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Seawater zinc/polypyrrole-air cell possessing multifunctional charge-discharge characteristics

Authorized Users Only
2017
Authors
Al-Eggiely, Ali H.
Alguail, Alsadek A.
Gvozdenović, Milica M.
Jugović, Branimir
Grgur, Branimir
Article (Published version)
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Abstract
An environmentally friendly cell using polypyrrole-air regenerative cathode and zinc as anode is investigated in the 3% sodium chloride solution. The cell can operate in different charge and discharge mode. Polypyrrole can be reoxidized (doped) with chloride anions either by using dissolved oxygen or by an external power supply, e.g., small photovoltaic cell. In that way, after discharge, capacity retaining can be achieved by using seawater as the electrolyte. During low discharge rate, the delicate balance between solid state diffusion-controlled dedoping and chemical oxidation of polypyrrole produced by hydrogen peroxide is achieved, generating stable voltage plateau. The cell is proposed to operate as a power supply for different sensor devices in two modes. In the low discharge mode (10–20 mA g−1), it can be used for data acquisition, and at the fast discharge mode (up to 2 A g−1) for collecting data transmission.
Keywords:
conducting polymers / Air regenerative cathode / Immersion batteries / Metal-air battery
Source:
Journal of Solid State Electrochemistry, 2017, 21, 10, 2769-2777
Projects:
  • Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies (RS-172046)

DOI: 10.1007/s10008-017-3597-0

WoS: 000410749000002

Scopus: 2-s2.0-85018805863
[ Google Scholar ]
2
1
URI
http://dais.sanu.ac.rs/123456789/16010
Collections
  • ITN SANU - Opšta kolekcija / ITS SASA - General collection
Institution
Институт техничких наука САНУ / Institute of Technical Sciences of SASA
TY  - JOUR
AU  - Al-Eggiely, Ali H.
AU  - Alguail, Alsadek A.
AU  - Gvozdenović, Milica M.
AU  - Jugović, Branimir
AU  - Grgur, Branimir
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/16010
AB  - An environmentally friendly cell using polypyrrole-air regenerative cathode and zinc as anode is investigated in the 3% sodium chloride solution. The cell can operate in different charge and discharge mode. Polypyrrole can be reoxidized (doped) with chloride anions either by using dissolved oxygen or by an external power supply, e.g., small photovoltaic cell. In that way, after discharge, capacity retaining can be achieved by using seawater as the electrolyte. During low discharge rate, the delicate balance between solid state diffusion-controlled dedoping and chemical oxidation of polypyrrole produced by hydrogen peroxide is achieved, generating stable voltage plateau. The cell is proposed to operate as a power supply for different sensor devices in two modes. In the low discharge mode (10–20 mA g−1), it can be used for data acquisition, and at the fast discharge mode (up to 2 A g−1) for collecting data transmission.
T2  - Journal of Solid State Electrochemistry
T1  - Seawater zinc/polypyrrole-air cell possessing multifunctional charge-discharge characteristics
SP  - 2769
EP  - 2777
VL  - 21
IS  - 10
DO  - 10.1007/s10008-017-3597-0
ER  - 
@article{
author = "Al-Eggiely, Ali H. and Alguail, Alsadek A. and Gvozdenović, Milica M. and Jugović, Branimir and Grgur, Branimir",
year = "2017",
url = "http://dais.sanu.ac.rs/123456789/16010",
abstract = "An environmentally friendly cell using polypyrrole-air regenerative cathode and zinc as anode is investigated in the 3% sodium chloride solution. The cell can operate in different charge and discharge mode. Polypyrrole can be reoxidized (doped) with chloride anions either by using dissolved oxygen or by an external power supply, e.g., small photovoltaic cell. In that way, after discharge, capacity retaining can be achieved by using seawater as the electrolyte. During low discharge rate, the delicate balance between solid state diffusion-controlled dedoping and chemical oxidation of polypyrrole produced by hydrogen peroxide is achieved, generating stable voltage plateau. The cell is proposed to operate as a power supply for different sensor devices in two modes. In the low discharge mode (10–20 mA g−1), it can be used for data acquisition, and at the fast discharge mode (up to 2 A g−1) for collecting data transmission.",
journal = "Journal of Solid State Electrochemistry",
title = "Seawater zinc/polypyrrole-air cell possessing multifunctional charge-discharge characteristics",
pages = "2769-2777",
volume = "21",
number = "10",
doi = "10.1007/s10008-017-3597-0"
}
Al-Eggiely AH, Alguail AA, Gvozdenović MM, Jugović B, Grgur B. Seawater zinc/polypyrrole-air cell possessing multifunctional charge-discharge characteristics. Journal of Solid State Electrochemistry. 2017;21(10):2769-2777
Al-Eggiely, A. H., Alguail, A. A., Gvozdenović, M. M., Jugović, B.,& Grgur, B. (2017). Seawater zinc/polypyrrole-air cell possessing multifunctional charge-discharge characteristics.
Journal of Solid State Electrochemistry, 21(10), 2769-2777. 
https://doi.org/10.1007/s10008-017-3597-0
Al-Eggiely Ali H., Alguail Alsadek A., Gvozdenović Milica M., Jugović Branimir, Grgur Branimir, "Seawater zinc/polypyrrole-air cell possessing multifunctional charge-discharge characteristics" 21, no. 10 (2017):2769-2777,
https://doi.org/10.1007/s10008-017-3597-0 .

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