Keywords:
amorphous materials / structural relaxation / thermal expansion / magnetic susceptibility
Source:
Science of Sintering, 2009, 41, 3, 283-291
Publisher:
  • Belgrade : International Institute for the Science of Sintering
Funding / projects:
  • Investigation of the relation in triad: Synthesis structure-properties for functional materials (RS-142011)

DOI: 10.2298/SOS0903283K

ISSN: 1820-7413 (Online); 0350-820X

WoS: 000275835500006

Scopus: 2-s2.0-76649102450
[ Google Scholar ]
7
7
Handle
https://hdl.handle.net/21.15107/rcub_dais_206
URI
https://dais.sanu.ac.rs/123456789/206
Collections
  • ИТН САНУ - Општа колекција / ITS SASA - General collection
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASA
TY  - JOUR
AU  - Kalezić Glišović, Aleksandra
AU  - Maričić, V. A.
AU  - Kosanović, Darko
AU  - Đukić, S.
AU  - Simeunović, R.
PY  - 2009
UR  - https://dais.sanu.ac.rs/123456789/206
AB  - The structural changes effect on functional properties of ribbon shaped samples of the Fe81B13Si4C2 amorphous alloy during annealing process was investigated in this paper. Differential scanning calorimetry method has shown that this alloy crystallizes in one stage, in temperature range from room temperature up to 700°C. Structural relaxation process was investigated by sensitive dilatation method in nonisothermal and isothermal conditions. It has been shown that structural relaxation process occurs in two stages by measuring thermal expansion at constant temperatures of t1=420°C, t2 = 440°C and t3 = 460°C. The first stage is characterized by linear logarithmic dependence of thermal expansion upon time at constant temperature. The second stage of structural relaxation process is characterized by linear dependence of isothermal expansion upon the square root of process time. These results imply that the first stage of structural relaxation process is a rapid kinetic process, while the second stage of structural relaxation process is a slow diffusion process. The rate constants k11 = 2,27⋅10- 3 s-1, k12 = 2,79⋅10-3 s-1, k13 = 3,6⋅10-3 s-1, k21 = 0,67⋅10-4 s-1, k22 = 3,72⋅10-4 s-1, k23 = 21,53⋅10-4 s-1 and activation energies E1 = 48,64 kJ/mol and E2 = 366, 23 kJ/mol were determined for both stages of structural relaxation process. The distinct correlation between structural relaxation process and magnetic susceptibility relative change was determined by thermomagnetic measurements. It has been shown that magnetic susceptibility can be increased by up to 80%, by convenient annealings after structural relaxation process, at magnetic field intensity of 8 kA/m.
PB  - Belgrade : International Institute for the Science of Sintering
T2  - Science of Sintering
T1  - Correlation between isothermal expansion and functional properties change of the Fe81B13Si4C2 amorphous alloy
SP  - 283
EP  - 291
VL  - 41
IS  - 3
DO  - 10.2298/SOS0903283K
UR  - https://hdl.handle.net/21.15107/rcub_dais_206
ER  - 
@article{
author = "Kalezić Glišović, Aleksandra and Maričić, V. A. and Kosanović, Darko and Đukić, S. and Simeunović, R.",
year = "2009",
abstract = "The structural changes effect on functional properties of ribbon shaped samples of the Fe81B13Si4C2 amorphous alloy during annealing process was investigated in this paper. Differential scanning calorimetry method has shown that this alloy crystallizes in one stage, in temperature range from room temperature up to 700°C. Structural relaxation process was investigated by sensitive dilatation method in nonisothermal and isothermal conditions. It has been shown that structural relaxation process occurs in two stages by measuring thermal expansion at constant temperatures of t1=420°C, t2 = 440°C and t3 = 460°C. The first stage is characterized by linear logarithmic dependence of thermal expansion upon time at constant temperature. The second stage of structural relaxation process is characterized by linear dependence of isothermal expansion upon the square root of process time. These results imply that the first stage of structural relaxation process is a rapid kinetic process, while the second stage of structural relaxation process is a slow diffusion process. The rate constants k11 = 2,27⋅10- 3 s-1, k12 = 2,79⋅10-3 s-1, k13 = 3,6⋅10-3 s-1, k21 = 0,67⋅10-4 s-1, k22 = 3,72⋅10-4 s-1, k23 = 21,53⋅10-4 s-1 and activation energies E1 = 48,64 kJ/mol and E2 = 366, 23 kJ/mol were determined for both stages of structural relaxation process. The distinct correlation between structural relaxation process and magnetic susceptibility relative change was determined by thermomagnetic measurements. It has been shown that magnetic susceptibility can be increased by up to 80%, by convenient annealings after structural relaxation process, at magnetic field intensity of 8 kA/m.",
publisher = "Belgrade : International Institute for the Science of Sintering",
journal = "Science of Sintering",
title = "Correlation between isothermal expansion and functional properties change of the Fe81B13Si4C2 amorphous alloy",
pages = "283-291",
volume = "41",
number = "3",
doi = "10.2298/SOS0903283K",
url = "https://hdl.handle.net/21.15107/rcub_dais_206"
}
Kalezić Glišović, A., Maričić, V. A., Kosanović, D., Đukić, S.,& Simeunović, R.. (2009). Correlation between isothermal expansion and functional properties change of the Fe81B13Si4C2 amorphous alloy. in Science of Sintering
Belgrade : International Institute for the Science of Sintering., 41(3), 283-291.
https://doi.org/10.2298/SOS0903283K
https://hdl.handle.net/21.15107/rcub_dais_206
Kalezić Glišović A, Maričić VA, Kosanović D, Đukić S, Simeunović R. Correlation between isothermal expansion and functional properties change of the Fe81B13Si4C2 amorphous alloy. in Science of Sintering. 2009;41(3):283-291.
doi:10.2298/SOS0903283K
https://hdl.handle.net/21.15107/rcub_dais_206 .
Kalezić Glišović, Aleksandra, Maričić, V. A., Kosanović, Darko, Đukić, S., Simeunović, R., "Correlation between isothermal expansion and functional properties change of the Fe81B13Si4C2 amorphous alloy" in Science of Sintering, 41, no. 3 (2009):283-291,
https://doi.org/10.2298/SOS0903283K .,
https://hdl.handle.net/21.15107/rcub_dais_206 .

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