Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200146 (University of Belgrade, Faculty of Physical Chemistry)

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Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200146 (University of Belgrade, Faculty of Physical Chemistry) (en)
Ministarstvo prosvete, nauke i tehnološkog razvoja Republike Srbije, Ugovor br. 451-03-68/2020-14/200146 (Univerzitet u Beogradu, Fakultet za fizičku hemiju) (sr_RS)
Министарство просвете, науке и технолошког развоја Републике Србије, Уговор бр. 451-03-68/2020-14/200146 (Универзитет у Београду, Факултет за физичку хемију) (sr)
Authors

Publications

Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook

Gezović, Aleksandra; Vujković, Milica; Milović, Miloš; Grudić, Veselinka; Dominko, Robert; Mentus, Slavko

(Elsevier BV, 2021)

TY  - JOUR
AU  - Gezović, Aleksandra
AU  - Vujković, Milica
AU  - Milović, Miloš
AU  - Grudić, Veselinka
AU  - Dominko, Robert
AU  - Mentus, Slavko
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11633
AB  - Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.
PB  - Elsevier BV
T2  - Energy Storage Materials
T1  - Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook
SP  - 243
EP  - 273
VL  - 37
DO  - 10.1016/j.ensm.2021.02.011
UR  - https://hdl.handle.net/21.15107/rcub_dais_11633
ER  - 
@article{
author = "Gezović, Aleksandra and Vujković, Milica and Milović, Miloš and Grudić, Veselinka and Dominko, Robert and Mentus, Slavko",
year = "2021",
abstract = "Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.",
publisher = "Elsevier BV",
journal = "Energy Storage Materials",
title = "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook",
pages = "243-273",
volume = "37",
doi = "10.1016/j.ensm.2021.02.011",
url = "https://hdl.handle.net/21.15107/rcub_dais_11633"
}
Gezović, A., Vujković, M., Milović, M., Grudić, V., Dominko, R.,& Mentus, S.. (2021). Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook. in Energy Storage Materials
Elsevier BV., 37, 243-273.
https://doi.org/10.1016/j.ensm.2021.02.011
https://hdl.handle.net/21.15107/rcub_dais_11633
Gezović A, Vujković M, Milović M, Grudić V, Dominko R, Mentus S. Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook. in Energy Storage Materials. 2021;37:243-273.
doi:10.1016/j.ensm.2021.02.011
https://hdl.handle.net/21.15107/rcub_dais_11633 .
Gezović, Aleksandra, Vujković, Milica, Milović, Miloš, Grudić, Veselinka, Dominko, Robert, Mentus, Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" in Energy Storage Materials, 37 (2021):243-273,
https://doi.org/10.1016/j.ensm.2021.02.011 .,
https://hdl.handle.net/21.15107/rcub_dais_11633 .
4
3
3

Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook

Gezović, Aleksandra; Vujković, Milica; Milović, Miloš; Grudić, Veselinka; Dominko, Robert; Mentus, Slavko

(Elsevier BV, 2021)

TY  - JOUR
AU  - Gezović, Aleksandra
AU  - Vujković, Milica
AU  - Milović, Miloš
AU  - Grudić, Veselinka
AU  - Dominko, Robert
AU  - Mentus, Slavko
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11632
AB  - Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.
PB  - Elsevier BV
T2  - Energy Storage Materials
T1  - Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook
SP  - 243
EP  - 273
VL  - 37
DO  - 10.1016/j.ensm.2021.02.011
UR  - https://hdl.handle.net/21.15107/rcub_dais_11632
ER  - 
@article{
author = "Gezović, Aleksandra and Vujković, Milica and Milović, Miloš and Grudić, Veselinka and Dominko, Robert and Mentus, Slavko",
year = "2021",
abstract = "Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.",
publisher = "Elsevier BV",
journal = "Energy Storage Materials",
title = "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook",
pages = "243-273",
volume = "37",
doi = "10.1016/j.ensm.2021.02.011",
url = "https://hdl.handle.net/21.15107/rcub_dais_11632"
}
Gezović, A., Vujković, M., Milović, M., Grudić, V., Dominko, R.,& Mentus, S.. (2021). Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook. in Energy Storage Materials
Elsevier BV., 37, 243-273.
https://doi.org/10.1016/j.ensm.2021.02.011
https://hdl.handle.net/21.15107/rcub_dais_11632
Gezović A, Vujković M, Milović M, Grudić V, Dominko R, Mentus S. Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook. in Energy Storage Materials. 2021;37:243-273.
doi:10.1016/j.ensm.2021.02.011
https://hdl.handle.net/21.15107/rcub_dais_11632 .
Gezović, Aleksandra, Vujković, Milica, Milović, Miloš, Grudić, Veselinka, Dominko, Robert, Mentus, Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" in Energy Storage Materials, 37 (2021):243-273,
https://doi.org/10.1016/j.ensm.2021.02.011 .,
https://hdl.handle.net/21.15107/rcub_dais_11632 .
4
3
3

Thermogravimetric insight in the reduction of xCuO – (1-x)MoO3 oxide system (0.1 ≤ x ≤ 0.9) by hydrogen

Jelić, Dijana; Zeljković, Saša; Jugović, Dragana; Mentus, Slavko

(Elsevier BV, 2021)

TY  - JOUR
AU  - Jelić, Dijana
AU  - Zeljković, Saša
AU  - Jugović, Dragana
AU  - Mentus, Slavko
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/10534
AB  - The oxide mixtures xCuO-(1-x) MoO3 were synthesized by gel-combustion procedure. The existence of phase mixture CuO + Cu3Mo2O9 and MoO3 + CuMoO4 in CuO-rich and MoO3 -rich composition region, respectively, were evidenced. The constant heating rate thermogravimetry in hydrogen atmosphere revealed that the reduction reactions proceed within the two clearly separated temperature regions. On the basis of mass changes, the mechanism of reduction processes was discussed. The measurements revealed considerable inhibition of CuO reduction by MoO3, and huge acceleration of MoO3 → MoO2 reduction step by copper. The particularities found in this system were commented in relation to our similar studies in NiO-MoO3 and CuO-WO3 systems. For particular composition, x = 0.5, existing preferably in form of a-CuMoO4, kinetic parameters of reduction were determined. The composition of oxide mixture influenced the particle size and morphology of resulting metallic Cu-Mo composites.
PB  - Elsevier BV
T2  - International Journal of Refractory Metals and Hard Materials
T1  - Thermogravimetric insight in the reduction of xCuO – (1-x)MoO3 oxide system (0.1 ≤ x ≤ 0.9) by hydrogen
SP  - 105480
VL  - 96
DO  - 10.1016/j.ijrmhm.2021.105480
UR  - https://hdl.handle.net/21.15107/rcub_dais_10534
ER  - 
@article{
author = "Jelić, Dijana and Zeljković, Saša and Jugović, Dragana and Mentus, Slavko",
year = "2021",
abstract = "The oxide mixtures xCuO-(1-x) MoO3 were synthesized by gel-combustion procedure. The existence of phase mixture CuO + Cu3Mo2O9 and MoO3 + CuMoO4 in CuO-rich and MoO3 -rich composition region, respectively, were evidenced. The constant heating rate thermogravimetry in hydrogen atmosphere revealed that the reduction reactions proceed within the two clearly separated temperature regions. On the basis of mass changes, the mechanism of reduction processes was discussed. The measurements revealed considerable inhibition of CuO reduction by MoO3, and huge acceleration of MoO3 → MoO2 reduction step by copper. The particularities found in this system were commented in relation to our similar studies in NiO-MoO3 and CuO-WO3 systems. For particular composition, x = 0.5, existing preferably in form of a-CuMoO4, kinetic parameters of reduction were determined. The composition of oxide mixture influenced the particle size and morphology of resulting metallic Cu-Mo composites.",
publisher = "Elsevier BV",
journal = "International Journal of Refractory Metals and Hard Materials",
title = "Thermogravimetric insight in the reduction of xCuO – (1-x)MoO3 oxide system (0.1 ≤ x ≤ 0.9) by hydrogen",
pages = "105480",
volume = "96",
doi = "10.1016/j.ijrmhm.2021.105480",
url = "https://hdl.handle.net/21.15107/rcub_dais_10534"
}
Jelić, D., Zeljković, S., Jugović, D.,& Mentus, S.. (2021). Thermogravimetric insight in the reduction of xCuO – (1-x)MoO3 oxide system (0.1 ≤ x ≤ 0.9) by hydrogen. in International Journal of Refractory Metals and Hard Materials
Elsevier BV., 96, 105480.
https://doi.org/10.1016/j.ijrmhm.2021.105480
https://hdl.handle.net/21.15107/rcub_dais_10534
Jelić D, Zeljković S, Jugović D, Mentus S. Thermogravimetric insight in the reduction of xCuO – (1-x)MoO3 oxide system (0.1 ≤ x ≤ 0.9) by hydrogen. in International Journal of Refractory Metals and Hard Materials. 2021;96:105480.
doi:10.1016/j.ijrmhm.2021.105480
https://hdl.handle.net/21.15107/rcub_dais_10534 .
Jelić, Dijana, Zeljković, Saša, Jugović, Dragana, Mentus, Slavko, "Thermogravimetric insight in the reduction of xCuO – (1-x)MoO3 oxide system (0.1 ≤ x ≤ 0.9) by hydrogen" in International Journal of Refractory Metals and Hard Materials, 96 (2021):105480,
https://doi.org/10.1016/j.ijrmhm.2021.105480 .,
https://hdl.handle.net/21.15107/rcub_dais_10534 .

Thermogravimetric insight in the reduction of xCuO – (1-x)MoO3 oxide system (0.1 ≤ x ≤ 0.9) by hydrogen

Jelić, Dijana; Zeljković, Saša; Jugović, Dragana; Mentus, Slavko

(Elsevier BV, 2021)

TY  - JOUR
AU  - Jelić, Dijana
AU  - Zeljković, Saša
AU  - Jugović, Dragana
AU  - Mentus, Slavko
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/10533
AB  - The oxide mixtures xCuO-(1-x) MoO3 were synthesized by gel-combustion procedure. The existence of phase mixture CuO + Cu3Mo2O9 and MoO3 + CuMoO4 in CuO-rich and MoO3 -rich composition region, respectively, were evidenced. The constant heating rate thermogravimetry in hydrogen atmosphere revealed that the reduction reactions proceed within the two clearly separated temperature regions. On the basis of mass changes, the mechanism of reduction processes was discussed. The measurements revealed considerable inhibition of CuO reduction by MoO3, and huge acceleration of MoO3 → MoO2 reduction step by copper. The particularities found in this system were commented in relation to our similar studies in NiO-MoO3 and CuO-WO3 systems. For particular composition, x = 0.5, existing preferably in form of a-CuMoO4, kinetic parameters of reduction were determined. The composition of oxide mixture influenced the particle size and morphology of resulting metallic Cu-Mo composites.
PB  - Elsevier BV
T2  - International Journal of Refractory Metals and Hard Materials
T1  - Thermogravimetric insight in the reduction of xCuO – (1-x)MoO3 oxide system (0.1 ≤ x ≤ 0.9) by hydrogen
SP  - 105480
VL  - 96
DO  - 10.1016/j.ijrmhm.2021.105480
UR  - https://hdl.handle.net/21.15107/rcub_dais_10533
ER  - 
@article{
author = "Jelić, Dijana and Zeljković, Saša and Jugović, Dragana and Mentus, Slavko",
year = "2021",
abstract = "The oxide mixtures xCuO-(1-x) MoO3 were synthesized by gel-combustion procedure. The existence of phase mixture CuO + Cu3Mo2O9 and MoO3 + CuMoO4 in CuO-rich and MoO3 -rich composition region, respectively, were evidenced. The constant heating rate thermogravimetry in hydrogen atmosphere revealed that the reduction reactions proceed within the two clearly separated temperature regions. On the basis of mass changes, the mechanism of reduction processes was discussed. The measurements revealed considerable inhibition of CuO reduction by MoO3, and huge acceleration of MoO3 → MoO2 reduction step by copper. The particularities found in this system were commented in relation to our similar studies in NiO-MoO3 and CuO-WO3 systems. For particular composition, x = 0.5, existing preferably in form of a-CuMoO4, kinetic parameters of reduction were determined. The composition of oxide mixture influenced the particle size and morphology of resulting metallic Cu-Mo composites.",
publisher = "Elsevier BV",
journal = "International Journal of Refractory Metals and Hard Materials",
title = "Thermogravimetric insight in the reduction of xCuO – (1-x)MoO3 oxide system (0.1 ≤ x ≤ 0.9) by hydrogen",
pages = "105480",
volume = "96",
doi = "10.1016/j.ijrmhm.2021.105480",
url = "https://hdl.handle.net/21.15107/rcub_dais_10533"
}
Jelić, D., Zeljković, S., Jugović, D.,& Mentus, S.. (2021). Thermogravimetric insight in the reduction of xCuO – (1-x)MoO3 oxide system (0.1 ≤ x ≤ 0.9) by hydrogen. in International Journal of Refractory Metals and Hard Materials
Elsevier BV., 96, 105480.
https://doi.org/10.1016/j.ijrmhm.2021.105480
https://hdl.handle.net/21.15107/rcub_dais_10533
Jelić D, Zeljković S, Jugović D, Mentus S. Thermogravimetric insight in the reduction of xCuO – (1-x)MoO3 oxide system (0.1 ≤ x ≤ 0.9) by hydrogen. in International Journal of Refractory Metals and Hard Materials. 2021;96:105480.
doi:10.1016/j.ijrmhm.2021.105480
https://hdl.handle.net/21.15107/rcub_dais_10533 .
Jelić, Dijana, Zeljković, Saša, Jugović, Dragana, Mentus, Slavko, "Thermogravimetric insight in the reduction of xCuO – (1-x)MoO3 oxide system (0.1 ≤ x ≤ 0.9) by hydrogen" in International Journal of Refractory Metals and Hard Materials, 96 (2021):105480,
https://doi.org/10.1016/j.ijrmhm.2021.105480 .,
https://hdl.handle.net/21.15107/rcub_dais_10533 .

The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries

Rakočević, Lazar; Štrbac, Svetlana; Potočnik, Jelena; Popović, Maja; Jugović, Dragana; Stojković Simatović, Ivana

(Elsevier, 2021)

TY  - JOUR
AU  - Rakočević, Lazar
AU  - Štrbac, Svetlana
AU  - Potočnik, Jelena
AU  - Popović, Maja
AU  - Jugović, Dragana
AU  - Stojković Simatović, Ivana
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11229
AB  - Cathodic material for sodium-ion rechargeable batteries based on NaxMnO2 were synthesized by glycine nitrate method and subsequent annealing at high temperatures. Different crystal structures with different morphologies were obtained depending on the annealing temperature: hexagonal layeredα-Na0.7MnO2.05 nanoplates were obtained at 850 ◦C, while 3-D tunnel structured Na0⋅4MnO2 and Na0⋅44MnO2, both with rod-like morphology, were obtained at 800 ◦C and 900 ◦C, respectively. The investigations of the electrochemical behavior of obtained cathodic materials in aqueous NaNO3 solution have shown that Na0⋅44MnO2 obtained at 900 ◦C has shown the best battery performance. Its initial discharge capacities are 123.5 mA h/g, 113.2 mA h/g, and 102.0 mA h/g at the high current densities of 1000, 2000 and 5000 mA/g, respectively.
PB  - Elsevier
T2  - Ceramics International
T1  - The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries
SP  - 4595
EP  - 4603
VL  - 47
IS  - 4
DO  - 10.1016/j.ceramint.2020.10.025
UR  - https://hdl.handle.net/21.15107/rcub_dais_11229
ER  - 
@article{
author = "Rakočević, Lazar and Štrbac, Svetlana and Potočnik, Jelena and Popović, Maja and Jugović, Dragana and Stojković Simatović, Ivana",
year = "2021",
abstract = "Cathodic material for sodium-ion rechargeable batteries based on NaxMnO2 were synthesized by glycine nitrate method and subsequent annealing at high temperatures. Different crystal structures with different morphologies were obtained depending on the annealing temperature: hexagonal layeredα-Na0.7MnO2.05 nanoplates were obtained at 850 ◦C, while 3-D tunnel structured Na0⋅4MnO2 and Na0⋅44MnO2, both with rod-like morphology, were obtained at 800 ◦C and 900 ◦C, respectively. The investigations of the electrochemical behavior of obtained cathodic materials in aqueous NaNO3 solution have shown that Na0⋅44MnO2 obtained at 900 ◦C has shown the best battery performance. Its initial discharge capacities are 123.5 mA h/g, 113.2 mA h/g, and 102.0 mA h/g at the high current densities of 1000, 2000 and 5000 mA/g, respectively.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries",
pages = "4595-4603",
volume = "47",
number = "4",
doi = "10.1016/j.ceramint.2020.10.025",
url = "https://hdl.handle.net/21.15107/rcub_dais_11229"
}
Rakočević, L., Štrbac, S., Potočnik, J., Popović, M., Jugović, D.,& Stojković Simatović, I.. (2021). The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries. in Ceramics International
Elsevier., 47(4), 4595-4603.
https://doi.org/10.1016/j.ceramint.2020.10.025
https://hdl.handle.net/21.15107/rcub_dais_11229
Rakočević L, Štrbac S, Potočnik J, Popović M, Jugović D, Stojković Simatović I. The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries. in Ceramics International. 2021;47(4):4595-4603.
doi:10.1016/j.ceramint.2020.10.025
https://hdl.handle.net/21.15107/rcub_dais_11229 .
Rakočević, Lazar, Štrbac, Svetlana, Potočnik, Jelena, Popović, Maja, Jugović, Dragana, Stojković Simatović, Ivana, "The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries" in Ceramics International, 47, no. 4 (2021):4595-4603,
https://doi.org/10.1016/j.ceramint.2020.10.025 .,
https://hdl.handle.net/21.15107/rcub_dais_11229 .
1

The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries

Rakočević, Lazar; Štrbac, Svetlana; Potočnik, Jelena; Popović, Maja; Jugović, Dragana; Stojković Simatović, Ivana

(Elsevier BV, 2021)

TY  - JOUR
AU  - Rakočević, Lazar
AU  - Štrbac, Svetlana
AU  - Potočnik, Jelena
AU  - Popović, Maja
AU  - Jugović, Dragana
AU  - Stojković Simatović, Ivana
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/10035
AB  - Cathodic material for sodium-ion rechargeable batteries based on NaxMnO2 were synthesized by glycine nitrate method and subsequent annealing at high temperatures. Different crystal structures with different morphologies were obtained depending on the annealing temperature: hexagonal layeredα-Na0.7MnO2.05 nanoplates were obtained at 850 °C, while 3-D tunnel structured Na0·4MnO2 and Na0·44MnO2, both with rod-like morphology, were obtained at 800 °C and 900 °C, respectively. The investigations of the electrochemical behavior of obtained cathodic materials in aqueous NaNO3 solution have shown that Na0·44MnO2 obtained at 900 °C has shown the best battery performance. Its initial discharge capacities are 123.5 mA h/g, 113.2 mA h/g, and 102.0 mA h/g at the high current densities of 1000, 2000 and 5000 mA/g, respectively.
PB  - Elsevier BV
T2  - Ceramics International
T1  - The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries
SP  - 4595
EP  - 4603
VL  - 47
IS  - 4
DO  - 10.1016/j.ceramint.2020.10.025
UR  - https://hdl.handle.net/21.15107/rcub_dais_10035
ER  - 
@article{
author = "Rakočević, Lazar and Štrbac, Svetlana and Potočnik, Jelena and Popović, Maja and Jugović, Dragana and Stojković Simatović, Ivana",
year = "2021",
abstract = "Cathodic material for sodium-ion rechargeable batteries based on NaxMnO2 were synthesized by glycine nitrate method and subsequent annealing at high temperatures. Different crystal structures with different morphologies were obtained depending on the annealing temperature: hexagonal layeredα-Na0.7MnO2.05 nanoplates were obtained at 850 °C, while 3-D tunnel structured Na0·4MnO2 and Na0·44MnO2, both with rod-like morphology, were obtained at 800 °C and 900 °C, respectively. The investigations of the electrochemical behavior of obtained cathodic materials in aqueous NaNO3 solution have shown that Na0·44MnO2 obtained at 900 °C has shown the best battery performance. Its initial discharge capacities are 123.5 mA h/g, 113.2 mA h/g, and 102.0 mA h/g at the high current densities of 1000, 2000 and 5000 mA/g, respectively.",
publisher = "Elsevier BV",
journal = "Ceramics International",
title = "The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries",
pages = "4595-4603",
volume = "47",
number = "4",
doi = "10.1016/j.ceramint.2020.10.025",
url = "https://hdl.handle.net/21.15107/rcub_dais_10035"
}
Rakočević, L., Štrbac, S., Potočnik, J., Popović, M., Jugović, D.,& Stojković Simatović, I.. (2021). The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries. in Ceramics International
Elsevier BV., 47(4), 4595-4603.
https://doi.org/10.1016/j.ceramint.2020.10.025
https://hdl.handle.net/21.15107/rcub_dais_10035
Rakočević L, Štrbac S, Potočnik J, Popović M, Jugović D, Stojković Simatović I. The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries. in Ceramics International. 2021;47(4):4595-4603.
doi:10.1016/j.ceramint.2020.10.025
https://hdl.handle.net/21.15107/rcub_dais_10035 .
Rakočević, Lazar, Štrbac, Svetlana, Potočnik, Jelena, Popović, Maja, Jugović, Dragana, Stojković Simatović, Ivana, "The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries" in Ceramics International, 47, no. 4 (2021):4595-4603,
https://doi.org/10.1016/j.ceramint.2020.10.025 .,
https://hdl.handle.net/21.15107/rcub_dais_10035 .
1

Supplementary information for the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011

Gezović, Aleksandra; Vujković, Milica; Milović, Miloš; Grudić, Veselinka; Dominko, Robert; Mentus, Slavko

(Elsevier BV, 2021)

TY  - DATA
AU  - Gezović, Aleksandra
AU  - Vujković, Milica
AU  - Milović, Miloš
AU  - Grudić, Veselinka
AU  - Dominko, Robert
AU  - Mentus, Slavko
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11634
AB  - Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.
PB  - Elsevier BV
T2  - Energy Storage Materials
T1  - Supplementary information for the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011
VL  - 37
UR  - https://hdl.handle.net/21.15107/rcub_dais_11634
ER  - 
@misc{
author = "Gezović, Aleksandra and Vujković, Milica and Milović, Miloš and Grudić, Veselinka and Dominko, Robert and Mentus, Slavko",
year = "2021",
abstract = "Sodium ion batteries (SIB) present one of the most perspective post lithium technology and their progress strongly depends on the development of compounds having the structure which enables fast sodium insertion/deinsertion reactions. Polyanion compounds have been widely investigated as cathode materials for SIBs where they compete effectively to the usually used layered oxides. This survey is focused on the development of specific family of isostructural polyanion phases encompassed by the common chemical formula Na4M3(PO4)2(P2O7). The comprehensive retrospective of their synthesis procedures, the kinetics and mechanism of sodiation/desodiation reactions, based on both experimental and theoretical results, is provided. First, the review summarizes the structural properties of variety of Na4M3(PO4)2(P2O7) compounds in terms of its electrical, vibrational and surface properties. Then, the synthesis methods and sodium/lithium storage performance, of each type of Na4M3(PO4)2(P2O7) compounds, are chronologically presented and discussed. Finally, the strengths and weaknesses of these mixed polyanion cathodes are outlined, with the aim to explain some discrepancies and unclarified issues encountered in the literature. Besides, this survey will make room for future development. It can be very useful for the future design of high-performance mixed polyanionic compounds as cathodes for alkaline-ion rechargeable batteries.",
publisher = "Elsevier BV",
journal = "Energy Storage Materials",
title = "Supplementary information for the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011",
volume = "37",
url = "https://hdl.handle.net/21.15107/rcub_dais_11634"
}
Gezović, A., Vujković, M., Milović, M., Grudić, V., Dominko, R.,& Mentus, S.. (2021). Supplementary information for the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011. in Energy Storage Materials
Elsevier BV., 37.
https://hdl.handle.net/21.15107/rcub_dais_11634
Gezović A, Vujković M, Milović M, Grudić V, Dominko R, Mentus S. Supplementary information for the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011. in Energy Storage Materials. 2021;37.
https://hdl.handle.net/21.15107/rcub_dais_11634 .
Gezović, Aleksandra, Vujković, Milica, Milović, Miloš, Grudić, Veselinka, Dominko, Robert, Mentus, Slavko, "Supplementary information for the article: Gezović Aleksandra, Vujković Milica, Milović Miloš, Grudić Veselinka, Dominko Robert, Mentus Slavko, "Recent developments of Na4M3(PO4)2(P2O7) as the cathode material for alkaline-ion rechargeable batteries: challenges and outlook" Energy Storage Materials, 37 (2021):243-273, https://doi.org/10.1016/j.ensm.2021.02.011" in Energy Storage Materials, 37 (2021),
https://hdl.handle.net/21.15107/rcub_dais_11634 .

HAp:Co as tunable VIS-NIR reflective pigment

Marković, Smilja; Stojanović, Zoran S.; Veselinović, Ljiljana; Simić, Danica; Samolov, Aleksandra; Stojković Simatović, Ivana

(Belgrade : Military Technical Institute, 2020)

TY  - CONF
AU  - Marković, Smilja
AU  - Stojanović, Zoran S.
AU  - Veselinović, Ljiljana
AU  - Simić, Danica
AU  - Samolov, Aleksandra
AU  - Stojković Simatović, Ivana
PY  - 2020
UR  - http://www.vti.mod.gov.rs/oteh/elementi/rad/125.pdf
UR  - https://dais.sanu.ac.rs/123456789/10038
AB  - Radar-absorbent materials, used in stealth technology for defense aircrafts, vehicles, satellites, etc. from radar detection, are commonly based on graphite or semiconductive particles embedded in a polymer matrix. In this study, we employed Co2+ ion-substitution to improve Vis-NIR reflectivity of hydroxyapatite (Ca10(PO4)6(OH)2, HAP) powder. HAP:Co with nominally 5 at.% of Co was prepared with hydrothermal processing of a precipitate. Synthesized powder was characterized by XRD, Raman and ATR-FTIR spectroscopy, FE-SEM and TEM. Thermal stability of HAP:Co powder was examined by simultaneous TG-DTA analyzer. To modify its optical properties and obtain powders with a varietty of color tone, the HAP:Co powder was calcined at 800, 1000, and 1100 °C, in an air atmosphere, for 1 hour. Afterward, the calcined particles were used to prepare composites with poly(vinyl butyral), (PVB); the concentration range was 1 wt.% of the HAP:Co in PVB. The composite coatings, in the form of thin films on glass, were prepared by the solvent-casting technique, using ethanol as a fast evaporating solvent. Firstly, the HAP:Co particles were dispersed in ethanol, then PVB was added (Mowital B30H) and dissolved. To evaporate the solvent before spectrophotometric measurements, the coatings on glass were dried at room temperature for 72 hours. To comprehend optical properties of the coatings, diffuse reflection, transmission, and color coordinates were determined. We found that calcined HAP:Co particles have potential to be used in the formulation of coatings for camouflage protection.
PB  - Belgrade : Military Technical Institute
C3  - 9th International Scientific Conference on Defensive Technologies : OTEH2020, Belgrade, Serbia, 15-16 October 2020
T1  - HAp:Co as tunable VIS-NIR reflective pigment
SP  - 475
EP  - 480
UR  - https://hdl.handle.net/21.15107/rcub_dais_10038
ER  - 
@conference{
author = "Marković, Smilja and Stojanović, Zoran S. and Veselinović, Ljiljana and Simić, Danica and Samolov, Aleksandra and Stojković Simatović, Ivana",
year = "2020",
abstract = "Radar-absorbent materials, used in stealth technology for defense aircrafts, vehicles, satellites, etc. from radar detection, are commonly based on graphite or semiconductive particles embedded in a polymer matrix. In this study, we employed Co2+ ion-substitution to improve Vis-NIR reflectivity of hydroxyapatite (Ca10(PO4)6(OH)2, HAP) powder. HAP:Co with nominally 5 at.% of Co was prepared with hydrothermal processing of a precipitate. Synthesized powder was characterized by XRD, Raman and ATR-FTIR spectroscopy, FE-SEM and TEM. Thermal stability of HAP:Co powder was examined by simultaneous TG-DTA analyzer. To modify its optical properties and obtain powders with a varietty of color tone, the HAP:Co powder was calcined at 800, 1000, and 1100 °C, in an air atmosphere, for 1 hour. Afterward, the calcined particles were used to prepare composites with poly(vinyl butyral), (PVB); the concentration range was 1 wt.% of the HAP:Co in PVB. The composite coatings, in the form of thin films on glass, were prepared by the solvent-casting technique, using ethanol as a fast evaporating solvent. Firstly, the HAP:Co particles were dispersed in ethanol, then PVB was added (Mowital B30H) and dissolved. To evaporate the solvent before spectrophotometric measurements, the coatings on glass were dried at room temperature for 72 hours. To comprehend optical properties of the coatings, diffuse reflection, transmission, and color coordinates were determined. We found that calcined HAP:Co particles have potential to be used in the formulation of coatings for camouflage protection.",
publisher = "Belgrade : Military Technical Institute",
journal = "9th International Scientific Conference on Defensive Technologies : OTEH2020, Belgrade, Serbia, 15-16 October 2020",
title = "HAp:Co as tunable VIS-NIR reflective pigment",
pages = "475-480",
url = "https://hdl.handle.net/21.15107/rcub_dais_10038"
}
Marković, S., Stojanović, Z. S., Veselinović, L., Simić, D., Samolov, A.,& Stojković Simatović, I.. (2020). HAp:Co as tunable VIS-NIR reflective pigment. in 9th International Scientific Conference on Defensive Technologies : OTEH2020, Belgrade, Serbia, 15-16 October 2020
Belgrade : Military Technical Institute., 475-480.
https://hdl.handle.net/21.15107/rcub_dais_10038
Marković S, Stojanović ZS, Veselinović L, Simić D, Samolov A, Stojković Simatović I. HAp:Co as tunable VIS-NIR reflective pigment. in 9th International Scientific Conference on Defensive Technologies : OTEH2020, Belgrade, Serbia, 15-16 October 2020. 2020;:475-480.
https://hdl.handle.net/21.15107/rcub_dais_10038 .
Marković, Smilja, Stojanović, Zoran S., Veselinović, Ljiljana, Simić, Danica, Samolov, Aleksandra, Stojković Simatović, Ivana, "HAp:Co as tunable VIS-NIR reflective pigment" in 9th International Scientific Conference on Defensive Technologies : OTEH2020, Belgrade, Serbia, 15-16 October 2020 (2020):475-480,
https://hdl.handle.net/21.15107/rcub_dais_10038 .