Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode
Abstract
The potential characteristics of graphite felt electrodes, modified by iron oxide, for oxygen reduction are evaluated. Modification is carried out by Successive Ion Layer Adsorption and Reaction (SILAR) method, using a solution of ferric nitrate in methanol for the adsorption of ions, and a solution of sodium hypochlorite for reaction. The reaction activity of the oxygen reduction from the air, in sodium sulfate based solution varying the number of SILAR cycles, as well as the influence of pH is investigated. By comparing the activity with pure platinum, similar activity is obtained at pH = 9.2, as well as good electrode stability. Possible mechanism of the oxygen reduction on the graphite felt modified by iron oxide is discussed.
Keywords:
Fuel cells / Platinum / Mechanism / Hematite / HypochloriteSource:
Electrochimica Acta, 2016, 212, 254-259Publisher:
- Elsevier
Funding / projects:
DOI: 10.1016/j.electacta.2016.07.029
ISSN: 0013-4686
WoS: 000382250200031
Scopus: 2-s2.0-84978288798
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Grgur, Branimir AU - Jugović, Branimir AU - Gvozdenović, Milica M. PY - 2016 UR - https://dais.sanu.ac.rs/123456789/15972 AB - The potential characteristics of graphite felt electrodes, modified by iron oxide, for oxygen reduction are evaluated. Modification is carried out by Successive Ion Layer Adsorption and Reaction (SILAR) method, using a solution of ferric nitrate in methanol for the adsorption of ions, and a solution of sodium hypochlorite for reaction. The reaction activity of the oxygen reduction from the air, in sodium sulfate based solution varying the number of SILAR cycles, as well as the influence of pH is investigated. By comparing the activity with pure platinum, similar activity is obtained at pH = 9.2, as well as good electrode stability. Possible mechanism of the oxygen reduction on the graphite felt modified by iron oxide is discussed. PB - Elsevier T2 - Electrochimica Acta T1 - Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode SP - 254 EP - 259 VL - 212 DO - 10.1016/j.electacta.2016.07.029 UR - https://hdl.handle.net/21.15107/rcub_dais_15972 ER -
@article{ author = "Grgur, Branimir and Jugović, Branimir and Gvozdenović, Milica M.", year = "2016", abstract = "The potential characteristics of graphite felt electrodes, modified by iron oxide, for oxygen reduction are evaluated. Modification is carried out by Successive Ion Layer Adsorption and Reaction (SILAR) method, using a solution of ferric nitrate in methanol for the adsorption of ions, and a solution of sodium hypochlorite for reaction. The reaction activity of the oxygen reduction from the air, in sodium sulfate based solution varying the number of SILAR cycles, as well as the influence of pH is investigated. By comparing the activity with pure platinum, similar activity is obtained at pH = 9.2, as well as good electrode stability. Possible mechanism of the oxygen reduction on the graphite felt modified by iron oxide is discussed.", publisher = "Elsevier", journal = "Electrochimica Acta", title = "Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode", pages = "254-259", volume = "212", doi = "10.1016/j.electacta.2016.07.029", url = "https://hdl.handle.net/21.15107/rcub_dais_15972" }
Grgur, B., Jugović, B.,& Gvozdenović, M. M.. (2016). Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode. in Electrochimica Acta Elsevier., 212, 254-259. https://doi.org/10.1016/j.electacta.2016.07.029 https://hdl.handle.net/21.15107/rcub_dais_15972
Grgur B, Jugović B, Gvozdenović MM. Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode. in Electrochimica Acta. 2016;212:254-259. doi:10.1016/j.electacta.2016.07.029 https://hdl.handle.net/21.15107/rcub_dais_15972 .
Grgur, Branimir, Jugović, Branimir, Gvozdenović, Milica M., "Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode" in Electrochimica Acta, 212 (2016):254-259, https://doi.org/10.1016/j.electacta.2016.07.029 ., https://hdl.handle.net/21.15107/rcub_dais_15972 .