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Mussolini of Yugoslavia? The Milan Stojadinović Regime and the Impact of Italian Fascism, 1937-1939

Bakić, Dragan

(Trieste : EUT Edizioni Università di Trieste, 2021-06)

TY  - JOUR
AU  - Bakić, Dragan
PY  - 2021-06
AB  - The Yugoslav prime minister (and foreign minister), Milan Stojadinović, and Italian foreign minister, Galeazzo Ciano, signed a friendship agreement on 25 March 1937, ushering in an atmosphere of confidence between the two formerly hostile countries. This rapprochement resulted from the changing international constellation: the resurgent Germany was expected to annex Austria and become a powerful neighbour to both countries. Ciano and Stojadinović struck close personal relations which no doubt buttressed the solidity of their agreement. Moreover, Ciano believed that Stojadinović was inclined towards authoritarian concept of power. There were also increasing signs that the Stojadinović regime was acquiring some fascist trappings in line with the new course of foreign policy. Indeed, Prince Regent, Paul, dropped Stojadinović from the government in February 1939 because he came to believe that his premier was intent on becoming a fascist dictator. This paper will explore whether there was substance to the often repeated accusations that Stojadinović was sliding towards fascism. Much of these accusations were centred on his foreign policy, especially his cordial relations with the fascist regime in Italy and, to a lesser extent, with Nazi Germany. Therefore, this paper will analyse, on the one hand, to what extent Stojadinović aligned Yugoslavia's conduct of foreign affairs with Rome's foreign policy and, on the other, to what degree the Yugoslav-Italian rapprochement was reflected in internal developments which might smack of fascism. The analysis will be undertaken with reference to the recent and influential theories of fascism.
PB  - Trieste : EUT Edizioni Università di Trieste
T2  - QUALESTORIA. Rivista di storia contemporanea.  L’Italia e la Jugoslavia tra le due guerre
T1  - Mussolini of Yugoslavia? The Milan Stojadinović Regime and the Impact of Italian Fascism, 1937-1939
SP  - 243
EP  - 267
VL  - XLIX
IS  - 1
DO  - 10.13137/0393-6082/32196
ER  - 
@article{
author = "Bakić, Dragan",
year = "2021-06",
abstract = "The Yugoslav prime minister (and foreign minister), Milan Stojadinović, and Italian foreign minister, Galeazzo Ciano, signed a friendship agreement on 25 March 1937, ushering in an atmosphere of confidence between the two formerly hostile countries. This rapprochement resulted from the changing international constellation: the resurgent Germany was expected to annex Austria and become a powerful neighbour to both countries. Ciano and Stojadinović struck close personal relations which no doubt buttressed the solidity of their agreement. Moreover, Ciano believed that Stojadinović was inclined towards authoritarian concept of power. There were also increasing signs that the Stojadinović regime was acquiring some fascist trappings in line with the new course of foreign policy. Indeed, Prince Regent, Paul, dropped Stojadinović from the government in February 1939 because he came to believe that his premier was intent on becoming a fascist dictator. This paper will explore whether there was substance to the often repeated accusations that Stojadinović was sliding towards fascism. Much of these accusations were centred on his foreign policy, especially his cordial relations with the fascist regime in Italy and, to a lesser extent, with Nazi Germany. Therefore, this paper will analyse, on the one hand, to what extent Stojadinović aligned Yugoslavia's conduct of foreign affairs with Rome's foreign policy and, on the other, to what degree the Yugoslav-Italian rapprochement was reflected in internal developments which might smack of fascism. The analysis will be undertaken with reference to the recent and influential theories of fascism.",
publisher = "Trieste : EUT Edizioni Università di Trieste",
journal = "QUALESTORIA. Rivista di storia contemporanea.  L’Italia e la Jugoslavia tra le due guerre",
title = "Mussolini of Yugoslavia? The Milan Stojadinović Regime and the Impact of Italian Fascism, 1937-1939",
pages = "243-267",
volume = "XLIX",
number = "1",
doi = "10.13137/0393-6082/32196"
}
Bakić, D. (2021-06). Mussolini of Yugoslavia? The Milan Stojadinović Regime and the Impact of Italian Fascism, 1937-1939.
QUALESTORIA. Rivista di storia contemporanea.  L’Italia e la Jugoslavia tra le due guerre
Trieste : EUT Edizioni Università di Trieste., XLIX(1), 243-267.
https://doi.org/10.13137/0393-6082/32196
Bakić D. Mussolini of Yugoslavia? The Milan Stojadinović Regime and the Impact of Italian Fascism, 1937-1939. QUALESTORIA. Rivista di storia contemporanea.  L’Italia e la Jugoslavia tra le due guerre. 2021;XLIX(1):243-267.
doi:10.13137/0393-6082/32196.
Bakić Dragan, "Mussolini of Yugoslavia? The Milan Stojadinović Regime and the Impact of Italian Fascism, 1937-1939" QUALESTORIA. Rivista di storia contemporanea.  L’Italia e la Jugoslavia tra le due guerre, XLIX, no. 1 (2021-06):243-267,
https://doi.org/10.13137/0393-6082/32196 .

Crystallographic Information for the article: 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior

Ristić, Predrag; Filipović, Nenad; Blagojević, Vladimir A.; Ćirković, Jovana; Holló, Berta Barta; Đokić, Veljko R.; Donnard, Morgan; Gulea, Mihaela; Marjanović, Ivana; Klisurić, Olivera R.; Todorović, Tamara R.

(Royal Society of Chemistry (RSC), 2021)

TY  - BOOK
AU  - Ristić, Predrag
AU  - Filipović, Nenad
AU  - Blagojević, Vladimir A.
AU  - Ćirković, Jovana
AU  - Holló, Berta Barta
AU  - Đokić, Veljko R.
AU  - Donnard, Morgan
AU  - Gulea, Mihaela
AU  - Marjanović, Ivana
AU  - Klisurić, Olivera R.
AU  - Todorović, Tamara R.
PY  - 2021
AB  - Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞ (1), {[Ag(L1)2]ClO4}∞ (2), {[Ag(L2)2]NO3·H2O}∞ (3) and {[Ag(L2)2]ClO4}∞ (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(I) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound 4, which can be correlated to its largest lattice volume.
PB  - Royal Society of Chemistry (RSC)
T2  - CrystEngComm
T1  - Crystallographic Information for the article: 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior
VL  - 23
IS  - 27
ER  - 
@book{
author = "Ristić, Predrag and Filipović, Nenad and Blagojević, Vladimir A. and Ćirković, Jovana and Holló, Berta Barta and Đokić, Veljko R. and Donnard, Morgan and Gulea, Mihaela and Marjanović, Ivana and Klisurić, Olivera R. and Todorović, Tamara R.",
year = "2021",
abstract = "Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞ (1), {[Ag(L1)2]ClO4}∞ (2), {[Ag(L2)2]NO3·H2O}∞ (3) and {[Ag(L2)2]ClO4}∞ (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(I) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound 4, which can be correlated to its largest lattice volume.",
publisher = "Royal Society of Chemistry (RSC)",
journal = "CrystEngComm",
title = "Crystallographic Information for the article: 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior",
volume = "23",
number = "27"
}
Ristić, P., Filipović, N., Blagojević, V. A., Ćirković, J., Holló, B. B., Đokić, V. R., Donnard, M., Gulea, M., Marjanović, I., Klisurić, O. R.,& Todorović, T. R. (2021). Crystallographic Information for the article: 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior.
CrystEngComm
Royal Society of Chemistry (RSC)., 23(27).
Ristić P, Filipović N, Blagojević VA, Ćirković J, Holló BB, Đokić VR, Donnard M, Gulea M, Marjanović I, Klisurić OR, Todorović TR. Crystallographic Information for the article: 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. CrystEngComm. 2021;23(27).
Ristić Predrag, Filipović Nenad, Blagojević Vladimir A., Ćirković Jovana, Holló Berta Barta, Đokić Veljko R., Donnard Morgan, Gulea Mihaela, Marjanović Ivana, Klisurić Olivera R., Todorović Tamara R., "Crystallographic Information for the article: 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior" CrystEngComm, 23, no. 27 (2021)

Supplementary information for the article: 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior

Ristić, Predrag; Filipović, Nenad; Blagojević, Vladimir A.; Ćirković, Jovana; Holló, Berta Barta; Đokić, Veljko R.; Donnard, Morgan; Gulea, Mihaela; Marjanović, Ivana; Klisurić, Olivera R.; Todorović, Tamara R.

(Royal Society of Chemistry (RSC), 2021)

TY  - BOOK
AU  - Ristić, Predrag
AU  - Filipović, Nenad
AU  - Blagojević, Vladimir A.
AU  - Ćirković, Jovana
AU  - Holló, Berta Barta
AU  - Đokić, Veljko R.
AU  - Donnard, Morgan
AU  - Gulea, Mihaela
AU  - Marjanović, Ivana
AU  - Klisurić, Olivera R.
AU  - Todorović, Tamara R.
PY  - 2021
AB  - Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞ (1), {[Ag(L1)2]ClO4}∞ (2), {[Ag(L2)2]NO3·H2O}∞ (3) and {[Ag(L2)2]ClO4}∞ (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(I) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound 4, which can be correlated to its largest lattice volume.
PB  - Royal Society of Chemistry (RSC)
T2  - CrystEngComm
T1  - Supplementary information for the article: 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior
VL  - 23
IS  - 27
ER  - 
@book{
author = "Ristić, Predrag and Filipović, Nenad and Blagojević, Vladimir A. and Ćirković, Jovana and Holló, Berta Barta and Đokić, Veljko R. and Donnard, Morgan and Gulea, Mihaela and Marjanović, Ivana and Klisurić, Olivera R. and Todorović, Tamara R.",
year = "2021",
abstract = "Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞ (1), {[Ag(L1)2]ClO4}∞ (2), {[Ag(L2)2]NO3·H2O}∞ (3) and {[Ag(L2)2]ClO4}∞ (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(I) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound 4, which can be correlated to its largest lattice volume.",
publisher = "Royal Society of Chemistry (RSC)",
journal = "CrystEngComm",
title = "Supplementary information for the article: 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior",
volume = "23",
number = "27"
}
Ristić, P., Filipović, N., Blagojević, V. A., Ćirković, J., Holló, B. B., Đokić, V. R., Donnard, M., Gulea, M., Marjanović, I., Klisurić, O. R.,& Todorović, T. R. (2021). Supplementary information for the article: 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior.
CrystEngComm
Royal Society of Chemistry (RSC)., 23(27).
Ristić P, Filipović N, Blagojević VA, Ćirković J, Holló BB, Đokić VR, Donnard M, Gulea M, Marjanović I, Klisurić OR, Todorović TR. Supplementary information for the article: 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. CrystEngComm. 2021;23(27).
Ristić Predrag, Filipović Nenad, Blagojević Vladimir A., Ćirković Jovana, Holló Berta Barta, Đokić Veljko R., Donnard Morgan, Gulea Mihaela, Marjanović Ivana, Klisurić Olivera R., Todorović Tamara R., "Supplementary information for the article: 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior" CrystEngComm, 23, no. 27 (2021)

2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior

Ristić, Predrag; Filipović, Nenad; Blagojević, Vladimir A.; Ćirković, Jovana; Holló, Berta Barta; Đokić, Veljko R.; Donnard, Morgan; Gulea, Mihaela; Marjanović, Ivana; Klisurić, Olivera R.; Todorović, Tamara R.

(Royal Society of Chemistry (RSC), 2021)

TY  - JOUR
AU  - Ristić, Predrag
AU  - Filipović, Nenad
AU  - Blagojević, Vladimir A.
AU  - Ćirković, Jovana
AU  - Holló, Berta Barta
AU  - Đokić, Veljko R.
AU  - Donnard, Morgan
AU  - Gulea, Mihaela
AU  - Marjanović, Ivana
AU  - Klisurić, Olivera R.
AU  - Todorović, Tamara R.
PY  - 2021
AB  - Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞ (1), {[Ag(L1)2]ClO4}∞ (2), {[Ag(L2)2]NO3·H2O}∞ (3) and {[Ag(L2)2]ClO4}∞ (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(I) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound 4, which can be correlated to its largest lattice volume.
PB  - Royal Society of Chemistry (RSC)
T2  - CrystEngComm
T1  - 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior
SP  - 4799
EP  - 4815
VL  - 23
IS  - 27
DO  - 10.1039/D1CE00394A
ER  - 
@article{
author = "Ristić, Predrag and Filipović, Nenad and Blagojević, Vladimir A. and Ćirković, Jovana and Holló, Berta Barta and Đokić, Veljko R. and Donnard, Morgan and Gulea, Mihaela and Marjanović, Ivana and Klisurić, Olivera R. and Todorović, Tamara R.",
year = "2021",
abstract = "Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞ (1), {[Ag(L1)2]ClO4}∞ (2), {[Ag(L2)2]NO3·H2O}∞ (3) and {[Ag(L2)2]ClO4}∞ (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(I) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound 4, which can be correlated to its largest lattice volume.",
publisher = "Royal Society of Chemistry (RSC)",
journal = "CrystEngComm",
title = "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior",
pages = "4799-4815",
volume = "23",
number = "27",
doi = "10.1039/D1CE00394A"
}
Ristić, P., Filipović, N., Blagojević, V. A., Ćirković, J., Holló, B. B., Đokić, V. R., Donnard, M., Gulea, M., Marjanović, I., Klisurić, O. R.,& Todorović, T. R. (2021). 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior.
CrystEngComm
Royal Society of Chemistry (RSC)., 23(27), 4799-4815.
https://doi.org/10.1039/D1CE00394A
Ristić P, Filipović N, Blagojević VA, Ćirković J, Holló BB, Đokić VR, Donnard M, Gulea M, Marjanović I, Klisurić OR, Todorović TR. 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. CrystEngComm. 2021;23(27):4799-4815.
doi:10.1039/D1CE00394A.
Ristić Predrag, Filipović Nenad, Blagojević Vladimir A., Ćirković Jovana, Holló Berta Barta, Đokić Veljko R., Donnard Morgan, Gulea Mihaela, Marjanović Ivana, Klisurić Olivera R., Todorović Tamara R., "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior" CrystEngComm, 23, no. 27 (2021):4799-4815,
https://doi.org/10.1039/D1CE00394A .
4

2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior

Ristić, Predrag; Filipović, Nenad; Blagojević, Vladimir A.; Ćirković, Jovana; Holló, Berta Barta; Đokić, Veljko R.; Donnard, Morgan; Gulea, Mihaela; Marjanović, Ivana; Klisurić, Olivera R.; Todorović, Tamara R.

(Royal Society of Chemistry (RSC), 2021)

TY  - JOUR
AU  - Ristić, Predrag
AU  - Filipović, Nenad
AU  - Blagojević, Vladimir A.
AU  - Ćirković, Jovana
AU  - Holló, Berta Barta
AU  - Đokić, Veljko R.
AU  - Donnard, Morgan
AU  - Gulea, Mihaela
AU  - Marjanović, Ivana
AU  - Klisurić, Olivera R.
AU  - Todorović, Tamara R.
PY  - 2021
AB  - Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞ (1), {[Ag(L1)2]ClO4}∞ (2), {[Ag(L2)2]NO3·H2O}∞ (3) and {[Ag(L2)2]ClO4}∞ (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(I) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound 4, which can be correlated to its largest lattice volume.
PB  - Royal Society of Chemistry (RSC)
T2  - CrystEngComm
T1  - 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior
SP  - 4799
EP  - 4815
VL  - 23
IS  - 27
DO  - 10.1039/D1CE00394A
ER  - 
@article{
author = "Ristić, Predrag and Filipović, Nenad and Blagojević, Vladimir A. and Ćirković, Jovana and Holló, Berta Barta and Đokić, Veljko R. and Donnard, Morgan and Gulea, Mihaela and Marjanović, Ivana and Klisurić, Olivera R. and Todorović, Tamara R.",
year = "2021",
abstract = "Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞ (1), {[Ag(L1)2]ClO4}∞ (2), {[Ag(L2)2]NO3·H2O}∞ (3) and {[Ag(L2)2]ClO4}∞ (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(I) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound 4, which can be correlated to its largest lattice volume.",
publisher = "Royal Society of Chemistry (RSC)",
journal = "CrystEngComm",
title = "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior",
pages = "4799-4815",
volume = "23",
number = "27",
doi = "10.1039/D1CE00394A"
}
Ristić, P., Filipović, N., Blagojević, V. A., Ćirković, J., Holló, B. B., Đokić, V. R., Donnard, M., Gulea, M., Marjanović, I., Klisurić, O. R.,& Todorović, T. R. (2021). 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior.
CrystEngComm
Royal Society of Chemistry (RSC)., 23(27), 4799-4815.
https://doi.org/10.1039/D1CE00394A
Ristić P, Filipović N, Blagojević VA, Ćirković J, Holló BB, Đokić VR, Donnard M, Gulea M, Marjanović I, Klisurić OR, Todorović TR. 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. CrystEngComm. 2021;23(27):4799-4815.
doi:10.1039/D1CE00394A.
Ristić Predrag, Filipović Nenad, Blagojević Vladimir A., Ćirković Jovana, Holló Berta Barta, Đokić Veljko R., Donnard Morgan, Gulea Mihaela, Marjanović Ivana, Klisurić Olivera R., Todorović Tamara R., "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior" CrystEngComm, 23, no. 27 (2021):4799-4815,
https://doi.org/10.1039/D1CE00394A .
4

XRPD data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp

(Belgrade : Institute of Technical Sciences of SASA, 2021)

TY  - BOOK
PY  - 2021
AB  - XRPD data for NaY0.78Yb0.2Tm0.02F4, collected on Philips PW-1050, synthesized for the CORE-SHELL Project through EDTA assisted solvothermal processing, Et:H2O=2:1, FF=60%, c=0.01 M, 200°C/2h; Re:NaF=1:7, Re:EDTA=1:1. 
***Dataset contents***
XRPD-Sample2.2.csv, comma-separated values (.csv) 
README.txt
***Column headers and field types***
2 theta, degree (number.decimal) 
Intensity, counts (number.decimal)
PB  - Belgrade : Institute of Technical Sciences of SASA
T1  - XRPD data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp
UR  - https://hdl.handle.net/21.15107/rcub_dais_11593
ER  - 
@book{
year = "2021",
abstract = "XRPD data for NaY0.78Yb0.2Tm0.02F4, collected on Philips PW-1050, synthesized for the CORE-SHELL Project through EDTA assisted solvothermal processing, Et:H2O=2:1, FF=60%, c=0.01 M, 200°C/2h; Re:NaF=1:7, Re:EDTA=1:1. 
***Dataset contents***
XRPD-Sample2.2.csv, comma-separated values (.csv) 
README.txt
***Column headers and field types***
2 theta, degree (number.decimal) 
Intensity, counts (number.decimal)",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
title = "XRPD data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp",
url = "https://hdl.handle.net/21.15107/rcub_dais_11593"
}
 (2021). XRPD data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp.

Belgrade : Institute of Technical Sciences of SASA..
 XRPD data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp. 2021;.
, "XRPD data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp" (2021)

FESEM analysis of NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp

(Belgrade : Institute of Technical Sciences of SASA, 2021)

TY  - BOOK
PY  - 2021
AB  - FESEM analysis of NaY0.78Yb0.2Tm0.02F4 , analyzed on Tescan Mira3 FESEM microscope, MAG 200 kx, synthesized for the CORE-SHELL Project, through EDTA-assisted solvothermal processing, Et:H2O=2:1, FF=60%, c=0.01 M, 200°C/2h; Re:NaF=1:7, Re:EDTA=1:1. 

Data were collected on 05/02/2021 at the University of Belgrade - Faculty of Technology and Metallurgy. 

***Dataset contents*** 
FESEM-Sample2.2.tif, image (.tif) 
README-FESEM.txt, text (.txt)
PB  - Belgrade : Institute of Technical Sciences of SASA
T1  - FESEM analysis of NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp
UR  - https://hdl.handle.net/21.15107/rcub_dais_11597
ER  - 
@book{
year = "2021",
abstract = "FESEM analysis of NaY0.78Yb0.2Tm0.02F4 , analyzed on Tescan Mira3 FESEM microscope, MAG 200 kx, synthesized for the CORE-SHELL Project, through EDTA-assisted solvothermal processing, Et:H2O=2:1, FF=60%, c=0.01 M, 200°C/2h; Re:NaF=1:7, Re:EDTA=1:1. 

Data were collected on 05/02/2021 at the University of Belgrade - Faculty of Technology and Metallurgy. 

***Dataset contents*** 
FESEM-Sample2.2.tif, image (.tif) 
README-FESEM.txt, text (.txt)",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
title = "FESEM analysis of NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp",
url = "https://hdl.handle.net/21.15107/rcub_dais_11597"
}
 (2021). FESEM analysis of NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp.

Belgrade : Institute of Technical Sciences of SASA..
 FESEM analysis of NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp. 2021;.
, "FESEM analysis of NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp" (2021)

PL data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp

(Belgrade : Institute of Technical Sciences of SASA, 2021)

TY  - BOOK
PY  - 2021
AB  - PL data for NaY0.78Yb0.2Tm0.02F4 collected by Edmund optics Glaciertm X TE Cooled CCD Array Spectrometer after excitation at 980nm, by 980M 1W Dragon Lasers, synthesized for CORE-SHELL Project through EDTA assisted solvothermal processing, Et:H2O=2:1, FF=60 %, c=0.01 M, 200°C/2h; Re:NaF=1:7, Re:EDTA=1:1. 

***Dataset contents***
PL-Sample2.2-500ms.csv, comma-separated values (.csv)
README-PL.txt

***Column headers and field types***
Wavelenght, nm (number.decimal)
Intensity, a.u. (number.decimal)
PB  - Belgrade : Institute of Technical Sciences of SASA
T1  - PL data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp
UR  - https://hdl.handle.net/21.15107/rcub_dais_11595
ER  - 
@book{
year = "2021",
abstract = "PL data for NaY0.78Yb0.2Tm0.02F4 collected by Edmund optics Glaciertm X TE Cooled CCD Array Spectrometer after excitation at 980nm, by 980M 1W Dragon Lasers, synthesized for CORE-SHELL Project through EDTA assisted solvothermal processing, Et:H2O=2:1, FF=60 %, c=0.01 M, 200°C/2h; Re:NaF=1:7, Re:EDTA=1:1. 

***Dataset contents***
PL-Sample2.2-500ms.csv, comma-separated values (.csv)
README-PL.txt

***Column headers and field types***
Wavelenght, nm (number.decimal)
Intensity, a.u. (number.decimal)",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
title = "PL data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp",
url = "https://hdl.handle.net/21.15107/rcub_dais_11595"
}
 (2021). PL data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp.

Belgrade : Institute of Technical Sciences of SASA..
 PL data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp. 2021;.
, "PL data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp" (2021)

FTIR data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp

(Belgrade : Institute of Technical Sciences of SASA, 2021)

TY  - BOOK
PY  - 2021
AB  - FTIR data for NaY0.78Yb0.2Tm0.02F4 collected on Thermo Scientific Nicolet IS10, synthesized for the CORE-SHELL Project, through EDTA-assisted solvothermal processing, Et:H2O=2:1, FF=60%, c=0.01 M, 200°C/2h; Re:NaF=1:7, Re:EDTA=1:1. 

***Dataset contents***
FTIR-Sample2.2.csv, comma-separated values (.csv)
README-FTIR.txt

***Column headers and field types***
Wavenumbers x106, cm-1 (number.decimal)
Transmittance x106, %  (number.decimal)
PB  - Belgrade : Institute of Technical Sciences of SASA
T1  - FTIR data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp
UR  - https://hdl.handle.net/21.15107/rcub_dais_11594
ER  - 
@book{
year = "2021",
abstract = "FTIR data for NaY0.78Yb0.2Tm0.02F4 collected on Thermo Scientific Nicolet IS10, synthesized for the CORE-SHELL Project, through EDTA-assisted solvothermal processing, Et:H2O=2:1, FF=60%, c=0.01 M, 200°C/2h; Re:NaF=1:7, Re:EDTA=1:1. 

***Dataset contents***
FTIR-Sample2.2.csv, comma-separated values (.csv)
README-FTIR.txt

***Column headers and field types***
Wavenumbers x106, cm-1 (number.decimal)
Transmittance x106, %  (number.decimal)",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
title = "FTIR data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp",
url = "https://hdl.handle.net/21.15107/rcub_dais_11594"
}
 (2021). FTIR data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp.

Belgrade : Institute of Technical Sciences of SASA..
 FTIR data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp. 2021;.
, "FTIR data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp" (2021)

CIE data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp

(Belgrade : Institute of Technical Sciences of SASA, 2021)

TY  - BOOK
PY  - 2021
AB  - CIE data for NaY0.78Yb0.2Tm0.02F4 analyzed by Color calculator, synthesized for the CORE-SHELL Project, through EDTA-assisted solvothermal processing, Et:H2O=2:1, FF=60 %, c=0.01 M, 200oC/2h; Re:NaF=1:7, Re:EDTA=1:1. 

***Dataset contents***
CIE-Sample2.2asp500ms.tif,  TIF Image (.tif)
README-CIE.txt, text (.txt)
PB  - Belgrade : Institute of Technical Sciences of SASA
T1  - CIE data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp
UR  - https://hdl.handle.net/21.15107/rcub_dais_11596
ER  - 
@book{
year = "2021",
abstract = "CIE data for NaY0.78Yb0.2Tm0.02F4 analyzed by Color calculator, synthesized for the CORE-SHELL Project, through EDTA-assisted solvothermal processing, Et:H2O=2:1, FF=60 %, c=0.01 M, 200oC/2h; Re:NaF=1:7, Re:EDTA=1:1. 

***Dataset contents***
CIE-Sample2.2asp500ms.tif,  TIF Image (.tif)
README-CIE.txt, text (.txt)",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
title = "CIE data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp",
url = "https://hdl.handle.net/21.15107/rcub_dais_11596"
}
 (2021). CIE data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp.

Belgrade : Institute of Technical Sciences of SASA..
 CIE data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp. 2021;.
, "CIE data for NaYF4:Yb,Tm; System 1 EDTA, Experiment 2, Sample 2.2 asp" (2021)

Electronic Supplementary Information associated with the article: Degli Esposti Lorenzo, Marković Smilja, Ignjatović Nenad, Panseri Silvia, Montesi Monica, Adamiano Alessio, Fosca Marco, Rau Julietta V., Uskoković Vuk, Iafisco Michele, "Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics." Journal of Materials Chemistry B, 9, no. 24 (2021):4832-4845, https://doi.org/10.1039/D1TB00601K

Degli Esposti, Lorenzo; Marković, Smilja; Ignjatović, Nenad; Panseri, Silvia; Montesi, Monica; Adamiano, Alessio; Fosca, Marco; Rau, Julietta V.; Uskoković, Vuk; Iafisco, Michele

(Royal Society of Chemistry, 2021)

TY  - BOOK
AU  - Degli Esposti, Lorenzo
AU  - Marković, Smilja
AU  - Ignjatović, Nenad
AU  - Panseri, Silvia
AU  - Montesi, Monica
AU  - Adamiano, Alessio
AU  - Fosca, Marco
AU  - Rau, Julietta V.
AU  - Uskoković, Vuk
AU  - Iafisco, Michele
PY  - 2021
AB  - Figure S1. The shift in the crystallization peak for (A) Cit-ACP-1 and (B) Cit-FACP-1 to higher temperatures in direct proportion with the heating rate; Figure S2. TGA curves of calcined Cit-ACP-4, Cit-ACP-2, and Cit-ACP-1; Figure S3. Pictures of calcined (A) Cit-ACP-4 and (B) Cit-ACP-1
PB  - Royal Society of Chemistry
T2  - Journal of Materials Chemistry B
T1  - Electronic Supplementary Information associated with the article: Degli Esposti Lorenzo, Marković Smilja, Ignjatović Nenad, Panseri Silvia, Montesi Monica, Adamiano Alessio, Fosca Marco, Rau Julietta V., Uskoković Vuk, Iafisco Michele, "Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics." Journal of Materials Chemistry B, 9, no. 24 (2021):4832-4845, https://doi.org/10.1039/D1TB00601K
VL  - 9
IS  - 24
UR  - https://hdl.handle.net/21.15107/rcub_dais_11642
ER  - 
@book{
author = "Degli Esposti, Lorenzo and Marković, Smilja and Ignjatović, Nenad and Panseri, Silvia and Montesi, Monica and Adamiano, Alessio and Fosca, Marco and Rau, Julietta V. and Uskoković, Vuk and Iafisco, Michele",
year = "2021",
abstract = "Figure S1. The shift in the crystallization peak for (A) Cit-ACP-1 and (B) Cit-FACP-1 to higher temperatures in direct proportion with the heating rate; Figure S2. TGA curves of calcined Cit-ACP-4, Cit-ACP-2, and Cit-ACP-1; Figure S3. Pictures of calcined (A) Cit-ACP-4 and (B) Cit-ACP-1",
publisher = "Royal Society of Chemistry",
journal = "Journal of Materials Chemistry B",
title = "Electronic Supplementary Information associated with the article: Degli Esposti Lorenzo, Marković Smilja, Ignjatović Nenad, Panseri Silvia, Montesi Monica, Adamiano Alessio, Fosca Marco, Rau Julietta V., Uskoković Vuk, Iafisco Michele, "Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics." Journal of Materials Chemistry B, 9, no. 24 (2021):4832-4845, https://doi.org/10.1039/D1TB00601K",
volume = "9",
number = "24",
url = "https://hdl.handle.net/21.15107/rcub_dais_11642"
}
Degli Esposti, L., Marković, S., Ignjatović, N., Panseri, S., Montesi, M., Adamiano, A., Fosca, M., Rau, J. V., Uskoković, V.,& Iafisco, M. (2021). Electronic Supplementary Information associated with the article: Degli Esposti Lorenzo, Marković Smilja, Ignjatović Nenad, Panseri Silvia, Montesi Monica, Adamiano Alessio, Fosca Marco, Rau Julietta V., Uskoković Vuk, Iafisco Michele, "Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics." Journal of Materials Chemistry B, 9, no. 24 (2021):4832-4845, https://doi.org/10.1039/D1TB00601K.
Journal of Materials Chemistry B
Royal Society of Chemistry., 9(24).
Degli Esposti L, Marković S, Ignjatović N, Panseri S, Montesi M, Adamiano A, Fosca M, Rau JV, Uskoković V, Iafisco M. Electronic Supplementary Information associated with the article: Degli Esposti Lorenzo, Marković Smilja, Ignjatović Nenad, Panseri Silvia, Montesi Monica, Adamiano Alessio, Fosca Marco, Rau Julietta V., Uskoković Vuk, Iafisco Michele, "Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics." Journal of Materials Chemistry B, 9, no. 24 (2021):4832-4845, https://doi.org/10.1039/D1TB00601K. Journal of Materials Chemistry B. 2021;9(24).
Degli Esposti Lorenzo, Marković Smilja, Ignjatović Nenad, Panseri Silvia, Montesi Monica, Adamiano Alessio, Fosca Marco, Rau Julietta V., Uskoković Vuk, Iafisco Michele, "Electronic Supplementary Information associated with the article: Degli Esposti Lorenzo, Marković Smilja, Ignjatović Nenad, Panseri Silvia, Montesi Monica, Adamiano Alessio, Fosca Marco, Rau Julietta V., Uskoković Vuk, Iafisco Michele, "Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics." Journal of Materials Chemistry B, 9, no. 24 (2021):4832-4845, https://doi.org/10.1039/D1TB00601K" Journal of Materials Chemistry B, 9, no. 24 (2021)

Supplementary information for the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011

Gezović, Aleksandra; Vujković, Milica; Milović, Miloš; Grudić, Veselinka; Dominko, Robert; Mentus, Slavko

(Elsevier BV, 2021)

TY  - BOOK
AU  - Gezović, Aleksandra
AU  - Vujković, Milica
AU  - Milović, Miloš
AU  - Grudić, Veselinka
AU  - Dominko, Robert
AU  - Mentus, Slavko
PY  - 2021
AB  - Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.
PB  - Elsevier BV
T2  - Energy Storage Materials
T1  - Supplementary information for the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011
VL  - 37
UR  - https://hdl.handle.net/21.15107/rcub_dais_11634
ER  - 
@book{
author = "Gezović, Aleksandra and Vujković, Milica and Milović, Miloš and Grudić, Veselinka and Dominko, Robert and Mentus, Slavko",
year = "2021",
abstract = "Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.",
publisher = "Elsevier BV",
journal = "Energy Storage Materials",
title = "Supplementary information for the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011",
volume = "37",
url = "https://hdl.handle.net/21.15107/rcub_dais_11634"
}
Gezović, A., Vujković, M., Milović, M., Grudić, V., Dominko, R.,& Mentus, S. (2021). Supplementary information for the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011.
Energy Storage Materials
Elsevier BV., 37.
Gezović A, Vujković M, Milović M, Grudić V, Dominko R, Mentus S. Supplementary information for the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011. Energy Storage Materials. 2021;37.
Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Supplementary information for the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011" Energy Storage Materials, 37 (2021)

Assessment of Grain Size and Grain Refinement Efficiency by Calculation of Released Heat Attributed to Formation of Primary Aluminum Crystals During Solidification of Al7Si4Cu Alloy

Mitrašinović, Aleksandar M.; Momčilović, Dejan B.; Odanović, Zoran

(Springer Science and Business Media LLC, 2021)

TY  - JOUR
AU  - Mitrašinović, Aleksandar M.
AU  - Momčilović, Dejan B.
AU  - Odanović, Zoran
PY  - 2021
AB  - Assessing heat released only related to the formation of primary crystals provides results with a significantly higher sensitivity than a traditional assessment of undercooling value. In this work, two similar Ti5B1 master alloys (commercial and refined) are used for grain refinement of Al7Si4Cu aluminum alloy to assess narrow differences in heat release during primary crystallization. The heat released related to primary crystallization is 2.50 ± 0.03, 3.16 ± 0.12, and 7.92 kJ kg−1 for samples treated with the refined master alloys, commercial master alloys, and sample solidified without grain refinement, respectively. The acquired results showed that the suggested method is more efficient in comparison with traditional metallographic or undercooling methods for the assessment of grain refining efficiency with the potential to extend the suggested approach on a wide range of metallic structures where solidification occurs by eutectic-type primary crystallization characteristics.
PB  - Springer Science and Business Media LLC
T2  - Transactions of the Indian Institute of Metals
T1  - Assessment of Grain Size and Grain Refinement Efficiency by Calculation of Released Heat Attributed to Formation of Primary Aluminum Crystals During Solidification of Al7Si4Cu Alloy
SP  - 1917
EP  - 1922
VL  - 74
IS  - 8
DO  - 10.1007/s12666-021-02279-6
ER  - 
@article{
author = "Mitrašinović, Aleksandar M. and Momčilović, Dejan B. and Odanović, Zoran",
year = "2021",
abstract = "Assessing heat released only related to the formation of primary crystals provides results with a significantly higher sensitivity than a traditional assessment of undercooling value. In this work, two similar Ti5B1 master alloys (commercial and refined) are used for grain refinement of Al7Si4Cu aluminum alloy to assess narrow differences in heat release during primary crystallization. The heat released related to primary crystallization is 2.50 ± 0.03, 3.16 ± 0.12, and 7.92 kJ kg−1 for samples treated with the refined master alloys, commercial master alloys, and sample solidified without grain refinement, respectively. The acquired results showed that the suggested method is more efficient in comparison with traditional metallographic or undercooling methods for the assessment of grain refining efficiency with the potential to extend the suggested approach on a wide range of metallic structures where solidification occurs by eutectic-type primary crystallization characteristics.",
publisher = "Springer Science and Business Media LLC",
journal = "Transactions of the Indian Institute of Metals",
title = "Assessment of Grain Size and Grain Refinement Efficiency by Calculation of Released Heat Attributed to Formation of Primary Aluminum Crystals During Solidification of Al7Si4Cu Alloy",
pages = "1917-1922",
volume = "74",
number = "8",
doi = "10.1007/s12666-021-02279-6"
}
Mitrašinović, A. M., Momčilović, D. B.,& Odanović, Z. (2021). Assessment of Grain Size and Grain Refinement Efficiency by Calculation of Released Heat Attributed to Formation of Primary Aluminum Crystals During Solidification of Al7Si4Cu Alloy.
Transactions of the Indian Institute of Metals
Springer Science and Business Media LLC., 74(8), 1917-1922.
https://doi.org/10.1007/s12666-021-02279-6
Mitrašinović AM, Momčilović DB, Odanović Z. Assessment of Grain Size and Grain Refinement Efficiency by Calculation of Released Heat Attributed to Formation of Primary Aluminum Crystals During Solidification of Al7Si4Cu Alloy. Transactions of the Indian Institute of Metals. 2021;74(8):1917-1922.
doi:10.1007/s12666-021-02279-6.
Mitrašinović Aleksandar M., Momčilović Dejan B., Odanović Zoran, "Assessment of Grain Size and Grain Refinement Efficiency by Calculation of Released Heat Attributed to Formation of Primary Aluminum Crystals During Solidification of Al7Si4Cu Alloy" Transactions of the Indian Institute of Metals, 74, no. 8 (2021):1917-1922,
https://doi.org/10.1007/s12666-021-02279-6 .

Electrochemical and structural study on cycling performance of γ-LiV2O5 cathode

Milović, Miloš; Vujković, Milica; Jugović, Dragana; Mitrić, Miodrag

(Elsevier BV, 2021)

TY  - JOUR
AU  - Milović, Miloš
AU  - Vujković, Milica
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
PY  - 2021
AB  - Electrochemical and structural properties of LiV2O5 cathode were investigated. Obtained by solid state reaction at high temperature the material crystallized as gamma polymorph phase, γ-LiV2O5. The gamma structure provides two crystallographic sites to accommodate lithium ions, Li1 and Li2 position. Lithium insertion at these two sites occurs at two respective voltages versus lithium metal: ~3.6 V (Li1) and ~2.4 V (Li2). Intercalation at Li1 position is reversible in both organic and aqueous electrolyte and provides stable cycling performance at the high voltage. On the contrary, sluggish insertion/removal of Li+ at Li2 sites causes unstable performance and significant storage capacity fade at lower voltages. Lithium diffusion 3d landscape was determined by bond valence calculations applied on the γ-LiV2O5 phase, as well as on the metastable phases of γ′-V2O5 and ζ-Li2V2O5 that exist at high and low voltages respectively. The model was proposed based on inactivity of Li2 position of the metastable ζ-Li2V2O5 phase which provides explanation for the observed storage capacity loss at low voltages.
PB  - Elsevier BV
T2  - Ceramics International
T1  - Electrochemical and structural study on cycling performance of γ-LiV2O5 cathode
SP  - 17077
EP  - 17083
VL  - 47
IS  - 12
DO  - 10.1016/j.ceramint.2021.03.016
UR  - https://hdl.handle.net/21.15107/rcub_dais_11655
ER  - 
@article{
author = "Milović, Miloš and Vujković, Milica and Jugović, Dragana and Mitrić, Miodrag",
year = "2021",
abstract = "Electrochemical and structural properties of LiV2O5 cathode were investigated. Obtained by solid state reaction at high temperature the material crystallized as gamma polymorph phase, γ-LiV2O5. The gamma structure provides two crystallographic sites to accommodate lithium ions, Li1 and Li2 position. Lithium insertion at these two sites occurs at two respective voltages versus lithium metal: ~3.6 V (Li1) and ~2.4 V (Li2). Intercalation at Li1 position is reversible in both organic and aqueous electrolyte and provides stable cycling performance at the high voltage. On the contrary, sluggish insertion/removal of Li+ at Li2 sites causes unstable performance and significant storage capacity fade at lower voltages. Lithium diffusion 3d landscape was determined by bond valence calculations applied on the γ-LiV2O5 phase, as well as on the metastable phases of γ′-V2O5 and ζ-Li2V2O5 that exist at high and low voltages respectively. The model was proposed based on inactivity of Li2 position of the metastable ζ-Li2V2O5 phase which provides explanation for the observed storage capacity loss at low voltages.",
publisher = "Elsevier BV",
journal = "Ceramics International",
title = "Electrochemical and structural study on cycling performance of γ-LiV2O5 cathode",
pages = "17077-17083",
volume = "47",
number = "12",
doi = "10.1016/j.ceramint.2021.03.016",
url = "https://hdl.handle.net/21.15107/rcub_dais_11655"
}
Milović, M., Vujković, M., Jugović, D.,& Mitrić, M. (2021). Electrochemical and structural study on cycling performance of γ-LiV2O5 cathode.
Ceramics International
Elsevier BV., 47(12), 17077-17083.
https://doi.org/10.1016/j.ceramint.2021.03.016
Milović M, Vujković M, Jugović D, Mitrić M. Electrochemical and structural study on cycling performance of γ-LiV2O5 cathode. Ceramics International. 2021;47(12):17077-17083.
doi:10.1016/j.ceramint.2021.03.016.
Milović Miloš, Vujković Milica, Jugović Dragana, Mitrić Miodrag, "Electrochemical and structural study on cycling performance of γ-LiV2O5 cathode" Ceramics International, 47, no. 12 (2021):17077-17083,
https://doi.org/10.1016/j.ceramint.2021.03.016 .

Integer codes correcting single asymmetric errors

Radonjic, Aleksandar

(Springer Science and Business Media LLC, 2021)

TY  - JOUR
AU  - Radonjic, Aleksandar
PY  - 2021
AB  - This paper presents a class of integer codes capable of correcting single asymmetric errors. The presented codes are defined over the ring of integers modulo 2b– 1 and are constructed with the help of a computer. The results of an exhaustive search have shown that, for practical lengths up to 4096 bits, the proposed codes use the same number of check bits as the best systematic single asymmetric error-correcting codes (SAECCs). Besides this, it is found that for some lengths the presented codes are perfect. Finally, the paper shows that the encoding/decoding complexity of the proposed codes is notably lower than that of the best systematic SAECCs.
PB  - Springer Science and Business Media LLC
T2  - Annals of Telecommunications
T1  - Integer codes correcting single asymmetric errors
SP  - 109
EP  - 113
VL  - 76
IS  - 1-2
DO  - 10.1007/s12243-020-00816-w
UR  - https://hdl.handle.net/21.15107/rcub_dais_11652
ER  - 
@article{
author = "Radonjic, Aleksandar",
year = "2021",
abstract = "This paper presents a class of integer codes capable of correcting single asymmetric errors. The presented codes are defined over the ring of integers modulo 2b– 1 and are constructed with the help of a computer. The results of an exhaustive search have shown that, for practical lengths up to 4096 bits, the proposed codes use the same number of check bits as the best systematic single asymmetric error-correcting codes (SAECCs). Besides this, it is found that for some lengths the presented codes are perfect. Finally, the paper shows that the encoding/decoding complexity of the proposed codes is notably lower than that of the best systematic SAECCs.",
publisher = "Springer Science and Business Media LLC",
journal = "Annals of Telecommunications",
title = "Integer codes correcting single asymmetric errors",
pages = "109-113",
volume = "76",
number = "1-2",
doi = "10.1007/s12243-020-00816-w",
url = "https://hdl.handle.net/21.15107/rcub_dais_11652"
}
Radonjic, A. (2021). Integer codes correcting single asymmetric errors.
Annals of Telecommunications
Springer Science and Business Media LLC., 76(1-2), 109-113.
https://doi.org/10.1007/s12243-020-00816-w
Radonjic A. Integer codes correcting single asymmetric errors. Annals of Telecommunications. 2021;76(1-2):109-113.
doi:10.1007/s12243-020-00816-w.
Radonjic Aleksandar, "Integer codes correcting single asymmetric errors" Annals of Telecommunications, 76, no. 1-2 (2021):109-113,
https://doi.org/10.1007/s12243-020-00816-w .

Electrochemical and structural study on cycling performance of γ-LiV2O5 cathode

Milović, Miloš; Vujković, Milica; Jugović, Dragana; Mitrić, Miodrag

(Elsevier BV, 2021)

TY  - JOUR
AU  - Milović, Miloš
AU  - Vujković, Milica
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
PY  - 2021
AB  - Electrochemical and structural properties of LiV2O5 cathode were investigated. Obtained by solid state reaction at high temperature the material crystallized as gamma polymorph phase, γ-LiV2O5. The gamma structure provides two crystallographic sites to accommodate lithium ions, Li1 and Li2 position. Lithium insertion at these two sites occurs at two respective voltages versus lithium metal: ~3.6 V (Li1) and ~2.4 V (Li2). Intercalation at Li1 position is reversible in both organic and aqueous electrolyte and provides stable cycling performance at the high voltage. On the contrary, sluggish insertion/removal of Li+ at Li2 sites causes unstable performance and significant storage capacity fade at lower voltages. Lithium diffusion 3d landscape was determined by bond valence calculations applied on the γ-LiV2O5 phase, as well as on the metastable phases of γ′-V2O5 and ζ-Li2V2O5 that exist at high and low voltages respectively. The model was proposed based on inactivity of Li2 position of the metastable ζ-Li2V2O5 phase which provides explanation for the observed storage capacity loss at low voltages.
PB  - Elsevier BV
T2  - Ceramics International
T1  - Electrochemical and structural study on cycling performance of γ-LiV2O5 cathode
SP  - 17077
EP  - 17083
VL  - 47
IS  - 12
DO  - 10.1016/j.ceramint.2021.03.016
UR  - https://hdl.handle.net/21.15107/rcub_dais_11645
ER  - 
@article{
author = "Milović, Miloš and Vujković, Milica and Jugović, Dragana and Mitrić, Miodrag",
year = "2021",
abstract = "Electrochemical and structural properties of LiV2O5 cathode were investigated. Obtained by solid state reaction at high temperature the material crystallized as gamma polymorph phase, γ-LiV2O5. The gamma structure provides two crystallographic sites to accommodate lithium ions, Li1 and Li2 position. Lithium insertion at these two sites occurs at two respective voltages versus lithium metal: ~3.6 V (Li1) and ~2.4 V (Li2). Intercalation at Li1 position is reversible in both organic and aqueous electrolyte and provides stable cycling performance at the high voltage. On the contrary, sluggish insertion/removal of Li+ at Li2 sites causes unstable performance and significant storage capacity fade at lower voltages. Lithium diffusion 3d landscape was determined by bond valence calculations applied on the γ-LiV2O5 phase, as well as on the metastable phases of γ′-V2O5 and ζ-Li2V2O5 that exist at high and low voltages respectively. The model was proposed based on inactivity of Li2 position of the metastable ζ-Li2V2O5 phase which provides explanation for the observed storage capacity loss at low voltages.",
publisher = "Elsevier BV",
journal = "Ceramics International",
title = "Electrochemical and structural study on cycling performance of γ-LiV2O5 cathode",
pages = "17077-17083",
volume = "47",
number = "12",
doi = "10.1016/j.ceramint.2021.03.016",
url = "https://hdl.handle.net/21.15107/rcub_dais_11645"
}
Milović, M., Vujković, M., Jugović, D.,& Mitrić, M. (2021). Electrochemical and structural study on cycling performance of γ-LiV2O5 cathode.
Ceramics International
Elsevier BV., 47(12), 17077-17083.
https://doi.org/10.1016/j.ceramint.2021.03.016
Milović M, Vujković M, Jugović D, Mitrić M. Electrochemical and structural study on cycling performance of γ-LiV2O5 cathode. Ceramics International. 2021;47(12):17077-17083.
doi:10.1016/j.ceramint.2021.03.016.
Milović Miloš, Vujković Milica, Jugović Dragana, Mitrić Miodrag, "Electrochemical and structural study on cycling performance of γ-LiV2O5 cathode" Ceramics International, 47, no. 12 (2021):17077-17083,
https://doi.org/10.1016/j.ceramint.2021.03.016 .

Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics

Degli Esposti, Lorenzo; Marković, Smilja; Ignjatović, Nenad; Panseri, Silvia; Montesi, Monica; Adamiano, Alessio; Fosca, Marco; Rau, Julietta V.; Uskoković, Vuk; Iafisco, Michele

(Royal Society of Chemistry, 2021)

TY  - JOUR
AU  - Degli Esposti, Lorenzo
AU  - Marković, Smilja
AU  - Ignjatović, Nenad
AU  - Panseri, Silvia
AU  - Montesi, Monica
AU  - Adamiano, Alessio
AU  - Fosca, Marco
AU  - Rau, Julietta V.
AU  - Uskoković, Vuk
AU  - Iafisco, Michele
PY  - 2021
AB  - Amorphous calcium phosphate (ACP) is a material of high interest for dentistry, orthopedics, and other biomedical sectors. Being intrinsically metastable, the process of transformation of ACP into a crystalline phase upon heating is of high relevance for the development of innovative bioceramics. Here we have first studied the thermal behavior of a citrate-stabilized ACP (Cit-ACP) also doped with fluoride ions (Cit-FACP) prepared at three different nominal Cit/Ca ratios (i.e. 4, 2, 1) by differential thermal analysis. Next, the physico-chemical features of the crystalline products as well as the in vitro cell response to the materials were investigated. A citrate and fluoride free ACP sample was also tested as the blank. We have found that the activation energy of crystallization of Cit-(F)ACP samples is lower in comparison to the blank ACP and this is influenced by the nominal Cit/Ca molar ratio. Interestingly, we have discovered that the thermal treatment of Cit-(F)ACP at 800 °C yields hydroxyapatite (HA) or fluorapatite (FHA) as the main products differently from blank ACP that, like most of the ACPs reported in the literature, yields β-tricalcium phosphate. This was attributed to the Ca/P ratio of Cit-(F)ACP, which is similar to HA. A study of the crystalline products has revealed that all the (F)HA samples were non-cytotoxic, and retained carbonate ions in the crystal structure despite the heat treatment that should have induced decarbonation. The morphology of the products is influenced by the nominal Cit/Ca ratio and the presence of fluoride, ranging from spherical nanoparticles to micrometric hexagonal rods. Overall, our results prove that the thermal crystallization of Cit-(F)ACP is markedly different from classic ACP based materials and the thermal treatment of Cit-(F)ACP represents an attractive route for producing pure bioactive HA ceramics.
PB  - Royal Society of Chemistry
T2  - Journal of Materials Chemistry B
T1  - Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics
SP  - 4832
EP  - 4845
VL  - 9
IS  - 24
DO  - 10.1039/D1TB00601K
UR  - https://hdl.handle.net/21.15107/rcub_dais_11640
ER  - 
@article{
author = "Degli Esposti, Lorenzo and Marković, Smilja and Ignjatović, Nenad and Panseri, Silvia and Montesi, Monica and Adamiano, Alessio and Fosca, Marco and Rau, Julietta V. and Uskoković, Vuk and Iafisco, Michele",
year = "2021",
abstract = "Amorphous calcium phosphate (ACP) is a material of high interest for dentistry, orthopedics, and other biomedical sectors. Being intrinsically metastable, the process of transformation of ACP into a crystalline phase upon heating is of high relevance for the development of innovative bioceramics. Here we have first studied the thermal behavior of a citrate-stabilized ACP (Cit-ACP) also doped with fluoride ions (Cit-FACP) prepared at three different nominal Cit/Ca ratios (i.e. 4, 2, 1) by differential thermal analysis. Next, the physico-chemical features of the crystalline products as well as the in vitro cell response to the materials were investigated. A citrate and fluoride free ACP sample was also tested as the blank. We have found that the activation energy of crystallization of Cit-(F)ACP samples is lower in comparison to the blank ACP and this is influenced by the nominal Cit/Ca molar ratio. Interestingly, we have discovered that the thermal treatment of Cit-(F)ACP at 800 °C yields hydroxyapatite (HA) or fluorapatite (FHA) as the main products differently from blank ACP that, like most of the ACPs reported in the literature, yields β-tricalcium phosphate. This was attributed to the Ca/P ratio of Cit-(F)ACP, which is similar to HA. A study of the crystalline products has revealed that all the (F)HA samples were non-cytotoxic, and retained carbonate ions in the crystal structure despite the heat treatment that should have induced decarbonation. The morphology of the products is influenced by the nominal Cit/Ca ratio and the presence of fluoride, ranging from spherical nanoparticles to micrometric hexagonal rods. Overall, our results prove that the thermal crystallization of Cit-(F)ACP is markedly different from classic ACP based materials and the thermal treatment of Cit-(F)ACP represents an attractive route for producing pure bioactive HA ceramics.",
publisher = "Royal Society of Chemistry",
journal = "Journal of Materials Chemistry B",
title = "Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics",
pages = "4832-4845",
volume = "9",
number = "24",
doi = "10.1039/D1TB00601K",
url = "https://hdl.handle.net/21.15107/rcub_dais_11640"
}
Degli Esposti, L., Marković, S., Ignjatović, N., Panseri, S., Montesi, M., Adamiano, A., Fosca, M., Rau, J. V., Uskoković, V.,& Iafisco, M. (2021). Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics.
Journal of Materials Chemistry B
Royal Society of Chemistry., 9(24), 4832-4845.
https://doi.org/10.1039/D1TB00601K
Degli Esposti L, Marković S, Ignjatović N, Panseri S, Montesi M, Adamiano A, Fosca M, Rau JV, Uskoković V, Iafisco M. Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics. Journal of Materials Chemistry B. 2021;9(24):4832-4845.
doi:10.1039/D1TB00601K.
Degli Esposti Lorenzo, Marković Smilja, Ignjatović Nenad, Panseri Silvia, Montesi Monica, Adamiano Alessio, Fosca Marco, Rau Julietta V., Uskoković Vuk, Iafisco Michele, "Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics" Journal of Materials Chemistry B, 9, no. 24 (2021):4832-4845,
https://doi.org/10.1039/D1TB00601K .
3
1

Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics

Degli Esposti, Lorenzo; Marković, Smilja; Ignjatović, Nenad; Panseri, Silvia; Montesi, Monica; Adamiano, Alessio; Fosca, Marco; Rau, Julietta V.; Uskoković, Vuk; Iafisco, Michele

(Royal Society of Chemistry, 2021)

TY  - JOUR
AU  - Degli Esposti, Lorenzo
AU  - Marković, Smilja
AU  - Ignjatović, Nenad
AU  - Panseri, Silvia
AU  - Montesi, Monica
AU  - Adamiano, Alessio
AU  - Fosca, Marco
AU  - Rau, Julietta V.
AU  - Uskoković, Vuk
AU  - Iafisco, Michele
PY  - 2021
AB  - Amorphous calcium phosphate (ACP) is a material of high interest for dentistry, orthopedics, and other biomedical sectors. Being intrinsically metastable, the process of transformation of ACP into a crystalline phase upon heating is of high relevance for the development of innovative bioceramics. Here we have first studied the thermal behavior of a citrate-stabilized ACP (Cit-ACP) also doped with fluoride ions (Cit-FACP) prepared at three different nominal Cit/Ca ratios (i.e. 4, 2, 1) by differential thermal analysis. Next, the physico-chemical features of the crystalline products as well as the in vitro cell response to the materials were investigated. A citrate and fluoride free ACP sample was also tested as the blank. We have found that the activation energy of crystallization of Cit-(F)ACP samples is lower in comparison to the blank ACP and this is influenced by the nominal Cit/Ca molar ratio. Interestingly, we have discovered that the thermal treatment of Cit-(F)ACP at 800 °C yields hydroxyapatite (HA) or fluorapatite (FHA) as the main products differently from blank ACP that, like most of the ACPs reported in the literature, yields β-tricalcium phosphate. This was attributed to the Ca/P ratio of Cit-(F)ACP, which is similar to HA. A study of the crystalline products has revealed that all the (F)HA samples were non-cytotoxic, and retained carbonate ions in the crystal structure despite the heat treatment that should have induced decarbonation. The morphology of the products is influenced by the nominal Cit/Ca ratio and the presence of fluoride, ranging from spherical nanoparticles to micrometric hexagonal rods. Overall, our results prove that the thermal crystallization of Cit-(F)ACP is markedly different from classic ACP based materials and the thermal treatment of Cit-(F)ACP represents an attractive route for producing pure bioactive HA ceramics.
PB  - Royal Society of Chemistry
T2  - Journal of Materials Chemistry B
T1  - Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics
SP  - 4832
EP  - 4845
VL  - 9
IS  - 24
DO  - 10.1039/D1TB00601K
UR  - https://hdl.handle.net/21.15107/rcub_dais_11639
ER  - 
@article{
author = "Degli Esposti, Lorenzo and Marković, Smilja and Ignjatović, Nenad and Panseri, Silvia and Montesi, Monica and Adamiano, Alessio and Fosca, Marco and Rau, Julietta V. and Uskoković, Vuk and Iafisco, Michele",
year = "2021",
abstract = "Amorphous calcium phosphate (ACP) is a material of high interest for dentistry, orthopedics, and other biomedical sectors. Being intrinsically metastable, the process of transformation of ACP into a crystalline phase upon heating is of high relevance for the development of innovative bioceramics. Here we have first studied the thermal behavior of a citrate-stabilized ACP (Cit-ACP) also doped with fluoride ions (Cit-FACP) prepared at three different nominal Cit/Ca ratios (i.e. 4, 2, 1) by differential thermal analysis. Next, the physico-chemical features of the crystalline products as well as the in vitro cell response to the materials were investigated. A citrate and fluoride free ACP sample was also tested as the blank. We have found that the activation energy of crystallization of Cit-(F)ACP samples is lower in comparison to the blank ACP and this is influenced by the nominal Cit/Ca molar ratio. Interestingly, we have discovered that the thermal treatment of Cit-(F)ACP at 800 °C yields hydroxyapatite (HA) or fluorapatite (FHA) as the main products differently from blank ACP that, like most of the ACPs reported in the literature, yields β-tricalcium phosphate. This was attributed to the Ca/P ratio of Cit-(F)ACP, which is similar to HA. A study of the crystalline products has revealed that all the (F)HA samples were non-cytotoxic, and retained carbonate ions in the crystal structure despite the heat treatment that should have induced decarbonation. The morphology of the products is influenced by the nominal Cit/Ca ratio and the presence of fluoride, ranging from spherical nanoparticles to micrometric hexagonal rods. Overall, our results prove that the thermal crystallization of Cit-(F)ACP is markedly different from classic ACP based materials and the thermal treatment of Cit-(F)ACP represents an attractive route for producing pure bioactive HA ceramics.",
publisher = "Royal Society of Chemistry",
journal = "Journal of Materials Chemistry B",
title = "Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics",
pages = "4832-4845",
volume = "9",
number = "24",
doi = "10.1039/D1TB00601K",
url = "https://hdl.handle.net/21.15107/rcub_dais_11639"
}
Degli Esposti, L., Marković, S., Ignjatović, N., Panseri, S., Montesi, M., Adamiano, A., Fosca, M., Rau, J. V., Uskoković, V.,& Iafisco, M. (2021). Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics.
Journal of Materials Chemistry B
Royal Society of Chemistry., 9(24), 4832-4845.
https://doi.org/10.1039/D1TB00601K
Degli Esposti L, Marković S, Ignjatović N, Panseri S, Montesi M, Adamiano A, Fosca M, Rau JV, Uskoković V, Iafisco M. Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics. Journal of Materials Chemistry B. 2021;9(24):4832-4845.
doi:10.1039/D1TB00601K.
Degli Esposti Lorenzo, Marković Smilja, Ignjatović Nenad, Panseri Silvia, Montesi Monica, Adamiano Alessio, Fosca Marco, Rau Julietta V., Uskoković Vuk, Iafisco Michele, "Thermal crystallization of amorphous calcium phosphate combined with citrate and fluoride doping: a novel route to produce hydroxyapatite bioceramics" Journal of Materials Chemistry B, 9, no. 24 (2021):4832-4845,
https://doi.org/10.1039/D1TB00601K .
3
1

Towards a green and cost-effective synthesis of polyanionic cathodes: comparative electrochemical behaviour of LiFePO4/C, Li2FeP2O7/C and Li2FeSiO4/C synthesized using methylcellulose matrix

Milović, Miloš; Jugović, Dragana; Vujković, Milica; Kuzmanović, Maja; Mraković, Ana; Mitrić, Miodrag

(Springer Science and Business Media LLC, 2021)

TY  - JOUR
AU  - Milović, Miloš
AU  - Jugović, Dragana
AU  - Vujković, Milica
AU  - Kuzmanović, Maja
AU  - Mraković, Ana
AU  - Mitrić, Miodrag
PY  - 2021
AB  - The polyanion cathodes for Li-ion batteries, namely LiFePO4, Li2FeP2O7 and Li2FeSiO4, were synthesized by very short high-temperature treatment (approximately several minutes) and subsequent quenching. Methylcellulose—a polymer with thermally driven water solubility—was used as the medium in which the precursor solutions were dispersed prior to high temperature treatment. The methylcellulose pyrolytically decomposes to carbon, thus producing the polyanion material/carbon composites of LiFePO4/C, Li2FeP2O7/C and Li2FeSiO4/C. The obtained powders have reduced crystallinity and significant microstructural characteristics: low crystallite size and notable microstrain. They exhibit stable electrochemical performances in both aqueous and organic electrolyte. The broadening of existing peaks in cyclic voltammetry and/or the emergence of new broad peaks was attributed to the presence of the amorphous phase in the samples. In galvanostatic charge–discharge tests, the materials provided high capacities at low current densities, while the highest rate performance was demonstrated by olivine-phosphate when compared to the other two materials.
PB  - Springer Science and Business Media LLC
T2  - Bulletin of Materials Science
T1  - Towards a green and cost-effective synthesis of polyanionic cathodes: comparative electrochemical behaviour of LiFePO4/C, Li2FeP2O7/C and Li2FeSiO4/C synthesized using methylcellulose matrix
SP  - 144
VL  - 44
IS  - 2
DO  - 10.1007/s12034-021-02397-3
UR  - https://hdl.handle.net/21.15107/rcub_dais_11635
ER  - 
@article{
author = "Milović, Miloš and Jugović, Dragana and Vujković, Milica and Kuzmanović, Maja and Mraković, Ana and Mitrić, Miodrag",
year = "2021",
abstract = "The polyanion cathodes for Li-ion batteries, namely LiFePO4, Li2FeP2O7 and Li2FeSiO4, were synthesized by very short high-temperature treatment (approximately several minutes) and subsequent quenching. Methylcellulose—a polymer with thermally driven water solubility—was used as the medium in which the precursor solutions were dispersed prior to high temperature treatment. The methylcellulose pyrolytically decomposes to carbon, thus producing the polyanion material/carbon composites of LiFePO4/C, Li2FeP2O7/C and Li2FeSiO4/C. The obtained powders have reduced crystallinity and significant microstructural characteristics: low crystallite size and notable microstrain. They exhibit stable electrochemical performances in both aqueous and organic electrolyte. The broadening of existing peaks in cyclic voltammetry and/or the emergence of new broad peaks was attributed to the presence of the amorphous phase in the samples. In galvanostatic charge–discharge tests, the materials provided high capacities at low current densities, while the highest rate performance was demonstrated by olivine-phosphate when compared to the other two materials.",
publisher = "Springer Science and Business Media LLC",
journal = "Bulletin of Materials Science",
title = "Towards a green and cost-effective synthesis of polyanionic cathodes: comparative electrochemical behaviour of LiFePO4/C, Li2FeP2O7/C and Li2FeSiO4/C synthesized using methylcellulose matrix",
pages = "144",
volume = "44",
number = "2",
doi = "10.1007/s12034-021-02397-3",
url = "https://hdl.handle.net/21.15107/rcub_dais_11635"
}
Milović, M., Jugović, D., Vujković, M., Kuzmanović, M., Mraković, A.,& Mitrić, M. (2021). Towards a green and cost-effective synthesis of polyanionic cathodes: comparative electrochemical behaviour of LiFePO4/C, Li2FeP2O7/C and Li2FeSiO4/C synthesized using methylcellulose matrix.
Bulletin of Materials Science
Springer Science and Business Media LLC., 44(2), 144.
https://doi.org/10.1007/s12034-021-02397-3
Milović M, Jugović D, Vujković M, Kuzmanović M, Mraković A, Mitrić M. Towards a green and cost-effective synthesis of polyanionic cathodes: comparative electrochemical behaviour of LiFePO4/C, Li2FeP2O7/C and Li2FeSiO4/C synthesized using methylcellulose matrix. Bulletin of Materials Science. 2021;44(2):144.
doi:10.1007/s12034-021-02397-3.
Milović Miloš, Jugović Dragana, Vujković Milica, Kuzmanović Maja, Mraković Ana, Mitrić Miodrag, "Towards a green and cost-effective synthesis of polyanionic cathodes: comparative electrochemical behaviour of LiFePO4/C, Li2FeP2O7/C and Li2FeSiO4/C synthesized using methylcellulose matrix" Bulletin of Materials Science, 44, no. 2 (2021):144,
https://doi.org/10.1007/s12034-021-02397-3 .

Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook

Gezović, Aleksandra; Vujković, Milica; Milović, Miloš; Grudić, Veselinka; Dominko, Robert; Mentus, Slavko

(Elsevier BV, 2021)

TY  - JOUR
AU  - Gezović, Aleksandra
AU  - Vujković, Milica
AU  - Milović, Miloš
AU  - Grudić, Veselinka
AU  - Dominko, Robert
AU  - Mentus, Slavko
PY  - 2021
AB  - Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.
PB  - Elsevier BV
T2  - Energy Storage Materials
T1  - Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook
SP  - 243
EP  - 273
VL  - 37
DO  - 10.1016/j.ensm.2021.02.011
UR  - https://hdl.handle.net/21.15107/rcub_dais_11633
ER  - 
@article{
author = "Gezović, Aleksandra and Vujković, Milica and Milović, Miloš and Grudić, Veselinka and Dominko, Robert and Mentus, Slavko",
year = "2021",
abstract = "Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.",
publisher = "Elsevier BV",
journal = "Energy Storage Materials",
title = "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook",
pages = "243-273",
volume = "37",
doi = "10.1016/j.ensm.2021.02.011",
url = "https://hdl.handle.net/21.15107/rcub_dais_11633"
}
Gezović, A., Vujković, M., Milović, M., Grudić, V., Dominko, R.,& Mentus, S. (2021). Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook.
Energy Storage Materials
Elsevier BV., 37, 243-273.
https://doi.org/10.1016/j.ensm.2021.02.011
Gezović A, Vujković M, Milović M, Grudić V, Dominko R, Mentus S. Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook. Energy Storage Materials. 2021;37:243-273.
doi:10.1016/j.ensm.2021.02.011.
Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273,
https://doi.org/10.1016/j.ensm.2021.02.011 .
1

Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook

Gezović, Aleksandra; Vujković, Milica; Milović, Miloš; Grudić, Veselinka; Dominko, Robert; Mentus, Slavko

(Elsevier BV, 2021)

TY  - JOUR
AU  - Gezović, Aleksandra
AU  - Vujković, Milica
AU  - Milović, Miloš
AU  - Grudić, Veselinka
AU  - Dominko, Robert
AU  - Mentus, Slavko
PY  - 2021
AB  - Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.
PB  - Elsevier BV
T2  - Energy Storage Materials
T1  - Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook
SP  - 243
EP  - 273
VL  - 37
DO  - 10.1016/j.ensm.2021.02.011
UR  - https://hdl.handle.net/21.15107/rcub_dais_11632
ER  - 
@article{
author = "Gezović, Aleksandra and Vujković, Milica and Milović, Miloš and Grudić, Veselinka and Dominko, Robert and Mentus, Slavko",
year = "2021",
abstract = "Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.",
publisher = "Elsevier BV",
journal = "Energy Storage Materials",
title = "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook",
pages = "243-273",
volume = "37",
doi = "10.1016/j.ensm.2021.02.011",
url = "https://hdl.handle.net/21.15107/rcub_dais_11632"
}
Gezović, A., Vujković, M., Milović, M., Grudić, V., Dominko, R.,& Mentus, S. (2021). Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook.
Energy Storage Materials
Elsevier BV., 37, 243-273.
https://doi.org/10.1016/j.ensm.2021.02.011
Gezović A, Vujković M, Milović M, Grudić V, Dominko R, Mentus S. Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook. Energy Storage Materials. 2021;37:243-273.
doi:10.1016/j.ensm.2021.02.011.
Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273,
https://doi.org/10.1016/j.ensm.2021.02.011 .
1

Changes in long-term properties and natural cycles of the Danube river level and flow induced by damming

Stratimirović, Đorđe; Batas-Bjelić, Ilija; Đurđevic, Vladimir; Blešić, Suzana

(Elsevier BV, 2021)

TY  - JOUR
AU  - Stratimirović, Đorđe
AU  - Batas-Bjelić, Ilija
AU  - Đurđevic, Vladimir
AU  - Blešić, Suzana
PY  - 2021
AB  - In this paper we assessed changes in scaling properties of the river Danube level and flow data, associated with building of Djerdap/Iron Gates hydrological power plants positioned on the border of Romania and Serbia. We used detrended fluctuation analysis (DFA), wavelet transform spectral analysis (WTS) and wavelet modulus maxima method (WTMM) to investigate time series of measurements from hydrological stations in the vicinity of dams and in the area of up to 480 km upstream from dams, and time series of simulated NOAA-CIRES 20th Century Global Reanalysis precipitation data for the Djerdap/Iron Gates region. By comparing river dynamics during the periods before and after construction of dams, we were able to register changes in scaling that are different for recordings from upstream and from downstream (from dams) areas. We found that damming caused appearance of human-made or enhancement of natural cycles in the small time scales region, which largely influenced the change in temporal scaling in downstream recording stations. We additionally found disappearance or decline in the amplitude of large-time-scale cycles as a result of damming, which changed the dynamics of upstream data. The most prominent finding of our paper is a demonstration of a complete or partial loss of annual cycles in the upstream stations’ data that stems from the operation of the artificial water reservoir and extends as far as 220 km from dams. We discussed probable sources of such found changes in scaling, aiming to provide explanations that could be of use in future environmental assessments.
PB  - Elsevier BV
T2  - Physica A: Statistical Mechanics and its Applications
T1  - Changes in long-term properties and natural cycles of the Danube river level and flow induced by damming
SP  - 125607
VL  - 566
DO  - 10.1016/j.physa.2020.125607
UR  - https://hdl.handle.net/21.15107/rcub_dais_10096
ER  - 
@article{
author = "Stratimirović, Đorđe and Batas-Bjelić, Ilija and Đurđevic, Vladimir and Blešić, Suzana",
year = "2021",
abstract = "In this paper we assessed changes in scaling properties of the river Danube level and flow data, associated with building of Djerdap/Iron Gates hydrological power plants positioned on the border of Romania and Serbia. We used detrended fluctuation analysis (DFA), wavelet transform spectral analysis (WTS) and wavelet modulus maxima method (WTMM) to investigate time series of measurements from hydrological stations in the vicinity of dams and in the area of up to 480 km upstream from dams, and time series of simulated NOAA-CIRES 20th Century Global Reanalysis precipitation data for the Djerdap/Iron Gates region. By comparing river dynamics during the periods before and after construction of dams, we were able to register changes in scaling that are different for recordings from upstream and from downstream (from dams) areas. We found that damming caused appearance of human-made or enhancement of natural cycles in the small time scales region, which largely influenced the change in temporal scaling in downstream recording stations. We additionally found disappearance or decline in the amplitude of large-time-scale cycles as a result of damming, which changed the dynamics of upstream data. The most prominent finding of our paper is a demonstration of a complete or partial loss of annual cycles in the upstream stations’ data that stems from the operation of the artificial water reservoir and extends as far as 220 km from dams. We discussed probable sources of such found changes in scaling, aiming to provide explanations that could be of use in future environmental assessments.",
publisher = "Elsevier BV",
journal = "Physica A: Statistical Mechanics and its Applications",
title = "Changes in long-term properties and natural cycles of the Danube river level and flow induced by damming",
pages = "125607",
volume = "566",
doi = "10.1016/j.physa.2020.125607",
url = "https://hdl.handle.net/21.15107/rcub_dais_10096"
}
Stratimirović, Đ., Batas-Bjelić, I., Đurđevic, V.,& Blešić, S. (2021). Changes in long-term properties and natural cycles of the Danube river level and flow induced by damming.
Physica A: Statistical Mechanics and its Applications
Elsevier BV., 566, 125607.
https://doi.org/10.1016/j.physa.2020.125607
Stratimirović Đ, Batas-Bjelić I, Đurđevic V, Blešić S. Changes in long-term properties and natural cycles of the Danube river level and flow induced by damming. Physica A: Statistical Mechanics and its Applications. 2021;566:125607.
doi:10.1016/j.physa.2020.125607.
Stratimirović Đorđe, Batas-Bjelić Ilija, Đurđevic Vladimir, Blešić Suzana, "Changes in long-term properties and natural cycles of the Danube river level and flow induced by damming" Physica A: Statistical Mechanics and its Applications, 566 (2021):125607,
https://doi.org/10.1016/j.physa.2020.125607 .
1

Thermodynamic and kinetics investigation of elemental evaporation from molten Al7Si4Cu alloy

Mitrašinović, Aleksandar M.; Odanović, Zoran

(Elsevier BV, 2021)

TY  - JOUR
AU  - Mitrašinović, Aleksandar M.
AU  - Odanović, Zoran
PY  - 2021
AB  - Treatment of liquid aluminum alloys in low vacuum conditions is often applied for parts production in the automotive and aerospace industry because of its effectiveness in removing dissolved gases. Because of the low vapour pressure of aluminum, concentrations of the most unwanted elements can be significantly reduced at lower pressures. Presented work analyzing kinetics parameters for elemental evaporation from liquid Al7Si4Cu alloy. The pressure inside mullite refractory material was below 2.1 kPa for melt temperatures between 760 and 910 °C. The alloy’s chemical composition was characterized by the Inductively Coupled Plasma Mass Spectrometry method. Lead, Zinc, and Mercury were reduced at the highest rate while the lowest evaporation occurred for key alloying elements such as Silicon and Copper. Higher evaporation rates were achieved at higher temperatures. The evaporation ratios, volatility coefficients, reaction rate constants, mass transfer coefficients, and elemental evaporation susceptibility on temperature increase were deduced for 16 elements. The obtained results confirmed that keeping molten aluminum alloys in low vacuum conditions for one hour is an efficient method in removing unwanted elements with great potential for further improvement in industrial conditions.
PB  - Elsevier BV
T2  - Thermochimica Acta
T1  - Thermodynamic and kinetics investigation of elemental evaporation from molten Al7Si4Cu alloy
SP  - 178816
VL  - 695
DO  - 10.1016/j.tca.2020.178816
UR  - https://hdl.handle.net/21.15107/rcub_dais_10001
ER  - 
@article{
author = "Mitrašinović, Aleksandar M. and Odanović, Zoran",
year = "2021",
abstract = "Treatment of liquid aluminum alloys in low vacuum conditions is often applied for parts production in the automotive and aerospace industry because of its effectiveness in removing dissolved gases. Because of the low vapour pressure of aluminum, concentrations of the most unwanted elements can be significantly reduced at lower pressures. Presented work analyzing kinetics parameters for elemental evaporation from liquid Al7Si4Cu alloy. The pressure inside mullite refractory material was below 2.1 kPa for melt temperatures between 760 and 910 °C. The alloy’s chemical composition was characterized by the Inductively Coupled Plasma Mass Spectrometry method. Lead, Zinc, and Mercury were reduced at the highest rate while the lowest evaporation occurred for key alloying elements such as Silicon and Copper. Higher evaporation rates were achieved at higher temperatures. The evaporation ratios, volatility coefficients, reaction rate constants, mass transfer coefficients, and elemental evaporation susceptibility on temperature increase were deduced for 16 elements. The obtained results confirmed that keeping molten aluminum alloys in low vacuum conditions for one hour is an efficient method in removing unwanted elements with great potential for further improvement in industrial conditions.",
publisher = "Elsevier BV",
journal = "Thermochimica Acta",
title = "Thermodynamic and kinetics investigation of elemental evaporation from molten Al7Si4Cu alloy",
pages = "178816",
volume = "695",
doi = "10.1016/j.tca.2020.178816",
url = "https://hdl.handle.net/21.15107/rcub_dais_10001"
}
Mitrašinović, A. M.,& Odanović, Z. (2021). Thermodynamic and kinetics investigation of elemental evaporation from molten Al7Si4Cu alloy.
Thermochimica Acta
Elsevier BV., 695, 178816.
https://doi.org/10.1016/j.tca.2020.178816
Mitrašinović AM, Odanović Z. Thermodynamic and kinetics investigation of elemental evaporation from molten Al7Si4Cu alloy. Thermochimica Acta. 2021;695:178816.
doi:10.1016/j.tca.2020.178816.
Mitrašinović Aleksandar M., Odanović Zoran, "Thermodynamic and kinetics investigation of elemental evaporation from molten Al7Si4Cu alloy" Thermochimica Acta, 695 (2021):178816,
https://doi.org/10.1016/j.tca.2020.178816 .
1
1

Argon/dust and pure argon pulsed plasmas explored using a spatially-averaged model

Denysenko, I. B.; Stefanović, Ilija; Mikikian, M.; Kovačević, E.; Berndt, J.

(IOP Publishing, 2021)

TY  - JOUR
AU  - Denysenko, I. B.
AU  - Stefanović, Ilija
AU  - Mikikian, M.
AU  - Kovačević, E.
AU  - Berndt, J.
PY  - 2021
AB  - The properties (densities of electrons and metastable argon atoms, effective electron temperature and dust charge) of argon/dust and pure argon pulsed plasmas are studied using a spatially-averaged model. The calculated time-dependencies for the densities of electrons and metastable atoms are compared with the experimental measurements and are found to be in a good qualitative agreement. It is analyzed how the plasma properties depend on the shape of the electron energy probability function (EEPF), the pulsing frequency and the duty cycle for both dust-free and dusty plasma. The analysis reveals that the agreement between theory and experiment is better with Druyvesteyn EEPF than the Maxwellian EEPF. Further, the variation in the pulsing frequency νp differently affects the metastable density nm in a dust-free and in a dusty plasma. For large νp, the metastable density in the dust-free pulsed plasma is larger than in the continuous-wave (CW) discharge, while the opposite is obtained in the presence of dust particles. This difference probably arises because of faster variation in the effective electron temperature in the dusty plasma due to collection of electrons by dust particles. Our calculations also show that dust particles may affect the behavior of electron density in the beginning of the on-period due to an enhancement in electron collection by dust particles.
PB  - IOP Publishing
T2  - Journal of Physics D: Applied Physics
T1  - Argon/dust and pure argon pulsed plasmas explored using a spatially-averaged model
SP  - 065202
VL  - 54
IS  - 6
DO  - 10.1088/1361-6463/abc210
UR  - https://hdl.handle.net/21.15107/rcub_dais_9988
ER  - 
@article{
author = "Denysenko, I. B. and Stefanović, Ilija and Mikikian, M. and Kovačević, E. and Berndt, J.",
year = "2021",
abstract = "The properties (densities of electrons and metastable argon atoms, effective electron temperature and dust charge) of argon/dust and pure argon pulsed plasmas are studied using a spatially-averaged model. The calculated time-dependencies for the densities of electrons and metastable atoms are compared with the experimental measurements and are found to be in a good qualitative agreement. It is analyzed how the plasma properties depend on the shape of the electron energy probability function (EEPF), the pulsing frequency and the duty cycle for both dust-free and dusty plasma. The analysis reveals that the agreement between theory and experiment is better with Druyvesteyn EEPF than the Maxwellian EEPF. Further, the variation in the pulsing frequency νp differently affects the metastable density nm in a dust-free and in a dusty plasma. For large νp, the metastable density in the dust-free pulsed plasma is larger than in the continuous-wave (CW) discharge, while the opposite is obtained in the presence of dust particles. This difference probably arises because of faster variation in the effective electron temperature in the dusty plasma due to collection of electrons by dust particles. Our calculations also show that dust particles may affect the behavior of electron density in the beginning of the on-period due to an enhancement in electron collection by dust particles.",
publisher = "IOP Publishing",
journal = "Journal of Physics D: Applied Physics",
title = "Argon/dust and pure argon pulsed plasmas explored using a spatially-averaged model",
pages = "065202",
volume = "54",
number = "6",
doi = "10.1088/1361-6463/abc210",
url = "https://hdl.handle.net/21.15107/rcub_dais_9988"
}
Denysenko, I. B., Stefanović, I., Mikikian, M., Kovačević, E.,& Berndt, J. (2021). Argon/dust and pure argon pulsed plasmas explored using a spatially-averaged model.
Journal of Physics D: Applied Physics
IOP Publishing., 54(6), 065202.
https://doi.org/10.1088/1361-6463/abc210
Denysenko IB, Stefanović I, Mikikian M, Kovačević E, Berndt J. Argon/dust and pure argon pulsed plasmas explored using a spatially-averaged model. Journal of Physics D: Applied Physics. 2021;54(6):065202.
doi:10.1088/1361-6463/abc210.
Denysenko I. B., Stefanović Ilija, Mikikian M., Kovačević E., Berndt J., "Argon/dust and pure argon pulsed plasmas explored using a spatially-averaged model" Journal of Physics D: Applied Physics, 54, no. 6 (2021):065202,
https://doi.org/10.1088/1361-6463/abc210 .

The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods

Šuljagić, Marija; Vulić, Predrag; Jeremić, Dejan; Pavlović, Vladimir B.; Filipović, Suzana; Kilanski, Lukasz; Lewinska, Sabina; Slawska-Waniewska, Anna; Milenković, Milica; Nikolić, Aleksandar S.; Anđelković, Ljubica

(Elsevier, 2021)

TY  - JOUR
AU  - Šuljagić, Marija
AU  - Vulić, Predrag
AU  - Jeremić, Dejan
AU  - Pavlović, Vladimir B.
AU  - Filipović, Suzana
AU  - Kilanski, Lukasz
AU  - Lewinska, Sabina
AU  - Slawska-Waniewska, Anna
AU  - Milenković, Milica
AU  - Nikolić, Aleksandar S.
AU  - Anđelković, Ljubica
PY  - 2021
AB  - To investigate the magnetic behavior of starch-coated cobalt ferrites, well-established synthetic methods, i.e., coprecipitation, mechanochemical, ultrasonically assisted coprecipitation, microemulsion, and microwave-assisted hydrothermal syntheses were chosen for their preparation. The obtained materials had pure single-phase spinel structures. Scanning and transmission electron microscopy analyses revealed that the morphology of the samples is not uniform, and particle aggregation is a dominant process. Fourier transform infrared spectra and thermogravimetric analysis confirmed the presence of starch in all–coated samples. The unusually higher saturation magnetization of starch-coated samples than their as-prepared analogs, obtained by coprecipitation, ultrasonically assisted coprecipitation, and microwave-assisted hydrothermal methods, might be explained by the Ostwald ripening mechanism induced by the coating process. A decrease in magnetization was noticed for the starch-functionalized nanomaterials synthesized by mechanochemical and microemulsion methods, in comparison to their as-prepared analogs, i.e., the size distribution of such nanoparticles is narrow, and the average diameter of the grains is near critical for the Ostwald ripening process.
PB  - Elsevier
T2  - Materials Research Bulletin
T1  - The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods
SP  - 111117
VL  - 134
DO  - 10.1016/j.materresbull.2020.111117
UR  - https://hdl.handle.net/21.15107/rcub_dais_9514
ER  - 
@article{
author = "Šuljagić, Marija and Vulić, Predrag and Jeremić, Dejan and Pavlović, Vladimir B. and Filipović, Suzana and Kilanski, Lukasz and Lewinska, Sabina and Slawska-Waniewska, Anna and Milenković, Milica and Nikolić, Aleksandar S. and Anđelković, Ljubica",
year = "2021",
abstract = "To investigate the magnetic behavior of starch-coated cobalt ferrites, well-established synthetic methods, i.e., coprecipitation, mechanochemical, ultrasonically assisted coprecipitation, microemulsion, and microwave-assisted hydrothermal syntheses were chosen for their preparation. The obtained materials had pure single-phase spinel structures. Scanning and transmission electron microscopy analyses revealed that the morphology of the samples is not uniform, and particle aggregation is a dominant process. Fourier transform infrared spectra and thermogravimetric analysis confirmed the presence of starch in all–coated samples. The unusually higher saturation magnetization of starch-coated samples than their as-prepared analogs, obtained by coprecipitation, ultrasonically assisted coprecipitation, and microwave-assisted hydrothermal methods, might be explained by the Ostwald ripening mechanism induced by the coating process. A decrease in magnetization was noticed for the starch-functionalized nanomaterials synthesized by mechanochemical and microemulsion methods, in comparison to their as-prepared analogs, i.e., the size distribution of such nanoparticles is narrow, and the average diameter of the grains is near critical for the Ostwald ripening process.",
publisher = "Elsevier",
journal = "Materials Research Bulletin",
title = "The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods",
pages = "111117",
volume = "134",
doi = "10.1016/j.materresbull.2020.111117",
url = "https://hdl.handle.net/21.15107/rcub_dais_9514"
}
Šuljagić, M., Vulić, P., Jeremić, D., Pavlović, V. B., Filipović, S., Kilanski, L., Lewinska, S., Slawska-Waniewska, A., Milenković, M., Nikolić, A. S.,& Anđelković, L. (2021). The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods.
Materials Research Bulletin
Elsevier., 134, 111117.
https://doi.org/10.1016/j.materresbull.2020.111117
Šuljagić M, Vulić P, Jeremić D, Pavlović VB, Filipović S, Kilanski L, Lewinska S, Slawska-Waniewska A, Milenković M, Nikolić AS, Anđelković L. The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods. Materials Research Bulletin. 2021;134:111117.
doi:10.1016/j.materresbull.2020.111117.
Šuljagić Marija, Vulić Predrag, Jeremić Dejan, Pavlović Vladimir B., Filipović Suzana, Kilanski Lukasz, Lewinska Sabina, Slawska-Waniewska Anna, Milenković Milica, Nikolić Aleksandar S., Anđelković Ljubica, "The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods" Materials Research Bulletin, 134 (2021):111117,
https://doi.org/10.1016/j.materresbull.2020.111117 .
2
1
2