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Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode

Authorized Users Only
2016
Authors
Grgur, Branimir
Jugović, Branimir
Gvozdenović, Milica M.
Article (Published version)
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Abstract
The potential characteristics of graphite felt electrodes, modified by iron oxide, for oxygen reduction are evaluated. Modification is carried out by Successive Ion Layer Adsorption and Reaction (SILAR) method, using a solution of ferric nitrate in methanol for the adsorption of ions, and a solution of sodium hypochlorite for reaction. The reaction activity of the oxygen reduction from the air, in sodium sulfate based solution varying the number of SILAR cycles, as well as the influence of pH is investigated. By comparing the activity with pure platinum, similar activity is obtained at pH = 9.2, as well as good electrode stability. Possible mechanism of the oxygen reduction on the graphite felt modified by iron oxide is discussed.
Keywords:
Fuel cells / Platinum / Mechanism / Hematite / Hypochlorite
Source:
Electrochimica Acta, 2016, 212, 254-259
Publisher:
  • Elsevier
Projects:
  • Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies (RS-172046)

DOI: 10.1016/j.electacta.2016.07.029

ISSN: 0013-4686

WoS: 000382250200031

Scopus: 2-s2.0-84978288798
[ Google Scholar ]
3
2
URI
http://dais.sanu.ac.rs/123456789/15972
Collections
  • ITN SANU - Opšta kolekcija / ITS SASA - General collection
Institution
Институт техничких наука САНУ / Institute of Technical Sciences of SASA
TY  - JOUR
AU  - Grgur, Branimir
AU  - Jugović, Branimir
AU  - Gvozdenović, Milica M.
PY  - 2016
UR  - http://dais.sanu.ac.rs/123456789/15972
AB  - The potential characteristics of graphite felt electrodes, modified by iron oxide, for oxygen reduction are evaluated. Modification is carried out by Successive Ion Layer Adsorption and Reaction (SILAR) method, using a solution of ferric nitrate in methanol for the adsorption of ions, and a solution of sodium hypochlorite for reaction. The reaction activity of the oxygen reduction from the air, in sodium sulfate based solution varying the number of SILAR cycles, as well as the influence of pH is investigated. By comparing the activity with pure platinum, similar activity is obtained at pH = 9.2, as well as good electrode stability. Possible mechanism of the oxygen reduction on the graphite felt modified by iron oxide is discussed.
PB  - Elsevier
T2  - Electrochimica Acta
T1  - Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode
SP  - 254
EP  - 259
VL  - 212
DO  - 10.1016/j.electacta.2016.07.029
ER  - 
@article{
author = "Grgur, Branimir and Jugović, Branimir and Gvozdenović, Milica M.",
year = "2016",
url = "http://dais.sanu.ac.rs/123456789/15972",
abstract = "The potential characteristics of graphite felt electrodes, modified by iron oxide, for oxygen reduction are evaluated. Modification is carried out by Successive Ion Layer Adsorption and Reaction (SILAR) method, using a solution of ferric nitrate in methanol for the adsorption of ions, and a solution of sodium hypochlorite for reaction. The reaction activity of the oxygen reduction from the air, in sodium sulfate based solution varying the number of SILAR cycles, as well as the influence of pH is investigated. By comparing the activity with pure platinum, similar activity is obtained at pH = 9.2, as well as good electrode stability. Possible mechanism of the oxygen reduction on the graphite felt modified by iron oxide is discussed.",
publisher = "Elsevier",
journal = "Electrochimica Acta",
title = "Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode",
pages = "254-259",
volume = "212",
doi = "10.1016/j.electacta.2016.07.029"
}
Grgur B, Jugović B, Gvozdenović MM. Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode. Electrochimica Acta. 2016;212:254-259
Grgur, B., Jugović, B.,& Gvozdenović, M. M. (2016). Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode.
Electrochimica ActaElsevier., 212, 254-259. 
https://doi.org/10.1016/j.electacta.2016.07.029
Grgur Branimir, Jugović Branimir, Gvozdenović Milica M., "Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode" 212 (2016):254-259,
https://doi.org/10.1016/j.electacta.2016.07.029 .

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