Solvothermal synthesis of Ag/ZnO and Pt/ZnO nanocomposites and comparison of their photocatalytic behaviors on dyes degradation
Abstract
Noble metal/ZnO nanoparticles were synthesized by a solvothermal method. The influence of reaction time, noble metal presence or kind of noble metal (Ag or Pt) was evaluated. The prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–vis diffuse reflectance spectroscopy (DRS) and BET surface area analysis. Hexagonal wurtzite and fcc were obtained for crystalline structures for ZnO and Ag/Pt, respectively. No characteristic phases which correspond to crystalline impurities were detected. It was displayed that ZnO nanoparticles presented nanowire morphology (NWs), while the metallic silver or platinum were found taking on quasi-spherical nanoparticles morphology (NPs), which appeared well dispersed onto ZnO NWs surface. Regarding particle sizes, ZnO aspect ratios were 2.5–13.3, Ag and Pt diameters were 17.3–24.3 nm and around ≈6.3 nm, respectively. The photocatalytic behavior of the synthesized system...s was studied as well by the removing reaction of methylene blue (MB) in water solution. It was verified that the increase of the photocatalytic activity was due to the noble metal presence, exhibiting higher effect of silver than platinum. Photocatalytic results (all samples reached >70% MB elimination) demonstrated the viability of the noble metal/ZnO nanocomposites synthesized by solvothermal method for usage in environmental applications.
Keywords:
Ag/ZnO & Pt/ZnO nanocomposites / Spherical nanoparticles and nanowires / Solvothermal method / PhotocatalysisSource:
Advanced Powder Technology, 2016, 27, 3, 983-993Publisher:
- Elsevier
Funding / projects:
- Innovation and Education Ministry, Spain, Project MAT2013-47460-C5-5-P
- Autonomous Region Program of Madrid, Spain, MULTIMAT-CHALLENGE (ref. S2013/MIT-2862)
- Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology (RS-172035)
- Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion (RS-45020)
DOI: 10.1016/j.apt.2016.03.021
ISSN: 0921-8831
WoS: 000377864600031
Scopus: 2-s2.0-85006173344
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Muñoz-Fernandez, Lidia AU - Sierra-Fernández, Aránzazu AU - Milošević, Olivera AU - Rabanal, Maria Eugenia PY - 2016 UR - https://dais.sanu.ac.rs/123456789/15991 AB - Noble metal/ZnO nanoparticles were synthesized by a solvothermal method. The influence of reaction time, noble metal presence or kind of noble metal (Ag or Pt) was evaluated. The prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–vis diffuse reflectance spectroscopy (DRS) and BET surface area analysis. Hexagonal wurtzite and fcc were obtained for crystalline structures for ZnO and Ag/Pt, respectively. No characteristic phases which correspond to crystalline impurities were detected. It was displayed that ZnO nanoparticles presented nanowire morphology (NWs), while the metallic silver or platinum were found taking on quasi-spherical nanoparticles morphology (NPs), which appeared well dispersed onto ZnO NWs surface. Regarding particle sizes, ZnO aspect ratios were 2.5–13.3, Ag and Pt diameters were 17.3–24.3 nm and around ≈6.3 nm, respectively. The photocatalytic behavior of the synthesized systems was studied as well by the removing reaction of methylene blue (MB) in water solution. It was verified that the increase of the photocatalytic activity was due to the noble metal presence, exhibiting higher effect of silver than platinum. Photocatalytic results (all samples reached >70% MB elimination) demonstrated the viability of the noble metal/ZnO nanocomposites synthesized by solvothermal method for usage in environmental applications. PB - Elsevier T2 - Advanced Powder Technology T1 - Solvothermal synthesis of Ag/ZnO and Pt/ZnO nanocomposites and comparison of their photocatalytic behaviors on dyes degradation SP - 983 EP - 993 VL - 27 IS - 3 DO - 10.1016/j.apt.2016.03.021 UR - https://hdl.handle.net/21.15107/rcub_dais_15991 ER -
@article{ author = "Muñoz-Fernandez, Lidia and Sierra-Fernández, Aránzazu and Milošević, Olivera and Rabanal, Maria Eugenia", year = "2016", abstract = "Noble metal/ZnO nanoparticles were synthesized by a solvothermal method. The influence of reaction time, noble metal presence or kind of noble metal (Ag or Pt) was evaluated. The prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–vis diffuse reflectance spectroscopy (DRS) and BET surface area analysis. Hexagonal wurtzite and fcc were obtained for crystalline structures for ZnO and Ag/Pt, respectively. No characteristic phases which correspond to crystalline impurities were detected. It was displayed that ZnO nanoparticles presented nanowire morphology (NWs), while the metallic silver or platinum were found taking on quasi-spherical nanoparticles morphology (NPs), which appeared well dispersed onto ZnO NWs surface. Regarding particle sizes, ZnO aspect ratios were 2.5–13.3, Ag and Pt diameters were 17.3–24.3 nm and around ≈6.3 nm, respectively. The photocatalytic behavior of the synthesized systems was studied as well by the removing reaction of methylene blue (MB) in water solution. It was verified that the increase of the photocatalytic activity was due to the noble metal presence, exhibiting higher effect of silver than platinum. Photocatalytic results (all samples reached >70% MB elimination) demonstrated the viability of the noble metal/ZnO nanocomposites synthesized by solvothermal method for usage in environmental applications.", publisher = "Elsevier", journal = "Advanced Powder Technology", title = "Solvothermal synthesis of Ag/ZnO and Pt/ZnO nanocomposites and comparison of their photocatalytic behaviors on dyes degradation", pages = "983-993", volume = "27", number = "3", doi = "10.1016/j.apt.2016.03.021", url = "https://hdl.handle.net/21.15107/rcub_dais_15991" }
Muñoz-Fernandez, L., Sierra-Fernández, A., Milošević, O.,& Rabanal, M. E.. (2016). Solvothermal synthesis of Ag/ZnO and Pt/ZnO nanocomposites and comparison of their photocatalytic behaviors on dyes degradation. in Advanced Powder Technology Elsevier., 27(3), 983-993. https://doi.org/10.1016/j.apt.2016.03.021 https://hdl.handle.net/21.15107/rcub_dais_15991
Muñoz-Fernandez L, Sierra-Fernández A, Milošević O, Rabanal ME. Solvothermal synthesis of Ag/ZnO and Pt/ZnO nanocomposites and comparison of their photocatalytic behaviors on dyes degradation. in Advanced Powder Technology. 2016;27(3):983-993. doi:10.1016/j.apt.2016.03.021 https://hdl.handle.net/21.15107/rcub_dais_15991 .
Muñoz-Fernandez, Lidia, Sierra-Fernández, Aránzazu, Milošević, Olivera, Rabanal, Maria Eugenia, "Solvothermal synthesis of Ag/ZnO and Pt/ZnO nanocomposites and comparison of their photocatalytic behaviors on dyes degradation" in Advanced Powder Technology, 27, no. 3 (2016):983-993, https://doi.org/10.1016/j.apt.2016.03.021 ., https://hdl.handle.net/21.15107/rcub_dais_15991 .