Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook
Аутори
Gezović, AleksandraVujković, Milica
Milović, Miloš
Grudić, Veselinka
Dominko, Robert
Mentus, Slavko
Чланак у часопису (Рецензирана верзија)
Метаподаци
Приказ свих података о документуАпстракт
Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compoun...ds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.
Кључне речи:
polyanionic materials / Na4M3(PO4)2(P2O7) / sodium-ion batteries / synthesis procedures / sodium redox processesИзвор:
Energy Storage Materials, 2021, 37, 243-273Издавач:
- Elsevier BV
Финансирање / пројекти:
- Scholarship for Doctoral Research in Montenegro
- HiSuperBat - High-Capacity Electrodes for Aqueous Rechargeable Multivalent-Ion Batteries and Supercapacitors: Next Step Towards a Hybrid Model (RS-6062667)
- NATO, Science for Peace and Security (SPS) Programme, the project SPC G5836 - SUPERCAR
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200146 (Универзитет у Београду, Факултет за физичку хемију) (RS-200146)
- Bilateral project Montenegro-Serbia: Development of ecological Li-ionic batteries
- Slovenian Research Agency, ARRS-MS-BI-ZP bilateral project and P2-0393
- Serbian Academy of Sciences and Arts, Project F-190
Напомена:
- This is the peer-reviewed version of the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021-05):243-273, https://doi.org/10.1016/j.ensm.2021.02.011
- Supplementary information: https://hdl.handle.net/21.15107/rcub_dais_11634
Повезане информације:
- Друга верзија
https://hdl.handle.net/21.15107/rcub_dais_11632 - Друга верзија
http://dx.doi.org/10.1016/j.ensm.2021.02.011 - Повезани садржај
https://hdl.handle.net/21.15107/rcub_dais_11634
DOI: 10.1016/j.ensm.2021.02.011
ISSN: 2405-8297
WoS: 000632798300001
Scopus: 2-s2.0-85101391942
Институција/група
Институт техничких наука САНУ / Institute of Technical Sciences of SASATY - JOUR AU - Gezović, Aleksandra AU - Vujković, Milica AU - Milović, Miloš AU - Grudić, Veselinka AU - Dominko, Robert AU - Mentus, Slavko PY - 2021 UR - https://dais.sanu.ac.rs/123456789/11633 AB - Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries. PB - Elsevier BV T2 - Energy Storage Materials T1 - Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook SP - 243 EP - 273 VL - 37 DO - 10.1016/j.ensm.2021.02.011 UR - https://hdl.handle.net/21.15107/rcub_dais_11633 ER -
@article{ author = "Gezović, Aleksandra and Vujković, Milica and Milović, Miloš and Grudić, Veselinka and Dominko, Robert and Mentus, Slavko", year = "2021", abstract = "Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.", publisher = "Elsevier BV", journal = "Energy Storage Materials", title = "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook", pages = "243-273", volume = "37", doi = "10.1016/j.ensm.2021.02.011", url = "https://hdl.handle.net/21.15107/rcub_dais_11633" }
Gezović, A., Vujković, M., Milović, M., Grudić, V., Dominko, R.,& Mentus, S.. (2021). Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook. in Energy Storage Materials Elsevier BV., 37, 243-273. https://doi.org/10.1016/j.ensm.2021.02.011 https://hdl.handle.net/21.15107/rcub_dais_11633
Gezović A, Vujković M, Milović M, Grudić V, Dominko R, Mentus S. Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook. in Energy Storage Materials. 2021;37:243-273. doi:10.1016/j.ensm.2021.02.011 https://hdl.handle.net/21.15107/rcub_dais_11633 .
Gezović, Aleksandra, Vujković, Milica, Milović, Miloš, Grudić, Veselinka, Dominko, Robert, Mentus, Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" in Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011 ., https://hdl.handle.net/21.15107/rcub_dais_11633 .