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HAp:Co as tunable VIS-NIR reflective pigment

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2020
125.pdf (750.3Kb)
Authors
Marković, Smilja
Stojanović, Zoran S.
Veselinović, Ljiljana
Simić, Danica
Samolov, Aleksandra
Stojković Simatović, Ivana
Conference object (Published version)
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Abstract
Radar-absorbent materials, used in stealth technology for defense aircrafts, vehicles, satellites, etc. from radar detection, are commonly based on graphite or semiconductive particles embedded in a polymer matrix. In this study, we employed Co2+ ion-substitution to improve Vis-NIR reflectivity of hydroxyapatite (Ca10(PO4)6(OH)2, HAP) powder. HAP:Co with nominally 5 at.% of Co was prepared with hydrothermal processing of a precipitate. Synthesized powder was characterized by XRD, Raman and ATR-FTIR spectroscopy, FE-SEM and TEM. Thermal stability of HAP:Co powder was examined by simultaneous TG-DTA analyzer. To modify its optical properties and obtain powders with a varietty of color tone, the HAP:Co powder was calcined at 800, 1000, and 1100 °C, in an air atmosphere, for 1 hour. Afterward, the calcined particles were used to prepare composites with poly(vinyl butyral), (PVB); the concentration range was 1 wt.% of the HAP:Co in PVB. The composite coatings, in the form of thin films on g...lass, were prepared by the solvent-casting technique, using ethanol as a fast evaporating solvent. Firstly, the HAP:Co particles were dispersed in ethanol, then PVB was added (Mowital B30H) and dissolved. To evaporate the solvent before spectrophotometric measurements, the coatings on glass were dried at room temperature for 72 hours. To comprehend optical properties of the coatings, diffuse reflection, transmission, and color coordinates were determined. We found that calcined HAP:Co particles have potential to be used in the formulation of coatings for camouflage protection.

Keywords:
hydroxyapatite / cobalt / coatings / Vis-NIR reflectivity / corrosion
Source:
9th International Scientific Conference on Defensive Technologies : OTEH2020, Belgrade, Serbia, 15-16 October 2020, 2020, 475-480
Publisher:
  • Belgrade : Military Technical Institute
Funding / projects:
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200175 (Institute of Technical Sciences of SASA, Belgrade) (RS-200175)
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200146 (University of Belgrade, Faculty of Physical Chemistry) (RS-200146)
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200325 (Military Technical Institute - MTI, Belgrade) (RS-200325)
[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_dais_10038
URI
http://www.vti.mod.gov.rs/oteh/elementi/rad/125.pdf
https://dais.sanu.ac.rs/123456789/10038
Collections
  • ИТН САНУ - Општа колекција / ITS SASA - General collection
Institution/Community
Институт техничких наука САНУ / Institute of Technical Sciences of SASA
TY  - CONF
AU  - Marković, Smilja
AU  - Stojanović, Zoran S.
AU  - Veselinović, Ljiljana
AU  - Simić, Danica
AU  - Samolov, Aleksandra
AU  - Stojković Simatović, Ivana
PY  - 2020
UR  - http://www.vti.mod.gov.rs/oteh/elementi/rad/125.pdf
UR  - https://dais.sanu.ac.rs/123456789/10038
AB  - Radar-absorbent materials, used in stealth technology for defense aircrafts, vehicles, satellites, etc. from radar detection, are commonly based on graphite or semiconductive particles embedded in a polymer matrix. In this study, we employed Co2+ ion-substitution to improve Vis-NIR reflectivity of hydroxyapatite (Ca10(PO4)6(OH)2, HAP) powder. HAP:Co with nominally 5 at.% of Co was prepared with hydrothermal processing of a precipitate. Synthesized powder was characterized by XRD, Raman and ATR-FTIR spectroscopy, FE-SEM and TEM. Thermal stability of HAP:Co powder was examined by simultaneous TG-DTA analyzer. To modify its optical properties and obtain powders with a varietty of color tone, the HAP:Co powder was calcined at 800, 1000, and 1100 °C, in an air atmosphere, for 1 hour. Afterward, the calcined particles were used to prepare composites with poly(vinyl butyral), (PVB); the concentration range was 1 wt.% of the HAP:Co in PVB. The composite coatings, in the form of thin films on glass, were prepared by the solvent-casting technique, using ethanol as a fast evaporating solvent. Firstly, the HAP:Co particles were dispersed in ethanol, then PVB was added (Mowital B30H) and dissolved. To evaporate the solvent before spectrophotometric measurements, the coatings on glass were dried at room temperature for 72 hours. To comprehend optical properties of the coatings, diffuse reflection, transmission, and color coordinates were determined. We found that calcined HAP:Co particles have potential to be used in the formulation of coatings for camouflage protection.
PB  - Belgrade : Military Technical Institute
C3  - 9th International Scientific Conference on Defensive Technologies : OTEH2020, Belgrade, Serbia, 15-16 October 2020
T1  - HAp:Co as tunable VIS-NIR reflective pigment
SP  - 475
EP  - 480
UR  - https://hdl.handle.net/21.15107/rcub_dais_10038
ER  - 
@conference{
author = "Marković, Smilja and Stojanović, Zoran S. and Veselinović, Ljiljana and Simić, Danica and Samolov, Aleksandra and Stojković Simatović, Ivana",
year = "2020",
abstract = "Radar-absorbent materials, used in stealth technology for defense aircrafts, vehicles, satellites, etc. from radar detection, are commonly based on graphite or semiconductive particles embedded in a polymer matrix. In this study, we employed Co2+ ion-substitution to improve Vis-NIR reflectivity of hydroxyapatite (Ca10(PO4)6(OH)2, HAP) powder. HAP:Co with nominally 5 at.% of Co was prepared with hydrothermal processing of a precipitate. Synthesized powder was characterized by XRD, Raman and ATR-FTIR spectroscopy, FE-SEM and TEM. Thermal stability of HAP:Co powder was examined by simultaneous TG-DTA analyzer. To modify its optical properties and obtain powders with a varietty of color tone, the HAP:Co powder was calcined at 800, 1000, and 1100 °C, in an air atmosphere, for 1 hour. Afterward, the calcined particles were used to prepare composites with poly(vinyl butyral), (PVB); the concentration range was 1 wt.% of the HAP:Co in PVB. The composite coatings, in the form of thin films on glass, were prepared by the solvent-casting technique, using ethanol as a fast evaporating solvent. Firstly, the HAP:Co particles were dispersed in ethanol, then PVB was added (Mowital B30H) and dissolved. To evaporate the solvent before spectrophotometric measurements, the coatings on glass were dried at room temperature for 72 hours. To comprehend optical properties of the coatings, diffuse reflection, transmission, and color coordinates were determined. We found that calcined HAP:Co particles have potential to be used in the formulation of coatings for camouflage protection.",
publisher = "Belgrade : Military Technical Institute",
journal = "9th International Scientific Conference on Defensive Technologies : OTEH2020, Belgrade, Serbia, 15-16 October 2020",
title = "HAp:Co as tunable VIS-NIR reflective pigment",
pages = "475-480",
url = "https://hdl.handle.net/21.15107/rcub_dais_10038"
}
Marković, S., Stojanović, Z. S., Veselinović, L., Simić, D., Samolov, A.,& Stojković Simatović, I.. (2020). HAp:Co as tunable VIS-NIR reflective pigment. in 9th International Scientific Conference on Defensive Technologies : OTEH2020, Belgrade, Serbia, 15-16 October 2020
Belgrade : Military Technical Institute., 475-480.
https://hdl.handle.net/21.15107/rcub_dais_10038
Marković S, Stojanović ZS, Veselinović L, Simić D, Samolov A, Stojković Simatović I. HAp:Co as tunable VIS-NIR reflective pigment. in 9th International Scientific Conference on Defensive Technologies : OTEH2020, Belgrade, Serbia, 15-16 October 2020. 2020;:475-480.
https://hdl.handle.net/21.15107/rcub_dais_10038 .
Marković, Smilja, Stojanović, Zoran S., Veselinović, Ljiljana, Simić, Danica, Samolov, Aleksandra, Stojković Simatović, Ivana, "HAp:Co as tunable VIS-NIR reflective pigment" in 9th International Scientific Conference on Defensive Technologies : OTEH2020, Belgrade, Serbia, 15-16 October 2020 (2020):475-480,
https://hdl.handle.net/21.15107/rcub_dais_10038 .

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