2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior
Authors
Ristić, Predrag
Filipović, Nenad

Blagojević, Vladimir A.

Ćirković, Jovana

Holló, Berta Barta

Đokić, Veljko R.

Donnard, Morgan

Gulea, Mihaela

Marjanović, Ivana

Klisurić, Olivera R.

Todorović, Tamara R.

Article (Accepted Version)
Metadata
Show full item recordAbstract
Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞ (1), {[Ag(L1)2]ClO4}∞ (2), {[Ag(L2)2]NO3·H2O}∞ (3) and {[Ag(L2)2]ClO4}∞ (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(I) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound 4, which can be correlated to its largest lattice volume.
Keywords:
coordination polymers / thiomorpholine-4-carbonitrile / piperazine-1,4-dicarbonitrile / photocatalysis / thermal behavior / intermolecular interactions / silverSource:
CrystEngComm, 2021, 23, 27, 4799-4815Publisher:
- Royal Society of Chemistry (RSC)
Funding / projects:
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200168 (University of Belgrade, Faculty of Chemistry) (RS-200168)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200116 (University of Belgrade, Faculty of Agriculture) (RS-200116)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200175 (Institute of Technical Sciences of SASA, Belgrade) (RS-200175)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200125 (University of Novi Sad, Faculty of Science) (RS-200125)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200135 (University of Belgrade, Faculty of Technology and Metallurgy) (RS-200135)
- Matériaux hiérarchiques et fonctionnels pour la santé, l’environnement et l’énergie (HiFunMat)
Note:
- This is the peer-reviewed version of the article: Ristić, P., Filipović, N., Blagojević, V. A., Ćirković, J., Holló, B. B., Đokić, V. R., Donnard, M., Gulea, M., Marjanović, I., Klisurić, O. R.,& Todorović, T. R. (2021). 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. CrystEngComm, Royal Society of Chemistry (RSC), 23(27), 4799-4815. https://doi.org/10.1039/D1CE00394A
- Supplementary information: https://hdl.handle.net/21.15107/rcub_dais_11759
- Related data: https://hdl.handle.net/21.15107/rcub_dais_11761
Related info:
- Version of
https://hdl.handle.net/21.15107/rcub_dais_11753 - Version of
http://dx.doi.org/10.1039/D1CE00394A - Referenced by
https://hdl.handle.net/21.15107/rcub_dais_11759 - Referenced by
https://hdl.handle.net/21.15107/rcub_dais_11761
DOI: 10.1039/D1CE00394A
ISSN: 1466-8033
WoS: 000664682100001
Scopus: 2-s2.0-85110010702
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Ristić, Predrag AU - Filipović, Nenad AU - Blagojević, Vladimir A. AU - Ćirković, Jovana AU - Holló, Berta Barta AU - Đokić, Veljko R. AU - Donnard, Morgan AU - Gulea, Mihaela AU - Marjanović, Ivana AU - Klisurić, Olivera R. AU - Todorović, Tamara R. PY - 2021 UR - https://dais.sanu.ac.rs/123456789/11757 AB - Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞ (1), {[Ag(L1)2]ClO4}∞ (2), {[Ag(L2)2]NO3·H2O}∞ (3) and {[Ag(L2)2]ClO4}∞ (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(I) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound 4, which can be correlated to its largest lattice volume. PB - Royal Society of Chemistry (RSC) T2 - CrystEngComm T1 - 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior SP - 4799 EP - 4815 VL - 23 IS - 27 DO - 10.1039/D1CE00394A UR - https://hdl.handle.net/21.15107/rcub_dais_11757 ER -
@article{ author = "Ristić, Predrag and Filipović, Nenad and Blagojević, Vladimir A. and Ćirković, Jovana and Holló, Berta Barta and Đokić, Veljko R. and Donnard, Morgan and Gulea, Mihaela and Marjanović, Ivana and Klisurić, Olivera R. and Todorović, Tamara R.", year = "2021", abstract = "Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞ (1), {[Ag(L1)2]ClO4}∞ (2), {[Ag(L2)2]NO3·H2O}∞ (3) and {[Ag(L2)2]ClO4}∞ (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(I) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound 4, which can be correlated to its largest lattice volume.", publisher = "Royal Society of Chemistry (RSC)", journal = "CrystEngComm", title = "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior", pages = "4799-4815", volume = "23", number = "27", doi = "10.1039/D1CE00394A", url = "https://hdl.handle.net/21.15107/rcub_dais_11757" }
Ristić, P., Filipović, N., Blagojević, V. A., Ćirković, J., Holló, B. B., Đokić, V. R., Donnard, M., Gulea, M., Marjanović, I., Klisurić, O. R.,& Todorović, T. R.. (2021). 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. in CrystEngComm Royal Society of Chemistry (RSC)., 23(27), 4799-4815. https://doi.org/10.1039/D1CE00394A https://hdl.handle.net/21.15107/rcub_dais_11757
Ristić P, Filipović N, Blagojević VA, Ćirković J, Holló BB, Đokić VR, Donnard M, Gulea M, Marjanović I, Klisurić OR, Todorović TR. 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. in CrystEngComm. 2021;23(27):4799-4815. doi:10.1039/D1CE00394A https://hdl.handle.net/21.15107/rcub_dais_11757 .
Ristić, Predrag, Filipović, Nenad, Blagojević, Vladimir A., Ćirković, Jovana, Holló, Berta Barta, Đokić, Veljko R., Donnard, Morgan, Gulea, Mihaela, Marjanović, Ivana, Klisurić, Olivera R., Todorović, Tamara R., "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior" in CrystEngComm, 23, no. 27 (2021):4799-4815, https://doi.org/10.1039/D1CE00394A ., https://hdl.handle.net/21.15107/rcub_dais_11757 .