A catalytic coating composed of a mixture of RuO2 and Pt nanocrystals was prepared by a thermal procedure on a titanium substrate and used for the electrochemical oxidation of methanol. The adsorption of the intermediate CO, formed by methanol oxidation on Pt nanocrystals, depended on potential and the coating composition. An increase in the RuO2 content decreased the rate of methanol dehydrogenation and increased the rate of oxidation of the strongly bound intermediate COad. This caused a decrease in the maximum coverage of Pt nanocrystals with COad and a shift of the rapid linear drop in COad coverage to more negative potentials.
Keywords:
Direct Methanol Fuel Cell (DMFC) / electrooxidation / electrocatalysts
TY - JOUR
AU - Spasojević, Milica
AU - Ribić Zelenović, Lenka
AU - Spasojević, Miroslav
AU - Trišović, Tomislav
PY - 2020
UR - https://dais.sanu.ac.rs/123456789/10033
AB - A catalytic coating composed of a mixture of RuO2 and Pt nanocrystals was prepared by a thermal procedure on a titanium substrate and used for the electrochemical oxidation of methanol. The adsorption of the intermediate CO, formed by methanol oxidation on Pt nanocrystals, depended on potential and the coating composition. An increase in the RuO2 content decreased the rate of methanol dehydrogenation and increased the rate of oxidation of the strongly bound intermediate COad. This caused a decrease in the maximum coverage of Pt nanocrystals with COad and a shift of the rapid linear drop in COad coverage to more negative potentials.
PB - Editura Academiei Romane
T2 - Revue Roumaine de Chimie
T1 - The effect of the composition of the alloy of RuO2 and Pt nanocrystals on intermediate adsorption during methanol oxidation
SP - 481
EP - 489
VL - 65
IS - 5
DO - 10.33224/rrch.2020.65.5.08
UR - https://hdl.handle.net/21.15107/rcub_dais_10033
ER -
@article{
author = "Spasojević, Milica and Ribić Zelenović, Lenka and Spasojević, Miroslav and Trišović, Tomislav",
year = "2020",
abstract = "A catalytic coating composed of a mixture of RuO2 and Pt nanocrystals was prepared by a thermal procedure on a titanium substrate and used for the electrochemical oxidation of methanol. The adsorption of the intermediate CO, formed by methanol oxidation on Pt nanocrystals, depended on potential and the coating composition. An increase in the RuO2 content decreased the rate of methanol dehydrogenation and increased the rate of oxidation of the strongly bound intermediate COad. This caused a decrease in the maximum coverage of Pt nanocrystals with COad and a shift of the rapid linear drop in COad coverage to more negative potentials.",
publisher = "Editura Academiei Romane",
journal = "Revue Roumaine de Chimie",
title = "The effect of the composition of the alloy of RuO2 and Pt nanocrystals on intermediate adsorption during methanol oxidation",
pages = "481-489",
volume = "65",
number = "5",
doi = "10.33224/rrch.2020.65.5.08",
url = "https://hdl.handle.net/21.15107/rcub_dais_10033"
}
Spasojević, M., Ribić Zelenović, L., Spasojević, M.,& Trišović, T.. (2020). The effect of the composition of the alloy of RuO2 and Pt nanocrystals on intermediate adsorption during methanol oxidation. in Revue Roumaine de Chimie
Editura Academiei Romane., 65(5), 481-489.
https://doi.org/10.33224/rrch.2020.65.5.08
https://hdl.handle.net/21.15107/rcub_dais_10033
Spasojević M, Ribić Zelenović L, Spasojević M, Trišović T. The effect of the composition of the alloy of RuO2 and Pt nanocrystals on intermediate adsorption during methanol oxidation. in Revue Roumaine de Chimie. 2020;65(5):481-489.
doi:10.33224/rrch.2020.65.5.08
https://hdl.handle.net/21.15107/rcub_dais_10033 .
Spasojević, Milica, Ribić Zelenović, Lenka, Spasojević, Miroslav, Trišović, Tomislav, "The effect of the composition of the alloy of RuO2 and Pt nanocrystals on intermediate adsorption during methanol oxidation" in Revue Roumaine de Chimie, 65, no. 5 (2020):481-489,
https://doi.org/10.33224/rrch.2020.65.5.08 .,
https://hdl.handle.net/21.15107/rcub_dais_10033 .
