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The effect of the composition of the alloy of RuO2 and Pt nanocrystals on intermediate adsorption during methanol oxidation

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2020
bitstream_41327.pdf (655.7Kb)
Authors
Spasojević, Milica
Ribić Zelenović, Lenka
Spasojević, Miroslav
Trišović, Tomislav
Article (Published version)
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Abstract
A catalytic coating composed of a mixture of RuO2 and Pt nanocrystals was prepared by a thermal procedure on a titanium substrate and used for the electrochemical oxidation of methanol. The adsorption of the intermediate CO, formed by methanol oxidation on Pt nanocrystals, depended on potential and the coating composition. An increase in the RuO2 content decreased the rate of methanol dehydrogenation and increased the rate of oxidation of the strongly bound intermediate COad. This caused a decrease in the maximum coverage of Pt nanocrystals with COad and a shift of the rapid linear drop in COad coverage to more negative potentials.
Keywords:
Direct Methanol Fuel Cell (DMFC) / electrooxidation / electrocatalysts
Source:
Revue Roumaine de Chimie, 2020, 65, 5, 481-489
Publisher:
  • Editura Academiei Romane
Projects:
  • Directed synthesis, structure and properties of multifunctional materials (RS-172057)

DOI: 10.33224/rrch.2020.65.5.08

ISSN: 00353930

WoS: 000582608300008

Scopus: 2-s2.0-85091837121
[ Google Scholar ]
URI
https://dais.sanu.ac.rs/123456789/10033
Collections
  • ITN SANU - Opšta kolekcija / ITS SASA - General collection
Institution
Институт техничких наука САНУ / Institute of Technical Sciences of SASA
TY  - JOUR
AU  - Spasojević, Milica
AU  - Ribić Zelenović, Lenka
AU  - Spasojević, Miroslav
AU  - Trišović, Tomislav
PY  - 2020
UR  - https://dais.sanu.ac.rs/123456789/10033
AB  - A catalytic coating composed of a mixture of RuO2 and Pt nanocrystals was prepared by a thermal procedure on a titanium substrate and used for the electrochemical oxidation of methanol. The adsorption of the intermediate CO, formed by methanol oxidation on Pt nanocrystals, depended on potential and the coating composition. An increase in the RuO2 content decreased the rate of methanol dehydrogenation and increased the rate of oxidation of the strongly bound intermediate COad. This caused a decrease in the maximum coverage of Pt nanocrystals with COad and a shift of the rapid linear drop in COad coverage to more negative potentials.
PB  - Editura Academiei Romane
T2  - Revue Roumaine de Chimie
T1  - The effect of the composition of the alloy of RuO2 and Pt nanocrystals on intermediate adsorption during methanol oxidation
SP  - 481
EP  - 489
VL  - 65
IS  - 5
DO  - 10.33224/rrch.2020.65.5.08
ER  - 
@article{
author = "Spasojević, Milica and Ribić Zelenović, Lenka and Spasojević, Miroslav and Trišović, Tomislav",
year = "2020",
url = "https://dais.sanu.ac.rs/123456789/10033",
abstract = "A catalytic coating composed of a mixture of RuO2 and Pt nanocrystals was prepared by a thermal procedure on a titanium substrate and used for the electrochemical oxidation of methanol. The adsorption of the intermediate CO, formed by methanol oxidation on Pt nanocrystals, depended on potential and the coating composition. An increase in the RuO2 content decreased the rate of methanol dehydrogenation and increased the rate of oxidation of the strongly bound intermediate COad. This caused a decrease in the maximum coverage of Pt nanocrystals with COad and a shift of the rapid linear drop in COad coverage to more negative potentials.",
publisher = "Editura Academiei Romane",
journal = "Revue Roumaine de Chimie",
title = "The effect of the composition of the alloy of RuO2 and Pt nanocrystals on intermediate adsorption during methanol oxidation",
pages = "481-489",
volume = "65",
number = "5",
doi = "10.33224/rrch.2020.65.5.08"
}
Spasojević M, Ribić Zelenović L, Spasojević M, Trišović T. The effect of the composition of the alloy of RuO2 and Pt nanocrystals on intermediate adsorption during methanol oxidation. Revue Roumaine de Chimie. 2020;65(5):481-489
Spasojević, M., Ribić Zelenović, L., Spasojević, M.,& Trišović, T. (2020). The effect of the composition of the alloy of RuO2 and Pt nanocrystals on intermediate adsorption during methanol oxidation.
Revue Roumaine de ChimieEditura Academiei Romane., 65(5), 481-489. 
https://doi.org/10.33224/rrch.2020.65.5.08
Spasojević Milica, Ribić Zelenović Lenka, Spasojević Miroslav, Trišović Tomislav, "The effect of the composition of the alloy of RuO2 and Pt nanocrystals on intermediate adsorption during methanol oxidation" 65, no. 5 (2020):481-489,
https://doi.org/10.33224/rrch.2020.65.5.08 .

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