TY  - JOUR
AU  - Nenadović, Snežana S.
AU  - Kljajević, Ljiljana M.
AU  - Nešić, Maja A.
AU  - Petković, Marijana
AU  - Trivunac, Katarina V.
AU  - Pavlović, Vladimir B.
PY  - 2017
UR  - https://dais.sanu.ac.rs/123456789/2348
AB  - The paper presents chemical and structural analysis of geopolymer materials which are obtained by alkali-activated calcined clay (metakaolin) originated from Serbia under strictly defined conditions. Characterization of the metakaolin and geopolymers molecular structure has been done using X-ray diffraction, scanning electron microscope, Fourier transform infrared spectroscopy and matrix-assisted laser desorption ionization time-of-flight mass spectrometry. The paper presents the possibility of obtaining geopolymer structure and differences in chemical and structural characterization of these materials taking into account the concentration of NaOH as a variable parameter. The results of MALDI analysis of metakaolin and synthesized geopolymer structures using various matrix system: 2,4,6 trihydroxyacetophenone (THAP), α-cyano-4-hydroxycinnamic, 2,6 dihydroxyacetophenone and laser desorption/ionization, have shown that THAP matrix is the most appropriate for analysing these aluminosilicate materials.
PB  - Springer
T2  - Environmental Earth Sciences
T1  - Structure analysis of geopolymers synthesized from clay originated from Serbia
SP  - 76
VL  - 79
DO  - 10.1007/s12665-016-6360-4
UR  - https://hdl.handle.net/21.15107/rcub_dais_2348
ER  - 

@article{
author = "Nenadović, Snežana S. and Kljajević, Ljiljana M. and Nešić, Maja A. and Petković, Marijana and Trivunac, Katarina V. and Pavlović, Vladimir B.",
year = "2017",
abstract = "The paper presents chemical and structural analysis of geopolymer materials which are obtained by alkali-activated calcined clay (metakaolin) originated from Serbia under strictly defined conditions. Characterization of the metakaolin and geopolymers molecular structure has been done using X-ray diffraction, scanning electron microscope, Fourier transform infrared spectroscopy and matrix-assisted laser desorption ionization time-of-flight mass spectrometry. The paper presents the possibility of obtaining geopolymer structure and differences in chemical and structural characterization of these materials taking into account the concentration of NaOH as a variable parameter. The results of MALDI analysis of metakaolin and synthesized geopolymer structures using various matrix system: 2,4,6 trihydroxyacetophenone (THAP), α-cyano-4-hydroxycinnamic, 2,6 dihydroxyacetophenone and laser desorption/ionization, have shown that THAP matrix is the most appropriate for analysing these aluminosilicate materials.",
publisher = "Springer",
journal = "Environmental Earth Sciences",
title = "Structure analysis of geopolymers synthesized from clay originated from Serbia",
pages = "76",
volume = "79",
doi = "10.1007/s12665-016-6360-4",
url = "https://hdl.handle.net/21.15107/rcub_dais_2348"
}

Nenadović, S. S., Kljajević, L. M., Nešić, M. A., Petković, M., Trivunac, K. V.,& Pavlović, V. B.. (2017). Structure analysis of geopolymers synthesized from clay originated from Serbia. in Environmental Earth Sciences
Springer., 79, 76.
https://doi.org/10.1007/s12665-016-6360-4
https://hdl.handle.net/21.15107/rcub_dais_2348

Nenadović SS, Kljajević LM, Nešić MA, Petković M, Trivunac KV, Pavlović VB. Structure analysis of geopolymers synthesized from clay originated from Serbia. in Environmental Earth Sciences. 2017;79:76.
doi:10.1007/s12665-016-6360-4
https://hdl.handle.net/21.15107/rcub_dais_2348 .

Nenadović, Snežana S., Kljajević, Ljiljana M., Nešić, Maja A., Petković, Marijana, Trivunac, Katarina V., Pavlović, Vladimir B., "Structure analysis of geopolymers synthesized from clay originated from Serbia" in Environmental Earth Sciences, 79 (2017):76,
https://doi.org/10.1007/s12665-016-6360-4 .,
https://hdl.handle.net/21.15107/rcub_dais_2348 .

TY  - JOUR
AU  - Kljajević, Ljiljana M.
AU  - Nenadović, Snežana S.
AU  - Nenadović, Miloš T.
AU  - Bundaleski, Nenad K.
AU  - Todorović, Bratislav Ž.
AU  - Pavlović, Vladimir B.
AU  - Rakočević, Zlatko
PY  - 2017
UR  - https://dais.sanu.ac.rs/123456789/2374
AB  - This article presents the results of the compositional, structural and morphological study of geopolymers synthesized from metakaolin and an alkali activator. The study involved the investigation of the structural and chemical properties of the geopolymer, in addition to thermally treated geopolymers up to 600 and 900 °C. The precursor of the geopolymer, and the geopolymer samples before and after the thermal treatment, were investigated by Fourier transformation infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and SEM analysis. The corrected average value of the ratio of silicon and aluminum in the geopolymer samples (SiGP:Al) is about 1.46, which suggests that the obtained geopolymer samples represent a mixture of roughly equal amounts of sialate and sialate-siloxo units. Annealing the geopolymer samples at 600 °C decreases the amount of Si-ONa bonds and induces the cross-linking of polymer changes. At the same time, other sodium containing alumino-silicate phases are created. The thermal treatment at 900 °C leads to a considerable reduction of oxygen and particularly sodium, followed by significant morphological changes i.e. formation of a complex porous structure. Additionally, a new semicrystaline phase appears. Both XRD and XPS results imply that this new phase may be nepheline and it is plausible that this phase begins to nucleate at temperatures below 900 °C.
PB  - Elsevier
T2  - Ceramics International
T1  - Structural and chemical properties of thermally treated geopolymer samples
SP  - 6700
SP  - 6700
EP  - 6708
EP  - 6708
VL  - 43
VL  - 43
IS  - 9
IS  - 9
DO  - 10.1016/j.ceramint.2017.02.066
UR  - https://hdl.handle.net/21.15107/rcub_dais_2374
ER  - 

@article{
author = "Kljajević, Ljiljana M. and Nenadović, Snežana S. and Nenadović, Miloš T. and Bundaleski, Nenad K. and Todorović, Bratislav Ž. and Pavlović, Vladimir B. and Rakočević, Zlatko",
year = "2017",
abstract = "This article presents the results of the compositional, structural and morphological study of geopolymers synthesized from metakaolin and an alkali activator. The study involved the investigation of the structural and chemical properties of the geopolymer, in addition to thermally treated geopolymers up to 600 and 900 °C. The precursor of the geopolymer, and the geopolymer samples before and after the thermal treatment, were investigated by Fourier transformation infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and SEM analysis. The corrected average value of the ratio of silicon and aluminum in the geopolymer samples (SiGP:Al) is about 1.46, which suggests that the obtained geopolymer samples represent a mixture of roughly equal amounts of sialate and sialate-siloxo units. Annealing the geopolymer samples at 600 °C decreases the amount of Si-ONa bonds and induces the cross-linking of polymer changes. At the same time, other sodium containing alumino-silicate phases are created. The thermal treatment at 900 °C leads to a considerable reduction of oxygen and particularly sodium, followed by significant morphological changes i.e. formation of a complex porous structure. Additionally, a new semicrystaline phase appears. Both XRD and XPS results imply that this new phase may be nepheline and it is plausible that this phase begins to nucleate at temperatures below 900 °C.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Structural and chemical properties of thermally treated geopolymer samples",
pages = "6700-6700-6708-6708",
volume = "43, 43",
number = "9, 9",
doi = "10.1016/j.ceramint.2017.02.066",
url = "https://hdl.handle.net/21.15107/rcub_dais_2374"
}

Kljajević, L. M., Nenadović, S. S., Nenadović, M. T., Bundaleski, N. K., Todorović, B. Ž., Pavlović, V. B.,& Rakočević, Z.. (2017). Structural and chemical properties of thermally treated geopolymer samples. in Ceramics International
Elsevier., 43(9), 6700-6708.
https://doi.org/10.1016/j.ceramint.2017.02.066
https://hdl.handle.net/21.15107/rcub_dais_2374

Kljajević LM, Nenadović SS, Nenadović MT, Bundaleski NK, Todorović BŽ, Pavlović VB, Rakočević Z. Structural and chemical properties of thermally treated geopolymer samples. in Ceramics International. 2017;43(9):6700-6708.
doi:10.1016/j.ceramint.2017.02.066
https://hdl.handle.net/21.15107/rcub_dais_2374 .

Kljajević, Ljiljana M., Nenadović, Snežana S., Nenadović, Miloš T., Bundaleski, Nenad K., Todorović, Bratislav Ž., Pavlović, Vladimir B., Rakočević, Zlatko, "Structural and chemical properties of thermally treated geopolymer samples" in Ceramics International, 43, no. 9 (2017):6700-6708,
https://doi.org/10.1016/j.ceramint.2017.02.066 .,
https://hdl.handle.net/21.15107/rcub_dais_2374 .