2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior
Само за регистроване кориснике
2021
Аутори
Ristić, PredragFilipović, Nenad
Blagojević, Vladimir A.
Ćirković, Jovana
Holló, Berta Barta
Đokić, Veljko R.
Donnard, Morgan
Gulea, Mihaela
Marjanović, Ivana
Klisurić, Olivera R.
Todorović, Tamara R.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞ (1), {[Ag(L1)2]ClO4}∞ (2), {[Ag(L2)2]NO3·H2O}∞ (3) and {[Ag(L2)2]ClO4}∞ (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(I) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound 4, which can be correlated to its largest lattice volume.
Кључне речи:
coordination polymers / thiomorpholine-4-carbonitrile / piperazine-1,4-dicarbonitrile / photocatalysis / thermal behavior / intermolecular interactions / silverИзвор:
CrystEngComm, 2021, 23, 27, 4799-4815Издавач:
- Royal Society of Chemistry (RSC)
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200168 (Универзитет у Београду, Хемијски факултет) (RS-200168)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200116 (Универзитет у Београду, Пољопривредни факултет) (RS-200116)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200175 (Институт техничких наука САНУ, Београд) (RS-200175)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200125 (Универзитет у Новом Саду, Природно-математички факултет) (RS-200125)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200135 (Универзитет у Београду, Технолошко-металуршки факултет) (RS-200135)
- Matériaux hiérarchiques et fonctionnels pour la santé, l’environnement et l’énergie (HiFunMat)
Напомена:
- Peer-reviewed manuscript: https://hdl.handle.net/21.15107/rcub_dais_11757
- Supplementary information: https://hdl.handle.net/21.15107/rcub_dais_11759
- Related data: https://hdl.handle.net/21.15107/rcub_dais_11761
Повезане информације:
- Друга верзија
https://hdl.handle.net/21.15107/rcub_dais_11757 - Повезани садржај
https://hdl.handle.net/21.15107/rcub_dais_11759 - Повезани садржај
https://hdl.handle.net/21.15107/rcub_dais_11761
DOI: 10.1039/D1CE00394A
ISSN: 1466-8033
WoS: 000664682100001
Scopus: 2-s2.0-85110010702
Институција/група
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Ristić, Predrag AU - Filipović, Nenad AU - Blagojević, Vladimir A. AU - Ćirković, Jovana AU - Holló, Berta Barta AU - Đokić, Veljko R. AU - Donnard, Morgan AU - Gulea, Mihaela AU - Marjanović, Ivana AU - Klisurić, Olivera R. AU - Todorović, Tamara R. PY - 2021 UR - https://dais.sanu.ac.rs/123456789/11753 AB - Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞ (1), {[Ag(L1)2]ClO4}∞ (2), {[Ag(L2)2]NO3·H2O}∞ (3) and {[Ag(L2)2]ClO4}∞ (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(I) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound 4, which can be correlated to its largest lattice volume. PB - Royal Society of Chemistry (RSC) T2 - CrystEngComm T1 - 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior SP - 4799 EP - 4815 VL - 23 IS - 27 DO - 10.1039/D1CE00394A UR - https://hdl.handle.net/21.15107/rcub_dais_11753 ER -
@article{ author = "Ristić, Predrag and Filipović, Nenad and Blagojević, Vladimir A. and Ćirković, Jovana and Holló, Berta Barta and Đokić, Veljko R. and Donnard, Morgan and Gulea, Mihaela and Marjanović, Ivana and Klisurić, Olivera R. and Todorović, Tamara R.", year = "2021", abstract = "Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞ (1), {[Ag(L1)2]ClO4}∞ (2), {[Ag(L2)2]NO3·H2O}∞ (3) and {[Ag(L2)2]ClO4}∞ (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(I) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound 4, which can be correlated to its largest lattice volume.", publisher = "Royal Society of Chemistry (RSC)", journal = "CrystEngComm", title = "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior", pages = "4799-4815", volume = "23", number = "27", doi = "10.1039/D1CE00394A", url = "https://hdl.handle.net/21.15107/rcub_dais_11753" }
Ristić, P., Filipović, N., Blagojević, V. A., Ćirković, J., Holló, B. B., Đokić, V. R., Donnard, M., Gulea, M., Marjanović, I., Klisurić, O. R.,& Todorović, T. R.. (2021). 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. in CrystEngComm Royal Society of Chemistry (RSC)., 23(27), 4799-4815. https://doi.org/10.1039/D1CE00394A https://hdl.handle.net/21.15107/rcub_dais_11753
Ristić P, Filipović N, Blagojević VA, Ćirković J, Holló BB, Đokić VR, Donnard M, Gulea M, Marjanović I, Klisurić OR, Todorović TR. 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. in CrystEngComm. 2021;23(27):4799-4815. doi:10.1039/D1CE00394A https://hdl.handle.net/21.15107/rcub_dais_11753 .
Ristić, Predrag, Filipović, Nenad, Blagojević, Vladimir A., Ćirković, Jovana, Holló, Berta Barta, Đokić, Veljko R., Donnard, Morgan, Gulea, Mihaela, Marjanović, Ivana, Klisurić, Olivera R., Todorović, Tamara R., "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior" in CrystEngComm, 23, no. 27 (2021):4799-4815, https://doi.org/10.1039/D1CE00394A ., https://hdl.handle.net/21.15107/rcub_dais_11753 .